In-Situ Direct Analysis of the Growing Species by119Sn NMR Spectroscopy:  Living Cationic Polymerization of Isobutyl Vinyl Ether with HCl/SnCl4/nBu4NCl1

1998 ◽  
Vol 31 (15) ◽  
pp. 4703-4709 ◽  
Author(s):  
Hiroshi Katayama ◽  
Masami Kamigaito ◽  
Mitsuo Sawamoto
Keyword(s):  
Nmr Spectroscopy ◽  
Vinyl Ether ◽  
Cationic Polymerization ◽  
Direct Analysis ◽  
Living Cationic Polymerization

In situ and readily prepared metal catalysts and initiators for living cationic polymerization of isobutyl vinyl ether: dual-purpose salphen as a ligand framework for ZrCl4and an initiating proton source

2015 ◽  
Vol 6 (1) ◽  
pp. 30-34 ◽  
Author(s):  
Sensho Kigoshi ◽  
Arihiro Kanazawa ◽  
Shokyoku Kanaoka ◽  
Sadahito Aoshima
Keyword(s):  
Vinyl Ether ◽  
Cationic Polymerization ◽  
Metal Catalysts ◽  
Dual Purpose ◽  
Living Cationic Polymerization ◽  
Proton Source

A well-defined catalyst, generated quantitativelyin situsimply by mixing ZrCl4and a salphen ligand was shown to induce the living cationic polymerization of isobutyl vinyl ether.

Living Cationic Polymerization of Vinyl Ether with a Thienyl Group

2015 ◽  
Vol 72 (7) ◽  
pp. 433-439
Author(s):  
Takeshi NAMIKOSHI ◽  
Ayaka KANEDA ◽  
Takashi MIYANAGA ◽  
Shinji WATANABE ◽  
Miki MURATA
Keyword(s):  
Vinyl Ether ◽  
Cationic Polymerization ◽  
Living Cationic Polymerization ◽  
Thienyl Group
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