Linear free energy relationships in the thiophen series. Part I. Leaving group effect in piperidino-substitution in methanol of some 2-L-3-nitro-5-X-thiophens

1975 ◽  
pp. 989 ◽  
Author(s):  
Domenico Spinelli ◽  
Giovanni Consiglio
Keyword(s):  
Free Energy ◽  
Linear Free Energy Relationships ◽  
Group Effect ◽  
Linear Free Energy ◽  
Leaving Group ◽  
Energy Relationships

scholarly journals Linear free energy relationships in RNA transesterification: theoretical models to aid experimental interpretations

2014 ◽  
Vol 16 (30) ◽  
pp. 15846-15855 ◽  
Author(s):  
Ming Huang ◽  
Darrin M. York
Keyword(s):  
Free Energy ◽  
Theoretical Models ◽  
Linear Free Energy Relationships ◽  
Stepwise Mechanism ◽  
Linear Free Energy ◽  
Leaving Group ◽  
Energy Relationships

Depending on the nature of the leaving group, reactions may proceedviaa stepwise mechanism or through a single early TS1. Brønsted correlations can be used to distinguish these two mechanisms.

Linear free energy relationships in CN bond dissociations in molecular ions of 4-substitutedN-(2-furylmethyl)anilines in the gas phase

2007 ◽  
Vol 42 (11) ◽  
pp. 1496-1503 ◽  
Author(s):  
Eduardo A. Solano Espinoza ◽  
Elena Stashenko ◽  
Jairo Martínez ◽  
Uriel Mora ◽  
Vladimir Kouznetsov
Keyword(s):  
Free Energy ◽  
Gas Phase ◽  
Molecular Ions ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Energy Relationships
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