Serendipitous isolation of a triazinone-based air stable organic radical: synthesis, crystal structure, and computation

New Journal of Chemistry ◽

10.1039/d0nj02028a ◽

2020 ◽

Vol 44 (26) ◽

pp. 10781-10785

Author(s):

Vedichi Madhu ◽

Arun Kumar Kanakati ◽

Samar K. Das

Keyword(s):

Crystal Structure ◽

Radical Cation ◽

Organic Radical ◽

Radical Cation Salt ◽

Isolation And Characterization

Here we report the synthesis, isolation, and characterization of a dication salt, namely 4,6-bis(4,4′-bipyridinium)-1,3,5-triazin-2-one {12+(PF6)22−·2H2O1(PF6)2·2H2O}, and its radical cation salt, namely 4,6-bis(4,4′-bipyridinium)-1,3,5-triazin-2-one (1+˙PF6−1˙PF6).

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Crystal Structure and Magnetic Properties of Organic Radical Cation Salt, α-(Benzo[1,2-d:4,5-d′]bis[1,3,2]dithiazole)2ReBr6

Chemistry Letters ◽

10.1246/cl.2010.1096 ◽

2010 ◽

Vol 39 (10) ◽

pp. 1096-1098 ◽

Author(s):

Ken-ichi Suzuki ◽

Takeshi Kodama ◽

Koichi Kikuchi ◽

Wataru Fujita

Keyword(s):

Crystal Structure ◽

Magnetic Properties ◽

Radical Cation ◽

Organic Radical ◽

Radical Cation Salt

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S · · · S Contact-assembled tetrathiafulvalene derivatives of copper(I) and silver(I) co-ordination polymers and organic radical cation salt

Journal of the Chemical Society Dalton Transactions ◽

10.1039/a804945i ◽

1998 ◽

pp. 3255-3262 ◽

Author(s):

Liang Ping Wu ◽

Jie Dai ◽

Megumu Munakata ◽

-Masahiko Maekawa ◽

Yusaku Suenaga ◽

...

Keyword(s):

Radical Cation ◽

Organic Radical ◽

Radical Cation Salt ◽

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Isolation and characterization of a novel multibridged tetradentate dianionic form of pyridoxic acid. Crystal structure of tetranuclear [Cu4(PAA)2(Bipyam)4(H2O)2Cl2](NO3)2·CH3OH·10H2O

10.1016/s0277-5387(00)86190-2 ◽

1991 ◽

Vol 10 (23-24) ◽

pp. 2851-2853 ◽

Author(s):

Irimpan I. Mathews ◽

Hattikudur Manohar

Keyword(s):

Crystal Structure ◽

Acid Crystal ◽

Isolation And Characterization ◽

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Crystal structure and physical properties of radical cation salt based on 4,5-ethylenedioxy-4′-iodotetrathiafulvalene (EDO-TTF-I) with iodine bonding ability

Materials Chemistry Frontiers ◽

10.1039/c7qm00575j ◽

2018 ◽

Vol 2 (4) ◽

pp. 752-759 ◽

Author(s):

Yoshiaki Nakano ◽

Yusuke Takahashi ◽

Kohdai Ishida ◽

Manabu Ishikawa ◽

Hideki Yamochi ◽

...

Keyword(s):

Crystal Structure ◽

Physical Properties ◽

Radical Cation ◽

Radical Cation Salt ◽

Molecular Arrangement

The radical cation salt of 4,5-ethylenedioxy-4′-iodotetrathiafulvalene possessing iodine bonding ability afforded the β′-type molecular arrangement in dimerized Mott insulating state.

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ChemInform Abstract: Chemistry of Organosilicon Compounds. Part 256. Isolation and Characterization of 1,2-Dilithio(tetrakis(trimethylsilyl))ethane. The First Crystal Structure of Nonconjugated 1,2-Dilithioethane.

10.1002/chin.198933249 ◽

1989 ◽

Vol 20 (33) ◽

Author(s):

A. SEKIGUCHI ◽

T. NAKANISHI ◽

C. KABUTO ◽

H. SAKURAI

Keyword(s):

Crystal Structure ◽

Organosilicon Compounds ◽

Isolation And Characterization

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Hydrogen Bonding and Sulfur–Sulfur Interactions in the Crystal Structure of the Radical-Cation Salt (BPDT-TTF)2[W6O19]

Journal of Chemical Crystallography ◽

10.1007/s10870-009-9521-4 ◽

2009 ◽

Vol 39 (10) ◽

pp. 723-729 ◽

Author(s):

Eric W. Reinheimer ◽

Marc Fourmigué ◽

Kim R. Dunbar

Keyword(s):

Crystal Structure ◽

Hydrogen Bonding ◽

Radical Cation ◽

Radical Cation Salt

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Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with tertiary phosphine and phosphite ligands. The isolation and characterization of the 1:1 adducts Re2X4(dppm)2(PR3) and Re2Cl4(dppm)2[P(OR)3] and the crystal structure of [Re2Cl3(dppm)2(NCEt)2]PF6

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)80451-x ◽

1990 ◽

Vol 172 (1) ◽

pp. 65-71 ◽

Author(s):

Phillip E. Fanwick ◽

Qi Ju-Sheng ◽

Shih Keng-Yu ◽

Richard A. Walton

Keyword(s):

Crystal Structure ◽

Tertiary Phosphine ◽

Isolation And Characterization ◽

Phosphite Ligands

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Isolation and characterization of the first bis(2-pyridyl)carbyltitanium(iv) complex derived from the C–O bond cleavage of the alkoxide ligand in CpTiMe2(OCMePy2). X-Ray crystal structure of [CpTi(μ-O)(CMePy2)]2 (Cp* = C5Me5)

Journal of the Chemical Society Dalton Transactions ◽

10.1039/b106481a ◽

2002 ◽

pp. 11 ◽

Author(s):

Rosa Fandos ◽

Carolina Hernández ◽

Antonio Otero ◽

Ana Rodríguez ◽

Maria José Ruiz ◽

...

Keyword(s):

Crystal Structure ◽

Bond Cleavage ◽

X Ray ◽

Isolation And Characterization ◽

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Isolation and characterization of the pyridazine (pydz) bridged halogenotrimethylplatinum(IV) complexes [PtXMe3)2(μ-pydz)] (X = Cl, Br, I). X-ray crystal structure of [(PtIMe3)2(μ-pydz)]

10.1016/s0277-5387(00)83090-9 ◽

1994 ◽

Vol 13 (17) ◽

pp. 2501-2505 ◽

Author(s):

Edward W. Abel ◽

Peter J. Heard ◽

Keith G. Orrell ◽

Michael B. Hursthouse ◽

K.M. Abdul Malik

Keyword(s):

Crystal Structure ◽

X Ray ◽

Isolation And Characterization

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Isolation and Characterization of Phenyl Viologen as a Radical Cation and Neutral Molecule

The Journal of Organic Chemistry ◽

10.1021/jo050328g ◽

2005 ◽

Vol 70 (13) ◽

pp. 5028-5035 ◽

Author(s):

William W. Porter ◽

Thomas P. Vaid

Keyword(s):

Radical Cation ◽

Neutral Molecule ◽

Isolation And Characterization

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