Room temperature HFIP/Ag-Promoted Palladium-Catalyzed C─H Functionalization of Benzothiazole with Iodoarenes

2022 ◽  
Author(s):  
Anant R. Kapdi ◽  
Santosh J Gharpure ◽  
SaiDurga Prasad Kommyreddy ◽  
Santosh Kori ◽  
Yuvraj Bhujbal ◽  
...  
Keyword(s):  
Room Temperature ◽  
Direct Arylation ◽  
Palladium Catalyzed

A versatile synthetic protocol involving the room temperature direct arylation of benzothiazole with a wide variety of iodoarenes under Ag-promoted Pd-catalyzed conditions in HFIP as the reaction solvent has been...

scholarly journals Room temperature Palladium-Catalyzed C─H Functionalization of Benzothiazole with Iodo(Hetero)Arenes

2020 ◽  
Author(s):  
Yuvraj Bhujbal ◽  
kamlesh vadagaonkar ◽  
santosh kori ◽  
Anant Kapdi
Keyword(s):  
Room Temperature ◽  
Antitumor Agent ◽  
One Pot ◽  
Direct Arylation ◽  
Palladium Catalyzed

A versatile synthetic protocol involving the room temperature direct arylation of benzothiazole with a wide variety of iodo(hetero)arenes under palladium-catalyzed conditions and promoted by HFIP as the reaction solvent has been presented herewith. An in-situ one-pot sequential HFIP promoted selective iodination of (hetero)arenes followed by Pd-catalyzed direct arylation of benzothiazole has also been disclosed. Synthesis of PMX 610 (antitumor agent) analog has been disclosed and also CJM 126 (antitumor agent) has been synthesized.

scholarly journals Room temperature Palladium-Catalyzed C─H Functionalization of Benzothiazole with Iodo(Hetero)Arenes

2020 ◽  
Author(s):  
Yuvraj Bhujbal ◽  
kamlesh vadagaonkar ◽  
santosh kori ◽  
Anant Kapdi
Keyword(s):  
Room Temperature ◽  
Antitumor Agent ◽  
One Pot ◽  
Direct Arylation ◽  
Palladium Catalyzed

A versatile synthetic protocol involving the room temperature direct arylation of benzothiazole with a wide variety of iodo(hetero)arenes under palladium-catalyzed conditions and promoted by HFIP as the reaction solvent has been presented herewith. An in-situ one-pot sequential HFIP promoted selective iodination of (hetero)arenes followed by Pd-catalyzed direct arylation of benzothiazole has also been disclosed. Synthesis of PMX 610 (antitumor agent) analog has been disclosed and also CJM 126 (antitumor agent) has been synthesized.

Water-Soluble Imine Ligand/Palladium-Catalyzed Suzuki Reaction at Room Temperature

2010 ◽  
Vol 31 (10) ◽  
pp. 1277-1280
Author(s):  
Chun LIU ◽  
Qijian NI ◽  
Pingping HU ◽  
Hao YUAN ◽  
Zilin JIN
Keyword(s):  
Room Temperature ◽  
Suzuki Reaction ◽  
Water Soluble ◽  
Palladium Catalyzed

scholarly journals Palladium-catalyzed direct arylation and cyclization of o-iodobiaryls to a library of tetraphenylenes

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Chendan Zhu ◽  
Yue Zhao ◽  
Di Wang ◽  
Wei-Yin Sun ◽  
Zhuangzhi Shi
Keyword(s):  
Direct Arylation ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Direct Arylation of Thiophenes Bearing SO2R Substituents.

ChemInform ◽  
2011 ◽  
Vol 42 (49) ◽  
pp. no-no
Author(s):  
Charles Beromeo Bheeter ◽  
Jitendra K. Bera ◽  
Henri Doucet
Keyword(s):  
Direct Arylation ◽  
Palladium Catalyzed

Palladium-Catalyzed Mono-α-arylation of Acetone at Room Temperature

2015 ◽  
Vol 21 (31) ◽  
pp. 11006-11009 ◽  
Author(s):  
Preston M. MacQueen ◽  
Alicia J. Chisholm ◽  
Breanna K. V. Hargreaves ◽  
Mark Stradiotto
Keyword(s):  
Room Temperature ◽  
Palladium Catalyzed

Palladium-catalyzed Mizoroki–Heck-type reactions of [Ph2SRfn][OTf] with alkenes at room temperature

2016 ◽  
Vol 52 (80) ◽  
pp. 11893-11896 ◽  
Author(s):  
Shi-Meng Wang ◽  
Hai-Xia Song ◽  
Xiao-Yan Wang ◽  
Nan Liu ◽  
Hua-Li Qin ◽  
...  
Keyword(s):  
Room Temperature ◽  
Cross Coupling ◽  
Palladium Catalyzed

The first Pd-catalyzed Mizoroki–Heck-type cross-coupling of phenylsulfonium salts with alkenes was disclosed at room temperature.

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