Cu-ion induced self-polymerization of Cu phthalocyanine to prepare low-cost organic cathode materials for Li-ion batteries with ultra-high voltage and ultra-fast rate capability

Author(s):  
Haichang Zhang ◽  
Rui Zhang ◽  
Xingjiang Liu ◽  
Fei Ding ◽  
Chunsheng Shi ◽  
...  

High cost, complex synthesis routes and low yield are pressing challenges hindering the practical application of organic battery materials. Herein, copper(II) phthalocyanine (CuPc), one of the most frequently used blue...


Nanoscale ◽  
2021 ◽  
Author(s):  
Jun Cao ◽  
Haijian Huang ◽  
Yifan Qu ◽  
Weijian Tang ◽  
Zeheng Yang ◽  
...  

Lithium-rich cathode materials are considered to be promising candidate cathode materials for the next-generation Li-ion batteries owing to their high specific capacities and low cost. Nevertheless, they still suffer from...



Author(s):  
Xueyi Guo ◽  
Chenlin Yang ◽  
Jinxiu Chen ◽  
Qinghua Tian ◽  
Hongmei Zhang ◽  
...  


Author(s):  
Yun Xu ◽  
Mingyang Zhao ◽  
Syed Khalid ◽  
Hongmei Luo ◽  
Kyle S. Brinkman

The high voltage cathode material, LiMn1.6Ni0.4O4, was prepared by a polymer-assisted method. The novelty of this work is the substitution of Ni with Mn, which already exists in the crystal structure instead of other isovalent metal ion dopants which would result in capacity loss. The electrochemical performance testing including stability and rate capability was evaluated. The temperature was found to impose a change on the valence and structure of the cathode materials. Specifically, manganese tends to be reduced at a high temperature of 800 °C and leads to structural changes. The manganese substituted LiMn1.5Ni0.5O4 (LMN) has proved to be a good candidate material for Li-ion battery cathodes displaying good rate capability and capacity retention. The cathode materials processed at 550 °C showed a stable performance with negligible capacity loss for 400 cycles.



2017 ◽  
Vol 254 ◽  
pp. 50-58 ◽  
Author(s):  
Xiaobo Jia ◽  
Mo Yan ◽  
Ziyou Zhou ◽  
Xianglei Chen ◽  
Chao Yao ◽  
...  


2020 ◽  
Vol 36 (1) ◽  
pp. 24-32 ◽  
Author(s):  
Xiaobo Zhu ◽  
Tobias Schulli ◽  
Lianzhou Wang


2007 ◽  
Vol 52 (11) ◽  
pp. 3870-3875 ◽  
Author(s):  
Yukai Fan ◽  
Jianming Wang ◽  
Zheng Tang ◽  
Weichun He ◽  
Jianqing Zhang


2010 ◽  
Vol 12 (8) ◽  
pp. 1099-1102 ◽  
Author(s):  
Jang-Hoon Park ◽  
Jong-Su Kim ◽  
Eun-Gi Shim ◽  
Kyung-Won Park ◽  
Young Taik Hong ◽  
...  


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