scholarly journals Rational design of zwitterionic porous organic framework loading Co (II) ions to host sulfur and synergistically boost polysulfides redox kinetics for lithium sulfur batteries

2022 ◽  
Author(s):  
Miao Sun ◽  
Gaojie Yan ◽  
Haifeng Ji ◽  
Yi Feng ◽  
Xiaojie Zhang ◽  
...  

In the development of lithium-sulfur batteries (LiSBs), the irreversible volume changes, annoying shuttle effect and slow conversion kinetics of lithium polysulfides (LiPSs) are main obstacles for further commercialization. Therefore, a...

2019 ◽  
Vol 55 (22) ◽  
pp. 3243-3246 ◽  
Author(s):  
Yaxi Tian ◽  
Huawen Huang ◽  
Guoxue Liu ◽  
Ran Bi ◽  
Lei Zhang

A yolk–shell NiS2/C–S cathode exhibits enhanced electrochemical performances in lithium–sulfur batteries due to the improved redox kinetics of polysulfide confined within the yolk–shell structure.


Author(s):  
Zhihao Wang ◽  
zhihao zeng ◽  
Wei Nong ◽  
Zhen Yang ◽  
Chenze Qi ◽  
...  

Lithium sulfur battery is one of the most promising applicants for the next generation of energy storage devices whose commercial applications are impeded by the key issue of shuttle effect....


2018 ◽  
Vol 6 (35) ◽  
pp. 17132-17141 ◽  
Author(s):  
Wenlong Huang ◽  
Zejing Lin ◽  
Huitian Liu ◽  
Ren Na ◽  
Jianhua Tian ◽  
...  

Cobalt phthalocyanine as a novel electrocatalyst enhances the redox kinetics of polysulfide species effectively for lithium–sulfur batteries.


2022 ◽  
Author(s):  
Fengfeng Han ◽  
Qi Jin ◽  
Junpeng Xiao ◽  
Lili Wu ◽  
Xitian Zhang

Lithium–sulfur batteries (LBSs) have potential to become the future energy storage system, yet they are plagued by the sluggish redox kinetics. Therefore, enhancing the redox kinetics of polysulfide is a...


2019 ◽  
Vol 7 (11) ◽  
pp. 6507-6513 ◽  
Author(s):  
Jianjun Song ◽  
Xin Guo ◽  
Jinqiang Zhang ◽  
Yi Chen ◽  
Chaoyue Zhang ◽  
...  

A Ti3C2Tx MXene/rGO hybrid aerogel is applied for the first time as a free-standing polysulfide reservoir to inhibit the shuttle effect and improve the overall performance of Li–S batteries.


2021 ◽  
Author(s):  
Ning Zhang ◽  
Shuangshuang Zheng ◽  
Menglong Zhao ◽  
Yang Lu ◽  
Jinbing Cheng ◽  
...  

The lithium polysulfides (LiPSs) shuttle effect and low redox kinetics is the key problem that hinders the performance improvement and prevents the achievement of commercial requirement for lithium-sulfur batteries (LSBs),...


Nanoscale ◽  
2021 ◽  
Author(s):  
Ke Wang ◽  
Teng Zhao ◽  
Nanxiang Zhang ◽  
Tao Feng ◽  
Li Li ◽  
...  

Sulfurized polyacrylonitrile (SPAN) is a promising cathode material for stable lithium-sulfur (Li-S) batteries due to its shuttle-free redox mechanism. However, the redox kinetics of SPAN needs to be enhanced to...


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