scholarly journals Characterization of a metallic interconnect operated in stack during 40,000 hours in SOFC mode

2022 ◽  
Vol 334 ◽  
pp. 06005
Author(s):  
Paolo Piccardo ◽  
Roberto Spotorno ◽  
Valeria Bongiorno ◽  
Daniele Paravidino ◽  
Christian Geipel ◽  
...  

An SOFC stack operated for 40,000 hours has been dismantled offering the opportunity to characterize the metallic interconnect. The metal plate was carefully investigated to define the evolution of the surfaces exposed to the air and to the hydrogen electrodes respectively. The observations of the surfaces reveal the stability of the layers applied on top of the rib at the air side while in the bottom of the channels the protective coating (i.e., Co-Mn base spinel oxide) shows large crystals. The cross section allowed to highlight the formation of a rather homogeneous layer of thermal grown oxide between the metal and the coating. The average thickness of the TGO is around 11 μm. The hydrogen side shows a superficial alteration (due to the interaction with the water vapour) changing from the inlet to the outlet where it seems thinner as if the TGO further reacted by forming volatile compounds. The cross section observations confirmed the presence of a porous TGO with a rather high content of manganese in a Cr-Mn spinel oxide. Several spots testifies the zones of contact with the Ni base contacting layer. The cross section corresponding to such zones highlighted the Ni diffusion in the metal substrate.

Mechanik ◽  
2019 ◽  
Vol 92 (7) ◽  
pp. 412-414
Author(s):  
Jan Burek ◽  
Rafał Flejszar ◽  
Barbara Jamuła

The analytical and numerical model of the cross-section of the machined layer in the process of milling of concave rounding is presented. Simulation tests were carried out to determine the cross-sectional area of the cutting layer. A strategy has been developed that allows to increase the stability of the cross-section area of the cutting layer when the mill enters the inner corner area.


2021 ◽  
Author(s):  
Pilar Clariana ◽  
Ruth Soto ◽  
Conxi Ayala ◽  
Aina Margalef ◽  
Antonio Casas-Sainz ◽  
...  

<p>The characterization of the basement architecture of the Pyrenean Axial Zone, backbone of the chain, is crucial to understand its geodynamic evolution and the interplay between tectonism and magmatism. In this work, a new gravity-constrained cross section was built along the Central Pyrenees, between two of the largest Pyrenean Late Variscan granitic complexes, La Maladeta and Andorra-Mont Louis granites, to infer the geometry at depth of the basement host rocks. This cross section is ca. 65 km long and extends from the Mesozoic Bóixols basin in the South to the Late Variscan Bassiès granite to the North, close to the northern end of the Axial Zone. It is based on available geological maps, previous published works and new geological field data; together with newly acquired gravimetric stations (1141), to improve the existent spatial resolution of the gravity data from the databases of the Spanish and Catalan Geological Surveys, and density values from 65 rock samples covering all different lithologies in the cross section. Thus, its geometry at depth is constrained by means of an integrated 2.5D gravity/structural/petrophysical modelling.</p><p>The La Maladeta and Andorra-Mont Louis granites appear aligned in a WNW-ESE direction and both lie within the same Alpine basement unit, the Orri thrust sheet. They are separated about 40 km by the WNW-ESE-oriented Llavorsí syncline, formed by Devonian and Silurian rocks and limited to the north and south by south vergent thrusts. This syncline is located between two large Cambro-Ordovician anticlinorium structures, the La Pallaresa and Orri massifs to the north and south respectively, formed by a monotonous alternation of shales and sandstones with some intercalations of limestones and conglomerates affected by very low to medium grade of metamorphism. Most structures show southern vergence along the cross section, and its southern part is characterized by the occurrence of Triassic evaporites, a significant detachment level decoupling deformation between the Paleozoic basement and the Mesozoic-Cenozoic cover rocks.</p><p>The observed residual anomaly along the cross section shows a relative maximum, coinciding with the southern edge of the Axial Zone (Nogueras Zone) and southern half of the Orri massif, followed to the north by a relative large minimum. This gravity minimum in the core of the Axial Zone coincides with the northern half of the Orri massif, the Llavorsí syncline and southern half of the La Pallaresa massif and must be related at depth with rocks of lower density with respect to rocks located to the North and South. Two possible solutions have been postulated to explain the presence of lower density rocks: (i) the presence of Triassic evaporites at depth as a continuation to the North of the Triassic evaporites outcropping in the Rialp window located to the South and/or (ii) the presence of buried granitic bodies equivalent to the adjacent La Maladeta and Andorra-Mont Louis granites.</p>


Author(s):  
Leonid S. Lyakhovich ◽  
Pavel A. Akimov ◽  
Boris A. Tukhfatullin

We have already presented original criterion of minimum material consumption within the design of the outline of the width of the I-shaped bar and the stability constraints or restriction to the value of the first natu­ral frequency in one principal plane of inertia of the cross-section. This paper is devoted in its turn to a criterion for the minimum material capacity of the I-shaped bar with a variation in its thickness and outline of the width, with restrictions to the value of the critical force or restriction to the value of the first natural frequency in two principal planes of inertia of the section


2021 ◽  
Vol 879 ◽  
pp. 151-168
Author(s):  
Van Khai Nguyen ◽  
Nghia Dai Van ◽  
Van Tuong Khanh Vo ◽  
Rin Anh Nguyen ◽  
Phuc Gia Nguyen ◽  
...  

Steel bridge structure without intermediate bracing system (IBS) has been widely used in several countries and one of them is Japan. In this type of structure, the main steel girder is not reinforced by the stiffeners. The stiffness of the main girder is enhanced with steel plate directly welded to the top flange of the main girder, forming the “beams–system”. The reinforced concrete deck slab with the set of main girder and steel plate works compositely through steel shear connectors whose shape is C (channel) or I character. As for steel bridge structures, the main role of shear connectors is shear resistance between the concrete deck slab and steel girder plate in the exploitation stage. However, previous research has shown that the density of shear connectors influences on the stability as well as the stiffness of the bridge structure. Therefore, it has approved that this appurtenance is able to not only have the ability of shear resistance but also enhance the stiffness of the steel bridge structure which is particularly surveyed with the type of especial bridge structure – the steel bridge structure without IBS. Hence, the shear connectors in this kind of bridge structure are deliberately researched as an extra role in the construction stage. The following factors of the channel shape shear connectors would be researched for evaluating their impacting level on the stability of the special steel bridge structure: the properties (the length and the moment of inertia of the cross-section) and the density on the steel plate. Through the analysis of impacting level to the stability of three mentioned factors (the length and density of the shear connectors; the moment of inertia of the cross-section), the expected result is as following: 1) The minimum density of shear connectors is proposed. 2) The influence of the moment of inertia of the cross-section, the density, and the length on the stability is quite clear. 3) As for the economy, the optimal designed range among three factors is also suggested.


Genome ◽  
1992 ◽  
Vol 35 (6) ◽  
pp. 975-980 ◽  
Author(s):  
Shaoke Wang ◽  
Nora L. V. Lapitan ◽  
Marion Roder ◽  
Takumi Tsuchiya

The ends of barley chromosomes hybridize in situ to the telomeric sequences of Arabidopsis thaliana. It was confirmed that the cross-hybridizing sequences in barley are found at the absolute ends of the chromosomes by exonuclease Bal31 digestion. The Bal31 experiments also indicated that telomere-like sequences do not occur in high copies at interstitial sites in barley. To determine whether healing of broken chromosomes occurred in aneuploid lines of barley containing extra chromosomes with breakages in different parts, in situ hybridization with the A. thaliana telomere on telotrisomic 4L and acrotrisomic 4L4S lines was conducted. Telosome 4L possesses breaks in the centromere and in an interstitial location in the long arm, while acrosome 4L4S possesses interstitial breaks in both long and short arms. In situ hybridization revealed the presence of telomere sequences on both broken ends of telosome 4L and acrosome 4L4S. In telosome 4L, telomere sequences were present even at the broken site of the centromere. These results show that broken ends of barley chromosomes were healed. Such healing may explain the stability of these chromosomes through many generations.Key words: telomere, centromere, telosome, acrosome, acrotrisomic, telotrisomic.


2020 ◽  
Vol 87 (12) ◽  
pp. 777-786
Author(s):  
Thomas Junge ◽  
Thomas Mehner ◽  
Andreas Nestler ◽  
Andreas Schubert ◽  
Thomas Lampke

AbstractThe surface integrity strongly affects the performance properties of parts. Therefore, it is of great importance to be able to measure and adjust the surface-layer properties during the manufacturing process. In particular, cutting operations are characterized by high mechanical loads and temperature gradients in the area of chip formation. To enable a targeted control of the surface-layer properties, a fundamental comprehension of the interrelationships between the thermomechanical impact and the thereby induced material modification is required. Hence, the subject of this study is to measure the thermomechanical changes during turning of the aluminium alloy EN AW-2017 and find correlations thereof to the surface integrity. In order to achieve a large variation of the thermal and mechanical loads, the feed f (0.04 mm to 0.2 mm) and the depth of cut {a_{\mathrm{p}}} (0.4 mm to 2 mm) are varied over a wide range. The cutting speed {v_{\mathrm{c}}} is kept constant (300 m/min). For the in-process measurement of the temperatures and contact conditions at the interface of the tool and the specimen, a tool-workpiece thermocouple is used. Additionally, the components of the resultant force are measured by a dynamometer. The characterization of the surface layer is performed by the measurement of the residual stresses using X-ray diffraction and supplemented by the determination of the geometrical properties of the machined surface using a stylus measurement instrument. The results show an increase in temperature and the components of the resultant force with the enlargement of the cross-section of the undeformed chip. Due to the temperature gradient, tensile residual stresses are introduced in the tangential direction of the surface layer. Compressive residual stresses occur only in the axial direction and can be correlated with the in-process measurement data by introducing the C-value. Consequently, the calculation of the presence of compressive residual stresses allows for a targeted control of the surface-layer properties during machining.


According to the vortex theory of matter, atoms consist of vortex rings in an infinite perfect liquid, the æther. These rings may be either hollow or filled with otating liquid. The cross section of the hollow or rotating core is in the simplest ase small and the ring is circular. Such vortices have been investigated. It has been hown that they can exist, and that they are stable for certain types of deformation, in this paper the stability of the hollow vortex ring is investigated further, with a view to proving that it is stable for all small deformations of its surface. An attempt also made to make the vortex theory of matter agree with the kinetic theory of ases as regards the relation between the velocity and the energy of an atom. On he latter theory the energy of an atom varies as the square of its velocity, while on he former theory the energy decreases as the velocity increases. As the two theories liffer on a fundamental point, while the consequences of the kinetic theory agree over wide range with experiment, those of the vortex theory are likely to be in discrepancy therewith. However, no account has been taken of the electric change which an atom must hold if electrolysis is to be explained. This electrification will evidently alter the relation between the energy and the velocity. The nature of the change thus produced is here discussed for the case of a hollow vortex, the surface of which behaves as a conductor of electricity, a representation which is dynamically realised by the theory of a rotationally-elastic fluid æther developed in Mr. Larmor’s paper, “A Dynamical Theory of the Electric and Luminiferous Medium.” The small oscillations also are worked out with a view to the discussion of the stability of an electrified vortex. 2. The velocity of translation of the vortex in its steady motion is constant and perpendicular to its plane. By impressing on the whole liquid a velocity equal and opposite to this, the hollow is reduced to rest. Since the cross section of the hollow is small, any small length of it may be regarded as cylindrical. A cylindrical vortex must, by reason of symmetry, have its cross section a circle, so that the cross section of the hollow of the annular vortex is approximately circular, and the hollow itself approximately a tore.


2014 ◽  
Vol 912-914 ◽  
pp. 217-226
Author(s):  
P. Kah ◽  
A. Njom ◽  
B. Mvola ◽  
J.A. Atangana ◽  
J. Martikainen

In this article, classification methods using mathematical morphology are used to generate the internal and external contours of an image of a natural fiber, "Rhektophyllum camerunense" taken by an epifluorescent electron microscope. The presence of impulse noise in the captured image and the presence of an almost identical texture characterized by the heterogeneity of the basic cells whose microstructure composes the fiber, make it difficult to use conventional methods of image analysis. As the fiber ofR. camerunenseconsists of basic cells interconnected by cellulosic hemicellulose, their delineation is possible by detecting the contour of the lumens. To distinguish the regions of basic cells, binarization is performed after application of a 3 × 3 median filter. The results obtained allow development of a method for calculating the geometrical parameters of the cross section of the fiberR. camerunenseand generation of the basic structure of the cross section by Voronoi diagram.


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