Spin switching in tris(8-aminoquinoline)iron(ii)(BPh4)2: quantitative guest-losing dependent spin crossover properties and single-crystal-to-single-crystal transformation

Feng-Lei Yang; Xin Chen; Wen-Hao Wu; Jing-Hang Zhang; Xiang-Mei Zhao; Yan-Hui Shi; Fei Shen

doi:10.1039/c8dt03584a

Spin switching in tris(8-aminoquinoline)iron(ii)(BPh4)2: quantitative guest-losing dependent spin crossover properties and single-crystal-to-single-crystal transformation

Dalton Transactions ◽

10.1039/c8dt03584a ◽

2019 ◽

Vol 48 (1) ◽

pp. 231-241 ◽

Cited By ~ 8

Author(s):

Feng-Lei Yang ◽

Xin Chen ◽

Wen-Hao Wu ◽

Jing-Hang Zhang ◽

Xiang-Mei Zhao ◽

...

Keyword(s):

Single Crystal ◽

Spin Crossover ◽

Crystal Transformation ◽

Spin Switching

Compound tris(8-aminoquinoline)Fe(ii)(BPh4)2·2(MeCN) displayed quantitative spin crossover properties with further occurrence of single-crystal-to-single-crystal transformation.

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Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

Journal of Materials Chemistry C ◽

10.1039/d1tc00470k ◽

2021 ◽

Vol 9 (15) ◽

pp. 5082-5087

Author(s):

Yu Gong ◽

Wang-Kang Han ◽

Hui-Shu Lu ◽

Qing-Tao Hu ◽

Huan Tu ◽

...

Keyword(s):

Magnetic Properties ◽

Single Crystal ◽

Coordination Polymers ◽

Ligand Exchange ◽

Spin Crossover ◽

Metal Organic Frameworks ◽

Crystal Transformation ◽

Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

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Water molecule induced reversible single-crystal-to-single-crystal transformation between two trinuclear Fe(ii) complexes with different spin crossover behaviour

Dalton Transactions ◽

10.1039/c8dt00318a ◽

2018 ◽

Vol 47 (12) ◽

pp. 4307-4314 ◽

Cited By ~ 13

Author(s):

Wen-Bin Chen ◽

Yan-Cong Chen ◽

Meng Yang ◽

Ming-Liang Tong ◽

Wen Dong

Keyword(s):

Water Molecule ◽

Single Crystal ◽

Spin Crossover ◽

Crystal Transformation

Water molecule induced reversible single-crystal-to-single-crystal transformation between two trinuclear Fe(ii) complexes with different spin crossover behaviour.

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A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

Chemical Communications ◽

10.1039/c9cc09063k ◽

2020 ◽

Vol 56 (1) ◽

pp. 133-136

Author(s):

Xiao-Peng Sun ◽

Zheng Tang ◽

Zi-Shuo Yao ◽

Jun Tao

Keyword(s):

Single Crystal ◽

Spin State ◽

Spin Crossover ◽

Crystal Transformation ◽

State Switching ◽

One Step ◽

3D Framework

A homochiral 3D mechanically interlocked framework based on 1D loops is presented, which shows reversible single-crystal-to-single-crystal transformation and enables the interconversion between one-step and two-step spin crossover behaviors.

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Single-crystal-to-single-crystal transformation in hydrogen-bond-induced high-spin pseudopolymorphs from protonated cation salts with a π-extended spin crossover Fe(III) complex anion

Polyhedron ◽

10.1016/j.poly.2017.03.046 ◽

2017 ◽

Vol 136 ◽

pp. 170-175 ◽

Cited By ~ 2

Author(s):

Suguru Murata ◽

Kazuyuki Takahashi ◽

Takahiro Sakurai ◽

Hitoshi Ohta

Keyword(s):

Hydrogen Bond ◽

Single Crystal ◽

High Spin ◽

Spin Crossover ◽

Complex Anion ◽

Crystal Transformation ◽

Protonated Cation

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Spin-Crossover FeII4 Squares: Two-Step Complete Spin Transition and Reversible Single-Crystal-to-Single-Crystal Transformation

Angewandte Chemie ◽

10.1002/ange.201103648 ◽

2011 ◽

Vol 123 (38) ◽

pp. 9102-9105 ◽

Cited By ~ 25

Author(s):

Rong-Jia Wei ◽

Qian Huo ◽

Jun Tao ◽

Rong-Bin Huang ◽

Lan-Sun Zheng

Keyword(s):

Single Crystal ◽

Spin Crossover ◽

Spin Transition ◽

Crystal Transformation

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Reversible on–off switching of both spin crossover and single-molecule magnet behaviours via a crystal-to-crystal transformation

Chemical Science ◽

10.1039/c8sc02774a ◽

2018 ◽

Vol 9 (41) ◽

pp. 7986-7991 ◽

Cited By ~ 34

Author(s):

Dong Shao ◽

Le Shi ◽

Lei Yin ◽

Bao-Lin Wang ◽

Zhen-Xing Wang ◽

...

Keyword(s):

Single Crystal ◽

Single Molecule ◽

Spin Crossover ◽

Single Molecule Magnet ◽

Crystal Transformation

A molecule complex exhibiting reversible on–off switching between spin crossover and single-molecule magnet behaviours via a single-crystal-to-single-crystal transformation is reported.

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Spin-Crossover FeII4 Squares: Two-Step Complete Spin Transition and Reversible Single-Crystal-to-Single-Crystal Transformation

Angewandte Chemie International Edition ◽

10.1002/anie.201103648 ◽

2011 ◽

Vol 50 (38) ◽

pp. 8940-8943 ◽

Cited By ~ 104

Author(s):

Rong-Jia Wei ◽

Qian Huo ◽

Jun Tao ◽

Rong-Bin Huang ◽

Lan-Sun Zheng

Keyword(s):

Single Crystal ◽

Spin Crossover ◽

Spin Transition ◽

Crystal Transformation

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Single crystal-to-single crystal transformation – from two distinct to three distinct spin crossover centers in 2D coordination polymer [Fe(bbtr)3](CF3SO3)2

Dalton Transactions ◽

10.1039/d1dt03578a ◽

2021 ◽

Author(s):

Robert Bronisz ◽

Maria Książek ◽

Joachim Kusz ◽

Marek Damian Weselski

Keyword(s):

Coordination Polymer ◽

Single Crystal ◽

Crystal Lattice ◽

Spin Crossover ◽

Triazole Ring ◽

Two Dimensional ◽

Crystal Transformation

1,4-di(1,2,3-triazol-1-yl)butane (bbtr) forms two-dimensional (2D) coordination polymer (1) in the reaction with iron(II) triflate. In the crystal lattice there are two crystallographically unique iron(II) ions surrounded octahedrally by 1,2,3-triazole ring...

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Spin crossover and reversible single-crystal to single-crystal transformation behaviour in two cyanide-bridged mixed-valence {FeIII2FeII2} clusters

Dalton Transactions ◽

10.1039/c6dt03436e ◽

2016 ◽

Vol 45 (43) ◽

pp. 17254-17263 ◽

Cited By ~ 23

Author(s):

Chunyang Zheng ◽

Juping Xu ◽

Feng Wang ◽

Jun Tao ◽

Dongfeng Li

Keyword(s):

Transition Temperature ◽

Single Crystal ◽

Spin Crossover ◽

Mixed Valence ◽

Transformation Behaviour ◽

Crystal Transformation

Two mixed-valence {FeIII2FeII2} clusters exhibit spin crossover behaviour, in which a distorted {Fe4(μ-CN)4} core and deviations of bent ∠Fe−NC angles play a key role in tuning the transition temperature.

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