Thiyl free radicals and the oxidation of ferrocytochrome c Direct observation of coupled hydrogen-atom- and electron-transfer reactions
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Absolute rate constants for the reaction of ferrocytochrome c with the thiyl radicals derived from cysteine, GSH, penicillamine and N-(2-mercaptopropionyl)glycine were measured by using the technique of pulse radiolysis. The reaction is believed to occur through a one-electron-transfer process, in agreement with the hypothesis that thiols may act as catalysts linking hydrogen-atom- and electron-transfer reactions.
1983 ◽
pp. 1133-1137
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1980 ◽
pp. 296
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2002 ◽
Vol 3
(1)
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pp. 33-42
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1983 ◽
pp. 961-965
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1992 ◽
pp. 207
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