Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

Sulfonyl esters 6. Elucidation of the first sequence in the Trithioorthoformate Reaction

1995 ◽  
Vol 73 (3) ◽  
pp. 444-452 ◽  
Author(s):  
James Clayton Baum ◽  
Bradley Eugene Black ◽  
Laura Precedo ◽  
John Edward Goehl ◽  
Richard Francis Langler
Keyword(s):  
Electron Transfer ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Computational Results ◽  
One Pot ◽  
The One ◽  
Sulfonate Ester

The one-pot conversion of a mercaptan and an aryl methanesulfonate into a trithioorthoformate is described. The intermediacy of a sulfide-sulfonate ester is firmly established. Experimental and computational results permit the formulation of a possible pathway for the formation of the intermediate sulfide-sulfonate ester. Keywords: single electron transfer, sulfonate esters, sulfide-sulfonate esters.

Sulfonyl esters 7. The second and third sequences in the Trithioorthoformate Reaction

1996 ◽  
Vol 74 (9) ◽  
pp. 1638-1648 ◽  
Author(s):  
Kashyapa Ananda Ginige ◽  
John Edward Goehl ◽  
Richard Francis Langler
Keyword(s):  
Electron Transfer ◽  
Key Words ◽  
Single Electron ◽  
Single Electron Transfer ◽  
One Pot ◽  
The One ◽  
Sulfonate Ester

A previous report has established the intermediacy of a sulfide-sulfonate ester in the one-pot conversion of an aryl mercaptan and a sulfonate ester into the corresponding trithioorthoformate. This report describes evidence for the sequential intermediacy of a bissulfide-sulfonate ester and a dithiosulfène in the conversion of the sulfide-sulfonate ester into the trithioorthoformate. A new sulfonate ester is shown to give the highest yield of trithioorthoformate. Key words: single electron transfer, sulfonate esters, sulfenes.

scholarly journals Stereoselective synthesis of Gly-Gly-type (E)-methylalkene and (Z)-chloroalkene dipeptide isosteres and their application to 14-mer RGG peptidomimetics

RSC Advances ◽  
2020 ◽  
Vol 10 (49) ◽  
pp. 29373-29377
Author(s):  
Hikari Okita ◽  
Yuna Kato ◽  
Tatsuki Masuzawa ◽  
Kosuke Arai ◽  
Sayuri Takeo ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Efficient Synthesis

An efficient synthesis of Gly-Gly-type (E)-methylalkene and (Z)-chloroalkene dipeptide isosteres is realized by organocuprate-mediated single electron transfer reduction.

Applications of ytterbium(II) reagent as Grignard reagent and single electron transfer reagent in the synthesis of 3-substituted-2-oxindoles

Synthesis ◽  
2021 ◽  
Author(s):  
Pengkai Wang ◽  
yan xu cao ◽  
Songlin Zhang
Keyword(s):  
Electron Transfer ◽  
Grignard Reagent ◽  
Nucleophilic Reagent ◽  
Point Of View ◽  
Single Electron ◽  
Single Electron Transfer ◽  
One Pot ◽  
First Time ◽  
Isatin Derivatives

The utilities of ytterbium(II) reagent, both as nucleophilic reagent and single electron transfer reagent in the reaction of isatin derivatives with ytterbium(II) reagent are reported for the first time in this paper. From a synthetic point of view, a general, efficient, and experimentally simple one-pot method for preparation of 3-substituted-2-oxindoles was developed.

Visible-light-induced phenylchalcogenyl-oxygenation of allenes having aryl or electron withdrawing substituents with ambient air as a sole oxidant

2016 ◽  
Vol 14 (48) ◽  
pp. 11415-11425 ◽  
Author(s):  
Gullapalli Kumaraswamy ◽  
Swargam Vijaykumar ◽  
Kukkadapu Ankamma ◽  
Vykunthapu Narayanarao
Keyword(s):  
Electron Transfer ◽  
Visible Light ◽  
Transfer Process ◽  
Stereoselective Synthesis ◽  
Ambient Air ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Electron Transfer Process ◽  
Electron Withdrawing Substituents

The stereoselective synthesis of α-phenylselenyl- or telluryl β-aryl acrylaldehydes/ketones from aryl allenes/1,3-diarylallene by an oxidative photo-induced single electron transfer process using benign ambient air as a sole oxidant was achieved.

Sign in / Sign up

Export Citation Format

Share Document