Stereoselective synthesis of 2,3-disubstituted indoline, pyrrolidine and cyclic ether-fused 1,2-dihydroquinoline derivatives using alkyne iminium ion cyclization of vinylogous carbamates: switch of regioselectivity using an internal hydroxy group as a nucleophile

TMSOTf promoted alkyne iminium ion cyclization of vinylogous carbamates gives stereoselective access to indolines, pyrrolidines and dihydroquinolines.