A novel chiral auxiliary from chiral spiranes. cis,cis-(+)- and (–)-spiro[4.4]nonane-1,6-diol as chiral modifier in lithium aluminium hydride reduction of phenyl alkyl ketones

1992 ◽  
Vol 0 (6) ◽  
pp. 493-494 ◽  
Author(s):  
Nivedita Srivastava ◽  
Alka Mital ◽  
Arvind Kumar
Keyword(s):  
Chiral Auxiliary ◽  
Lithium Aluminium Hydride ◽  
Hydride Reduction ◽  
Lithium Aluminium ◽  
Chiral Modifier

Lithium aluminium hydride reduction of some organo-sulphur compounds.

1967 ◽  
Vol 8 (11) ◽  
pp. 971-974 ◽  
Author(s):  
Kazi Abdul Latif ◽  
Paritosh Kumar Chakraborty
Keyword(s):  
Lithium Aluminium Hydride ◽  
Sulphur Compounds ◽  
Hydride Reduction ◽  
Lithium Aluminium

scholarly journals Lithium Aluminium Hydride Reduction of Pregnenolone under Conditions of Assumed Kinetic and Equilibrium Control.

1981 ◽  
Vol 35b ◽  
pp. 407-410 ◽  
Author(s):  
Stig Allenmark ◽  
Hans Borén ◽  
Bertil Samuelsson ◽  
Bertil Samuelsson ◽  
Ulrika Örn
Keyword(s):  
Lithium Aluminium Hydride ◽  
Hydride Reduction ◽  
Lithium Aluminium ◽  
Equilibrium Control

Reactions of propargyl alcohols. II. Solvent effects in the reduction of 1,1-Diphenylbut-2-yn-1-ol with lithium aluminium hydride

1977 ◽  
Vol 30 (4) ◽  
pp. 865 ◽  
Author(s):  
MP Hartshorn ◽  
RS Thompson ◽  
J Vaughan
Keyword(s):  
Solvent Effects ◽  
Diisopropyl Ether ◽  
Lithium Aluminium Hydride ◽  
Hydride Reduction ◽  
Lithium Aluminium ◽  
Tetrahydrofuran Solution ◽  
Propargyl Alcohols

Lithium aluminium hydride reduction of 1,1-diphenylbut-2-yn-1-ol in diethyl or diisopropyl ether gave 1,1-diphenylbuta-1,2-diene (4) and the (Z)- and (E)-1,1-diphenylbut-2-en-1-ols (5) and (6), but reaction in tetrahydrofuran solution gave only the (E)-alkenol (6).

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