A low-loading Ru-rich anode catalyst for high-power anion exchange membrane fuel cells

2020 ◽  
Vol 56 (42) ◽  
pp. 5669-5672
Author(s):  
Zhanna Tatus-Portnoy ◽  
Anna Kitayev ◽  
Thazhe Veettil Vineesh ◽  
Ervin Tal-Gutelmacher ◽  
Miles Page ◽  
...  

Herein, we report a Ru-rich anode catalyst for alkaline exchange membrane fuel cells. At 80 °C, a fuel cell with a RuPdIr/C anode and Ag based cathode attained a peak power density close to 1 W cm−2 with 0.2 mg cm−2 anode loading in comparison to 0.77 W cm−2 for the cell tested with the same metal loading of Pt.

2015 ◽  
Vol 3 (4) ◽  
pp. 1410-1416 ◽  
Author(s):  
L. Zeng ◽  
T. S. Zhao ◽  
L. An

The use of supportless Ag NWs enabled the H2/O2 AEMFC to yield a peak power density of 164 mW cm−2.


2020 ◽  
Vol 3 (10) ◽  
pp. 10209-10214 ◽  
Author(s):  
Hamish A. Miller ◽  
Maria V. Pagliaro ◽  
Marco Bellini ◽  
Francesco Bartoli ◽  
Lianqin Wang ◽  
...  

2014 ◽  
Vol 6 (16) ◽  
pp. 13330-13333 ◽  
Author(s):  
Xiaoming Ren ◽  
Samuel C. Price ◽  
Aaron C. Jackson ◽  
Natalie Pomerantz ◽  
Frederick L. Beyer

RSC Advances ◽  
2017 ◽  
Vol 7 (31) ◽  
pp. 19153-19161 ◽  
Author(s):  
Xueqiang Gao ◽  
Hongmei Yu ◽  
Jia Jia ◽  
Jinkai Hao ◽  
Feng Xie ◽  
...  

The anion exchange ionomer incorporated into the electrodes of an anion exchange membrane fuel cell (AEMFC) enhances anion transport in the catalyst layer of the electrode, and thus improves performance and durability of the AEMFC.


2007 ◽  
Vol 60 (7) ◽  
pp. 528 ◽  
Author(s):  
Jason M. Tang ◽  
Kurt Jensen ◽  
Wenzhen Li ◽  
Mahesh Waje ◽  
Paul Larsen ◽  
...  

A simple and promising fuel-cell architecture is demonstrated using a carbon nanotube free-standing membrane (CNTFSM) made from Pt supported on purified single-walled carbon nanotubes (Pt/SWNT), which act as the catalyst layer in a hydrogen proton exchange membrane fuel cell without the need for Nafion in the catalyst layer. The CNTFSM made from Pt/SWNT at a loading of 0.082 mg Pt cm–2 exhibits higher performance with a peak power density of 0.675 W cm–2 in comparison with a commercially available E-TEK electrocatalyst made of Pt supported on XC-72 carbon black, which had a peak power density of 0.395 W cm–2 at a loading of 0.084 mg Pt cm–2 also without Nafion in the catalyst layer.


Chemija ◽  
2018 ◽  
Vol 29 (4) ◽  
Author(s):  
Aldona Balčiūnaitė ◽  
Zita Sukackienė ◽  
Loreta Tamašauskaitė-Tamašiūnaitė ◽  
Rimantas Vaitkus ◽  
Eugenijus Norkus

The electroless deposition and galvanic displacement methods were used for the fabrication of cobalt–boron (CoB) catalysts modified with small amounts of platinum crystallites in the range of 9.8 to 14.4 μgPt cm–2. The prepared catalysts were studied as the anode materials for direct borohydride–hydrogen peroxide (NaBH4/H2O2) fuel cells at temperatures of 25–55°C. Polarization curves have been recorded with the aim to evaluate the fuel cell performance using the prepared CoB and that modified with Pt crystallites as the anode catalysts. For all catalysts (pure CoB and PtCoB) investigated, the peak power density values increase consecutively with the increment in temperature from 25°C up to 55°C. The values from 86–146 mV cm–2 and 146–234 mV cm–2 were determined for pure CoB and PtCoB catalysts, respectively. The highest specific peak power density of 21.5 kWgPt–1 was achieved at 55°C temperature when the PtCoB catalyst with the Pt loading of 9.8 μgPtcm–2 was employed as the anode catalyst in the NaBH4/H2O2 single fuel cell.


Energies ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 582 ◽  
Author(s):  
Van Men Truong ◽  
Julian Richard Tolchard ◽  
Jørgen Svendby ◽  
Maidhily Manikandan ◽  
Hamish A. Miller ◽  
...  

The development of active hydrogen oxidation reaction (HOR) and oxygen reduction reaction (ORR) catalysts for use in anion exchange membrane fuel cells (AEMFCs), which are free from platinum group metals (PGMs), is expected to bring this technology one step closer to commercial applications. This paper reports our recent progress developing HOR Pt-free and PGM-free catalysts (Pd/CeO2 and NiCo/C, respectively), and ORR PGM-free Co3O4 for AEMFCs. The catalysts were prepared by different synthesis techniques and characterized by both physical-chemical and electrochemical methods. A hydrothermally synthesized Co3O4 + C composite ORR catalyst used in combination with Pt/C as HOR catalyst shows good H2/O2 AEMFC performance (peak power density of ~388 mW cm−2), while the same catalyst coupled with our flame spray pyrolysis synthesised Pd/CeO2 anode catalysts reaches peak power densities of ~309 mW cm−2. Changing the anode to nanostructured NiCo/C catalyst, the performance is significantly reduced. This study confirms previous conclusions, that is indeed possible to develop high performing AEMFCs free from Pt; however, the challenge to achieve completely PGM-free AEMFCs still remains.


RSC Advances ◽  
2021 ◽  
Vol 11 (50) ◽  
pp. 31477-31486
Author(s):  
Dominik Seeberger ◽  
Pascal Hauenstein ◽  
Adrian Hartert ◽  
Simon Thiele

The AEM layer content in a bipolar interface fuel cell enables the opportunity to regulate the influx rate of water into the porous layer.


Sign in / Sign up

Export Citation Format

Share Document