Nickel-Catalyzed Reductive Cross-Coupling of Benzylic Sulfonium Salts with Aryl Iodides

Synlett ◽  
2022 ◽  
Author(s):  
Fan Wu ◽  
Wei Wang ◽  
Ken Yao
Keyword(s):  
Electron Transfer ◽  
Transfer Process ◽  
Bond Cleavage ◽  
Cross Coupling ◽  
Direct Access ◽  
Single Electron Transfer ◽  
Mechanistic Studies ◽  
Electron Transfer Process ◽  
Sulfonium Salts ◽  
Aryl Iodides

A nickel-catalyzed cross-electrophile coupling of benzylic sulfonium salts with aryl iodides has been developed, providing direct access to diarylalkanes from readily available and stable coupling partners. Preliminary mechanistic studies suggest that the C–S bond cleavage proceeds through a single-electron transfer process to generate a benzylic radical.

Fluoroalkylation of Various Nucleophiles with Fluoroalkyl Sulfones through a Single Electron Transfer Process

2019 ◽  
Vol 84 (13) ◽  
pp. 8345-8359 ◽  
Author(s):  
Pan Xiao ◽  
Chuanfa Ni ◽  
Wenjun Miao ◽  
Min Zhou ◽  
Jingyu Hu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transfer Process ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Electron Transfer Process

scholarly journals Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process

2016 ◽  
Vol 7 (1) ◽  
Author(s):  
Bao-Sheng Li ◽  
Yuhuang Wang ◽  
Rupert S. J. Proctor ◽  
Yuexia Zhang ◽  
Richard D. Webster ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transfer Process ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Reductive Coupling ◽  
Electron Transfer Process
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