scholarly journals Efficient electrochemical synthesis of a manganese-based metal–organic framework for H2 and CO2 uptake

2021 ◽  
Vol 23 (3) ◽  
pp. 1220-1227
Author(s):  
Aisha Asghar ◽  
Naseem Iqbal ◽  
Tayyaba Noor ◽  
Benson M. Kariuki ◽  
Luke Kidwell ◽  
...  

Electrochemical synthesis, from manganese strips and dissolved linker, of a new amine-containing manganese-based metal–organic framework with enhanced CO2 uptake.

2017 ◽  
Vol 301 ◽  
pp. 125-132 ◽  
Author(s):  
Feng Zhang ◽  
Tingting Zhang ◽  
Xiaoqin Zou ◽  
Xiaoqiang Liang ◽  
Guangshan Zhu ◽  
...  

2019 ◽  
Vol 3 (12) ◽  
pp. 2759-2767 ◽  
Author(s):  
Jong Hyeak Choe ◽  
Dong Won Kang ◽  
Minjung Kang ◽  
Hyojin Kim ◽  
Jeoung Ryul Park ◽  
...  

Heavily tetraethylenepentamine (tepa)-functionalized Mg2(dobpdc) showed an unusual increase in CO2 uptake on increasing the temperature and selective adsorption of CO2 over water vapors.


2012 ◽  
Vol 3 (10) ◽  
pp. 2993 ◽  
Author(s):  
Wenbin Yang ◽  
Andrew J. Davies ◽  
Xiang Lin ◽  
Mikhail Suyetin ◽  
Ryotaro Matsuda ◽  
...  

Nanomaterials ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 1063 ◽  
Author(s):  
Aisha Asghar ◽  
Naseem Iqbal ◽  
Tayyaba Noor ◽  
Majid Ali ◽  
Timothy L. Easun

Herein we report a facile, efficient, low cost, and easily scalable route for an amine-functionalized MOF (metal organic framework) synthesis. Cu-BDC⊃HMTA (HMTA = hexamethylenetetramine) has high nitrogen content and improved thermal stability when compared with the previously reported and well-studied parent Cu-BDC MOF (BDC = 1,4-benzenedicarboxylate). Cu-BDC⊃HMTA was obtained via the same synthetic method, but with the addition of HMTA in a single step synthesis. Thermogravimetric studies reveal that Cu-BDC⊃HMTA is more thermally stable than Cu-BDC MOF. Cu-BDC⊃HMTA exhibited a CO2 uptake of 21.2 wt % at 273 K and 1 bar, which compares favorably to other nitrogen-containing MOF materials.


CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6287-6290 ◽  
Author(s):  
Mingxing Zhang ◽  
Qian Wang ◽  
Zhiyong Lu ◽  
Huiyan Liu ◽  
Wenlong Liu ◽  
...  

A nitro-decorated and highly porous metal–organic framework with NbO topology was reported, exhibiting good adsorption selectivity of CO2/CH4 (8) and CO2/N2 (24) at 273 K and 1 bar, high methane total uptake of 184 cm3 cm−3 at 290 K and 35 bar.


Sign in / Sign up

Export Citation Format

Share Document