scholarly journals Calcium-free double-layered cuprate superconductors with critical temperature above 100 K

2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Hiroki Ninomiya ◽  
Kenji Kawashima ◽  
Akira Iyo ◽  
Hiroshi Fujihisa ◽  
Shigeyuki Ishida ◽  
...  
Keyword(s):  
Critical Temperature ◽  
Cuprate Superconductors ◽  
Structural Parameters ◽  
Synthesis Process ◽  
Critical Temperatures ◽  
Potential Applications ◽  
Layered Cuprates

AbstractCalcium is a vital constituent in multilayered cuprate superconductors with critical temperatures (Tc) above 100 K, because it plays a key role in separating CuO2 planes. Here, we demonstrate the synthesis of calcium-free double-layered cuprates: Sr2SrCu2O4(X,O)2(X = F, Cl, and Br) and M(Sr,Ba)2SrCu2Oy(M = Hg/Re, Tl, and B/C), where strontium exists between the CuO2 planes. Oxyfluoride and mercury-based materials show a Tc of 107 K and 110 K, respectively, which are high compared to existing calcium-free cuprates. These findings indicate Tc greater than 100 K can be realized by replacing both barium and calcium, which have been indispensable in conventional multilayered cuprates, with strontium. Furthermore, the non-toxicity of Sr2SrCu2O4F2 and (B,C)Sr2SrCu2Oy simplifies the synthesis process and ensures their safety in potential applications. We also perform a comparison of the characteristic structural parameters between the calcium-free and calcium-containing cuprates considering the number of CuO2 planes.

Graphene nanocomposites: A review on processes, properties, and applications

2021 ◽  
pp. 152808372110242
Author(s):  
Kadir Bilisik ◽  
Mahmuda Akter
Keyword(s):  
Textile Industry ◽  
In Situ Polymerization ◽  
Resin Transfer Molding ◽  
Single Layer ◽  
Chemical Vapor ◽  
Synthesis Process ◽  
Graphene Nanocomposites ◽  
Transfer Molding ◽  
Potential Applications ◽  
Nano Graphene

In this paper, graphene, graphene/matrix, and graphene/fiber nanocomposites, including their synthesis process, fabrication, properties, and potential applications, were reviewed. It was found that several synthesis techniques for nanographene were developed, such as liquid-phase exfoliation and chemical vapor deposition. In addition, some fabrication processes of graphene/matrix and graphene/fiber-based nanocomposites were made, including in-situ polymerization, nanostitching in that single layer nano graphene plate could be interconnected by means of carbon nanotube stitching, resin transfer molding, and vacuum-assisted resin transfer molding. Several properties, including mechanical, thermal, and electrical, on the graphene nanoplatelets materials were summarized in this review paper. It was realized that graphene, graphene/matrix, and graphene/fiber nanocomposites have extraordinary mechanical, thermal, and electrical properties used in advanced engineering applications, including soft robotics, microelectronics, energy storage, biomedical and biosensors as well as textile industry.

scholarly journals The Structure–Properties–Cytotoxicity Interplay: A Crucial Pathway to Determining Graphene Oxide Biocompatibility

2021 ◽  
Vol 22 (10) ◽  
pp. 5401
Author(s):  
Marta Dziewięcka ◽  
Mirosława Pawlyta ◽  
Łukasz Majchrzycki ◽  
Katarzyna Balin ◽  
Sylwia Barteczko ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Defense Mechanisms ◽  
Physicochemical Analysis ◽  
Experimental Models ◽  
Acheta Domesticus ◽  
Synthesis Process ◽  
Synthesis Methods ◽  
Toxicity Potential ◽  
Potential Applications

Interest in graphene oxide nature and potential applications (especially nanocarriers) has resulted in numerous studies, but the results do not lead to clear conclusions. In this paper, graphene oxide is obtained by multiple synthesis methods and generally characterized. The mechanism of GO interaction with the organism is hard to summarize due to its high chemical activity and variability during the synthesis process and in biological buffers’ environments. When assessing the biocompatibility of GO, it is necessary to take into account many factors derived from nanoparticles (structure, morphology, chemical composition) and the organism (species, defense mechanisms, adaptation). This research aims to determine and compare the in vivo toxicity potential of GO samples from various manufacturers. Each GO sample is analyzed in two concentrations and applied with food. The physiological reactions of an easy model Acheta domesticus (cell viability, apoptosis, oxidative defense, DNA damage) during ten-day lasting exposure were observed. This study emphasizes the variability of the GO nature and complements the biocompatibility aspect, especially in the context of various GO-based experimental models. Changes in the cell biomarkers are discussed in light of detailed physicochemical analysis.

scholarly journals TEMPERATURE CHARACTERISTICS FOR PULSATION FREQUENCY IN GONIONEMUS

1928 ◽  
Vol 11 (5) ◽  
pp. 547-562 ◽  
Author(s):  
Ernst Wolf
Keyword(s):  
Critical Temperature ◽  
Functional Unit ◽  
Temperature Characteristic ◽  
Nerve Ring ◽  
Pulsation Frequency ◽  
Sense Organs ◽  
Critical Temperatures ◽  
Temperature Characteristics ◽  
System A ◽  
Definite Temperature

The frequency of contraction of the bell of Gonionemus was studied in relation to temperature, with intact animals and also where different operations were made on the nervous system. A number of values of µ are found for intact animals namely 8,100±, 10,500±, 32,000± and 22,500±, with critical temperatures at 9.6°, 12.3°, and 14.0°. Four different classes of operations were used: (1) Animals where the nerve ring was cut on two opposite sides of the bell; the µ values found are 10,500± and 21,300±, with a critical temperature at 13.4°. (2) Animals with four cuts through the nerve ring gave µ = 10,600 ± and µ = 21,000, with a critical temperature at 13.1°. (3) In animals where the bell was cut in half the temperature characteristic was found to be 16,900. And finally (4) in the animals where the nerve ring was totally removed µ values of 8,100, 16,000±, and 29,000 were found, with critical temperatures at 15.0° and 9.4°. These results are discussed from the standpoint of the theory which supposes that definite "temperature characteristics" may be associated with the functional activity of particular elements in a complex functional unit, and that these elements may be separately studied and identified by suitable experimental procedures involving the magnitudes of the respective temperature characteristics and the locations of associated critical temperatures. The swimming bell of medusæ with its marginal sense organs permits a fairly direct approach to such questions. It is found that even slight injuries to the marginal nerve ring, for example, produce specific modifications in the temperature relations which are different from those appearing when the organism is cut in half.

scholarly journals EFFECTS OF c-AXIS HOPPING IN THE INTERLAYER TUNNELING MODEL OF HIGH-Tc LAYERED CUPRATES

1999 ◽  
Vol 13 (13) ◽  
pp. 1619-1632
Author(s):  
BIPLAB CHATTOPADHYAY ◽  
A. N. DAS
Keyword(s):  
Experimental Data ◽  
Transition Temperature ◽  
Cuprate Superconductors ◽  
Interlayer Coupling ◽  
Superconducting Gap ◽  
Tunneling Model ◽  
High Tc ◽  
Optimal Doping ◽  
Pair Tunneling ◽  
Layered Cuprates

We consider the interlayer pair-tunneling model for layered cuprates, including an effective single particle hopping along the c-axis. A phenomenological suppression of the c-axis hopping matrix element, by the pseudogap in cuprate superconductors, is incorporated. At optimal doping, quantities characteristic to the superconducting state, such as the transition temperature and the superconducting gap are calculated. Results from our calculations are consistent with the experimental observations with the noteworthy point that, the superconducting gap as a function of temperature shows excellent match to the experimental data. Predictions within the model, regarding T c variation with interlayer coupling, are natural outcomes which could be tested further.

Crystalline-To-Amorphous Transformation of Intermetallic Compounds in the Zr-Fe-M System Induced by Irradiation

1994 ◽  
Vol 373 ◽  
Author(s):  
Arthur T. Motta ◽  
Lawrence M. Howe ◽  
Paul R. Okamoto
Keyword(s):  
Critical Temperature ◽  
Low Temperature ◽  
Dose Rate ◽  
Intermetallic Compounds ◽  
Electron Energy ◽  
Energy Dependence ◽  
Electron Irradiation ◽  
Critical Temperatures ◽  
Lower Critical Temperature ◽  
Ternary Intermetallic Compounds

AbstractThe binary and ternary intermetallic compounds Zr3Fe, Zr2 Fe, (Zr0.5,Nb0.5)3Fe, Zr3(Fe0.9,Ni0.1) and Zr3(Fe0.5,Ni0.5) were subjected to 900 keV electron irradiation until amorphous to study the change in the dose-to-amorphization with temperature. The critical temperatures were observed to vary with dose rate, and with the type of compound. Hexagonal (Zr0.5,Nb0.5)3Fe had an appreciably lower critical temperature and higher dose to amorphization at low temperature than orthorombic Zr3Fe, whereas other orthorombic Zr3(Fex,NiI-x) compounds were essentially identical in behavior to Zr3Fe. The electron energy dependence of the dose-to-amorphization was studied in Zr3Fe between 250 and 900 keV. The analysis of the results gives displacement energies of EZrd = 26 eV, EFed = 18 eV in the Zr3Fe compound.

scholarly journals Strong correlation between electronic bonding network and critical temperature in hydrogen-based superconductors

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Francesco Belli ◽  
Trinidad Novoa ◽  
J. Contreras-García ◽  
Ion Errea
Keyword(s):  
Critical Temperature ◽  
Physical Properties ◽  
Fermi Level ◽  
Electronic Properties ◽  
Density Of States ◽  
Strong Correlation ◽  
Critical Temperatures ◽  
Structural And Electronic Properties ◽  
Superconducting Compounds ◽  
Better Than

AbstractBy analyzing structural and electronic properties of more than a hundred predicted hydrogen-based superconductors, we determine that the capacity of creating an electronic bonding network between localized units is key to enhance the critical temperature in hydrogen-based superconductors. We define a magnitude named as the networking value, which correlates with the predicted critical temperature better than any other descriptor analyzed thus far. By classifying the studied compounds according to their bonding nature, we observe that such correlation is bonding-type independent, showing a broad scope and generality. Furthermore, combining the networking value with the hydrogen fraction in the system and the hydrogen contribution to the density of states at the Fermi level, we can predict the critical temperature of hydrogen-based compounds with an accuracy of about 60 K. Such correlation is useful to screen new superconducting compounds and offers a deeper understating of the chemical and physical properties of hydrogen-based superconductors, while setting clear paths for chemically engineering their critical temperatures.

Thermodynamic of the charged AdS black holes in Rastall gravity: P − V critical and Joule–Thomson expansion

2020 ◽  
Vol 35 (14) ◽  
pp. 2050113
Author(s):  
Sen Guo ◽  
Yan Han ◽  
Guo Ping Li
Keyword(s):  
Black Holes ◽  
Black Hole ◽  
Critical Temperature ◽  
Critical Exponents ◽  
State Equation ◽  
The State ◽  
Thermodynamic Quantities ◽  
Critical Temperatures ◽  
Ads Black Holes ◽  
And Inversion

In this paper, we study the thermodynamic of the charged AdS black holes in Rastall gravity. Firstly, the thermodynamic quantities of the charged AdS black holes in Rastall gravity are reviewed and the state equation of this black hole is obtained. Then, we investigate the [Formula: see text] critical and the Joule–Thomson expansion of the charged AdS black holes in Rastall gravity in which the critical temperature and the critical exponents are obtained. In addition, we get the inversion temperature and plot the isenthalpic and inversion curves in the [Formula: see text] plane, and also determine the cooling-heating regions of this black hole through the Joule–Thomson expansion. Finally, we investigate the ratio between the minimum inversion and critical temperatures, and find that the Rastall constant [Formula: see text] does not affect of this ratio.

scholarly journals PULSATION FREQUENCY OF THE ADVISCERAL AND ABVISCERAL HEART BEATS OF CIONA INTESTINALIS IN RELATION TO TEMPERATURE

1932 ◽  
Vol 16 (1) ◽  
pp. 89-98 ◽  
Author(s):  
Ernst Wolf
Keyword(s):  
Critical Temperature ◽  
Arrhenius Equation ◽  
Ciona Intestinalis ◽  
Pulsation Frequency ◽  
Critical Temperatures ◽  
Temperature Characteristics ◽  
Metabolic Condition ◽  
Controlling Processes

The frequency of pulsation of the heart of Ciona intestinalis increases with temperature in both advisceral and abvisceral direction, according to the Arrhenius equation. The increase in pulsation is the same in both directions. The following µ values were obtained: 8,000–, 12,000+, 16,000, in several combinations, with critical temperatures at 10°, 15°, and 20°C. The values found are comparable with earlier findings for activity of the heart in different animals. This quantitative correspondence suggests anew the conception that temperature characteristics may be employed for recognition of controlling processes. The fact that the µ's and the critical temperature are the same for advisceral and abvisceral beats, indicates that the general metabolic condition of the two ends of the heart is the same in any one individual.

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