scholarly journals Characteristics of ultrafine-ground potassium-bearing shale and the effects of roasting pre-cracking

2022 ◽  
Vol 12 (1) ◽  
Author(s):  
Zaisheng Zhu ◽  
Zhenquan He ◽  
Guosheng Gai

AbstractPotassium-bearing shale is being developed as a potential alternative to potash for use in fertilisers. The first step in this process is to reduce its particle size by crushing. This paper explores whether roasting pre-cracked potassium-bearing shale can improve the quality of the resulting ultrafine product. Analysis of the particle size distribution of the ultrafine product and its fractal dimension found contradictory results: the minimum particle size distribution was obtained by roasting for 2.5 h, while the minimum fractal dimension was obtained by roasting for 1 h. Fuzzy comprehensive evaluation was conducted with three indicators—(1) the weight of the − 10 μm product, (2) the fractal dimension of the particle size distribution, and (3) d97—to obtain a unique combination of indicators that reflects the quality and quantity of the products. The weights of the three indicators were calculated by an analytic hierarchical process to be 0.69, 0.149 and 0.161, respectively. Roasting pre-cracked shale for 2–2.5 h was found to improve the mean values of the fuzzy comprehensive evaluation indicators by about 0.07. However, the cost increased from 2.82 RMB to ≥ 10.08 RMB, which is not feasible for widespread industrial implementation.

2021 ◽  
Author(s):  
Zaisheng Zhu ◽  
Zhenquan He ◽  
Guosheng Gai

Abstract As potassium-bearing shale is still being developed as a potential alternative to potash, the first step to improve its utilisation is to reduce its particle size. This paper explores whether roasting pre-cracked potassium-bearing shale can improve the quality of ultra-fine crushing products. By analysing the particle size distribution and the fractal dimension of the particle size distribution, the results for 1 h and 2 h roasting pre-cracking experiments were found to be contradictory. AHP-fuzzy comprehensive evaluation of the three indicators of product quality and quantity was used, resulting in a unique indicator. Roasting pre-cracking for 2 h was found to have a facilitating effect, with the average of the three fuzzy comprehensive evaluation values increasing from 0.71 to 0.78. The great difference in cost outlay suggests that the technique is not suitable for industrial applications. Subsequently, two groups of microwave pretreatment experiments were carried out but led to unsatisfactory results in which microwave pretreatment was not conducive to the ultrafine grinding of potassium-bearing shale.


2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Xinlei Jia ◽  
Jingyu Wang ◽  
Conghua Hou ◽  
Yingxin Tan

Herein, a green process for preparing nano-HMX, mechanical demulsification shearing (MDS) technology, was developed. Nano-HMX was successfully fabricated via MDS technology without using any chemical reagents, and the fabrication mechanism was proposed. Based on the “fractal theory,” the optimal shearing time for mechanical emulsification was deduced by calculating the fractal dimension of the particle size distribution. The as-prepared nano-HMX was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). And the impact sensitivities of HMX particles were contrastively investigated. The raw HMX had a lower fractal dimension of 1.9273. The ideal shearing time was 7 h. The resultant nano-HMX possessed a particle size distribution ranging from 203.3 nm to 509.1 nm as compared to raw HMX. Nano-HMX particles were dense spherical, maintaining β-HMX crystal form. In addition, they had much lower impact sensitivity. However, the apparent activation energy as well as thermal decomposition temperature of nano-HMX particles was decreased, attributing to the reduced probability for hotspot generation. Especially when the shearing time was 7 h, the activation energy was markedly decreased.


1982 ◽  
Vol 60 (8) ◽  
pp. 1101-1107
Author(s):  
C. V. Mathai ◽  
A. W. Harrison

As part of an ongoing general research program on the effects of atmospheric aerosols on visibility and its dependence on aerosol size distributions in Calgary, this paper presents the results of a comparative study of particle size distribution and visibility in residential (NW) and industrial (SE) sections of the city using a mobile laboratory. The study was conducted in the period October–December, 1979. An active scattering aerosol spectrometer measured the size distributions and the corresponding visibilities were deduced from scattering coefficients measured with an integrating nephelometer.The results of this transit study show significantly higher suspended particle concentrations and reduced visibilities in the SE than in the NW. The mean values of the visibilities are 44 and 97 km for the SE and the NW respectively. The exponent of R (particle radius) in the power law aerosol size distribution has a mean value of −3.36 ± 0.24 in the SE compared with the corresponding value of −3.89 ± 0.39 for the NW. These results arc in good agreement with the observations of Alberta Environment; however, they are in contradiction with a recent report published by the City of Calgary.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Yufeng Bai ◽  
Yan Qin ◽  
Xinrui Lu ◽  
Jitao Zhang ◽  
Guoshuang Chen ◽  
...  

AbstractThe purpose of this study was to identify the fractal dimension and their relationships with alkalinity properties of soils, and to evaluate the potential of fractal dimension as an indicator of alkalinity properties of soil. Six soils with an increasing salinity (electrical conductivity was 0.09, 0.18, 0.62, 0.78, 1.57 and 1.99 dS m−1, respectively) were selected from the western part of the Songnen Plain (China). Salt content, exchangeable sodium percentage, sodium adsorption ratio and other properties of the soils were determined and the soil particle-size distribution (0–2000 μm) was measured using a laser diffraction particle size analyser. Our results show that the overall fractal dimension of the selected soils ranged from 2.35 to 2.60. A linear regression analysis showed a significant negative correlation between fractal dimension and the amount of coarse sand and fine sand (r =  − 0.5452, P < 0.05 and r =  − 0.8641, P < 0.01, respectively), and a significant positive correlation with silt and clay (r = 0.9726, P < 0.01 and r = 0.9526, P < 0.01, respectively). Thus, soils with higher silt and clay content have higher fractal dimension values. Strong linear relationships between fractal dimension and salt content (P < 0.05), in particular a very significant positive relationship with HCO3− (P < 0.01), also exist. It is therefore possible to conclude that a soil’s fractal dimension could serve as a potential indicator of soil alkalization and the variability in alkaline soil texture.


2013 ◽  
Vol 12 (1) ◽  
pp. vzj2012.0064 ◽  
Author(s):  
Andrzej Bieganowski ◽  
Tymoteusz Chojecki ◽  
Magdalena Ryżak ◽  
Agata Sochan ◽  
Krzysztof Lamorski

2011 ◽  
Vol 243-249 ◽  
pp. 4827-4830
Author(s):  
Hao Yu Li ◽  
Jun Nan ◽  
Wei Peng He

The coagulation experiment, with Kaolin as objects, aluminum chloride (PAC) as coagulant and hydrated MnO2 as coagulant aid, were accomplished under different conditions. In the experiment, the particle size distribution and turbidity in water were detected by on-line detector. The results show that increase PAC dosage, original turbidity, hydrated MnO2 dosage and coagulation time will make the fractal dimensions of floc growth in micro-coagulation stage increase. The fractal dimensions of floc growth in micro-coagulation stage increasing means more particle size <5µm flocs are removed. Hydrated MnO2 can strengthen micro-coagulation.


2013 ◽  
Vol 136 ◽  
pp. 85-92 ◽  
Author(s):  
De-Xin Ding ◽  
Hai-Ying Fu ◽  
Yong-Jun Ye ◽  
Nan Hu ◽  
Guang-Yue Li ◽  
...  

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