scholarly journals Effect of sodium hydroxide concentration on the compressive strength of geopolymer mortar using fly ash PLTU Tanjungjati B Jepara

2022 ◽  
Vol 955 (1) ◽  
pp. 012010
Author(s):  
A Kustirini ◽  
Antonius ◽  
P Setiyawan
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Coal Industry ◽  
Waste Materials ◽  
Geopolymer Concrete ◽  
Sodium Hydroxide Concentration ◽  
Alkaline Activator ◽  
Maximum Compressive Strength

Abstract Geopolymer concrete is concrete that uses environmentally friendly materials, using fly ash from waste materials from the coal industry as a substitute for cement. To produce geopolymer concrete, an alkaline activator is required, with a mixture of Sodium Hydroxide and Sodium Silicate. This research is an experimental study to determine the effect of variations in the concentration of sodium hydroxide (NaOH) 8 Mol, 10 Mol, 12 Mol, and 14 Mol on the compressive strength of geopolymer concrete. Mortar Geopolymer uses a mixture of 1: 3 for the ratio of fly ash and sand, 2.5: 0.45 for the ratio of sodium silicate and sodium hydroxide as an alkaline solution. The specimens used a cube mold having dimension 5 cm x 5 cm x 5 cm, then tested at 7 days and 28 days. The test resulted that concentration of NaOH 12 Mol obtained the maximum compressive strength of geopolymer concrete, that is 38.54 MPa. At concentrations of 12 Mol NaOH and exceeding 12M, the compressive strength of geopolymer concrete decreased.

Correlation between Na2SiO3/NaOH Ratio and Fly Ash/Alkaline Activator Ratio to the Strength of Geopolymer

2011 ◽  
Vol 341-342 ◽  
pp. 189-193 ◽  
Author(s):  
Mohd Mustafa Al Bakri Abdullah ◽  
H. Kamarudin ◽  
I. Khairul Nizar ◽  
M. Bnhussain ◽  
Y. Zarina ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Aluminosilicate Gel ◽  
Alkaline Activator ◽  
Maximum Compressive Strength

Geopolymer requires an alkaline activator to induce it pozzolanic property and to accelerate the geopolymerisation process. The geopolymerisation process occurs due to the mixing of fly ash, sodium silicate and sodium hydroxide as the alkaline activator, which produces aluminosilicate gel that acts as a binder. As such, the ratios of fly ash to alkaline activator and Na2SiO3/NaOH play an important role in obtaining desirable compressive strength; the concentration of NaOH used in this study was 12 M. Different ratios of fly ash to alkaline activator (0.5, 1.0, 1.5, 2.0, 2.5 and 3.0) and Na2SiO3/NaOH (0.5, 1.0, 1.5, 2.0, 2.5 and 3.0) were investigated in order to determine the maximum compressive strength. The alkaline activator was mixed with fly ash with different ratio as mentioned above and the samples were cured at 70°C for 24 hours and tested on the seventh day. The maximum compressive strength was obtained when the ratios of fly ash to alkaline activator and Na2SiO3/NaOH were 2.0 and 2.5 with compressive strength 73.86 MPa.

The Effect of Curing Time on the Properties of Fly Ash-Based Geopolymer Bricks

2012 ◽  
Vol 626 ◽  
pp. 937-941 ◽  
Author(s):  
W.I. Wan Mastura ◽  
H. Kamarudin ◽  
I. Khairul Nizar ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
H. Mohammed
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Water Absorption ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Experimental Work ◽  
Base Material ◽  
Curing Time ◽  
Curing Conditions ◽  
Alkaline Activator

This paper reports the results of an experimental work conducted to investigate the effect of curing conditions on the properties of fly ash-based geopolymer bricks prepared by using fly ash as base material and combination of sodium hydroxide and sodium silicate as alkaline activator. The experiments were conducted by varying the curing time in the range of 1-24 hours respectively. The specimens cured for a period of 24 hours have presented the highest compressive strength for all ratio of fly ash to sand. For increasing curing time improve compressive strength and decreasing water absorption.

scholarly journals Artificial Intelligence Approaches for Prediction of Compressive Strength of Geopolymer Concrete

Materials ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 983 ◽  
Author(s):  
Dong Dao ◽  
Hai-Bang Ly ◽  
Son Trinh ◽  
Tien-Thinh Le ◽  
Binh Pham
Keyword(s):  
Artificial Intelligence ◽  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Steel Slag ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Partial Replacement ◽  
Geopolymer Concrete

Geopolymer concrete (GPC) has been used as a partial replacement of Portland cement concrete (PCC) in various construction applications. In this paper, two artificial intelligence approaches, namely adaptive neuro fuzzy inference (ANFIS) and artificial neural network (ANN), were used to predict the compressive strength of GPC, where coarse and fine waste steel slag were used as aggregates. The prepared mixtures contained fly ash, sodium hydroxide in solid state, sodium silicate solution, coarse and fine steel slag aggregates as well as water, in which four variables (fly ash, sodium hydroxide, sodium silicate solution, and water) were used as input parameters for modeling. A total number of 210 samples were prepared with target-specified compressive strength at standard age of 28 days of 25, 35, and 45 MPa. Such values were obtained and used as targets for the two AI prediction tools. Evaluation of the model’s performance was achieved via criteria such as mean absolute error (MAE), root mean square error (RMSE), and coefficient of determination (R2). The results showed that both ANN and ANFIS models have strong potential for predicting the compressive strength of GPC but ANFIS (MAE = 1.655 MPa, RMSE = 2.265 MPa, and R2 = 0.879) is better than ANN (MAE = 1.989 MPa, RMSE = 2.423 MPa, and R2 = 0.851). Sensitivity analysis was then carried out, and it was found that reducing one input parameter could only make a small change to the prediction performance.

scholarly journals Life Cycle Assessment and Impact Correlation Analysis of Fly Ash Geopolymer Concrete

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7375
Author(s):  
Xiaoshuang Shi ◽  
Cong Zhang ◽  
Yongchen Liang ◽  
Jinqian Luo ◽  
Xiaoqi Wang ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Life Cycle Assessment ◽  
Life Cycle ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Co2 Emissions ◽  
Co2 Emission ◽  
Gray Relational Analysis ◽  
Geopolymer Concrete ◽  
Sodium Hydroxide Concentration

Geopolymer concrete (GPC) has drawn widespread attention as a universally accepted ideal green material to improve environmental conditions in recent years. The present study systematically quantifies and compares the environmental impact of fly ash GPC and ordinary Portland cement (OPC) concrete under different strength grades by conducting life cycle assessment (LCA). The alkali activator solution to fly ash ratio (S/F), sodium hydroxide concentration (CNaOH), and sodium silicate to sodium hydroxide ratio (SS/SH) were further used as three key parameters to consider their sensitivity to strength and CO2 emissions. The correlation and influence rules were analyzed by Multivariate Analysis of Variance (MANOVA) and Gray Relational Analysis (GRA). The results indicated that the CO2 emission of GPC can be reduced by 62.73%, and the correlation between CO2 emission and compressive strength is not significant for GPC. The degree of influence of the three factors on the compressive strength is CNaOH (66.5%) > SS/SH (20.7%) > S/F (9%) and on CO2 emissions is S/F (87.2%) > SS/SH (10.3%) > CNaOH (2.4%). Fly ash GPC effectively controls the environmental deterioration without compromising its compressive strength; in fact, it even in favor.

scholarly journals Compressive Strength of Geopolymer Concrete Composites: Modeling and Comprehensive Systematic Review

2021 ◽  
Author(s):  
Hemn Unis Ahmed ◽  
Azad A. Mohammed ◽  
Ahmed S. Mohammed
Keyword(s):  
Systematic Review ◽  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Alkaline Solution ◽  
Construction Material ◽  
Assessment Tools ◽  
Curing Temperature ◽  
Geopolymer Concrete

Abstract The growing concern about global climate change and its adverse impacts on societies is putting severe pressure on the construction industry as one of the largest producers of greenhouse gases. Given the environmental issues associated with cement production, geopolymer concrete has emerged as a sustainable construction material. Geopolymer concrete is cementless concrete that uses industrial or agro by-product ashes as the main binder instead of ordinary Portland cement; this leads to being an eco-efficient and environmentally friendly construction material. Compressive strength is one of the most important mechanical property for all types of concrete composites including geopolymer concrete, and it is affected by several parameters like an alkaline solution to binder ratio (l/b), fly ash (FA) content, SiO2/Al2O3 (Si/Al) of the FA, fine aggregate (F) and coarse aggregate (C) content, sodium hydroxide (SH) and sodium silicate (SS) content, ratio of sodium silicate to sodium hydroxide (SS/SH), molarity (M), curing temperature (T), curing duration (CD) inside the oven and specimen ages (A). In this regard, a comprehensive systematic review was carried out to show the effect of these different parameters on the compressive strength of the fly ash-based geopolymer concrete (FA-GPC). In addition, multi-scale models such as Artificial Neural Network (ANN), M5P-tree (M5P), Linear Regression (LR), and Multi-logistic Regression (MLR) models were developed to predict the compressive strength of FA-GPC composites. For the first time, in the modeling process, twelve effective parameters including l/b, FA, Si/Al, F, C, SH, SS, SS/SH, M, T, CD, and A were considered the modeling input parameters. Then, the efficiency of the developed models was assessed by various statistical assessment tools like Root Mean Squared Error (RMSE), Mean Absolute Error (MAE), Scatter Index (SI), OBJ value, and the Coefficient of determination (R2). Results show that the curing temperature, sodium silicate content, and ratio of the alkaline solution to the binder content are the most significant independent parameters that influence on the compressive strength of the FA-GPC, and the ANN model has better performance for predicting the compressive strength of FA-GPC in compared to the other developed models.

scholarly journals Compressive Strength of Sustainable Geopolymer Concrete Composites: A State-of-the-Art Review

2021 ◽  
Vol 13 (24) ◽  
pp. 13502
Author(s):  
Hemn Unis Ahmed ◽  
Azad A. Mohammed ◽  
Serwan Rafiq ◽  
Ahmed S. Mohammed ◽  
Amir Mosavi ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Construction Material ◽  
Curing Temperature ◽  
Geopolymer Concrete ◽  
Palm Oil Fuel Ash ◽  
Silicate Content ◽  
Binder Ratio

The building industry, which emits a significant quantity of greenhouse gases, is under tremendous pressure due to global climate change and its consequences for communities. Given the environmental issues associated with cement production, geopolymer concrete has emerged as a sustainable construction material. Geopolymer concrete is an eco-friendly construction material that uses industrial or agricultural by-product ashes as the principal binder instead of Portland cement. Fly ash, ground granulated blast furnace slag, rice husk ash, metakaolin, and palm oil fuel ash were all employed as binders in geopolymer concrete, with fly ash being the most frequent. The most important engineering property for all types of concrete composites, including geopolymer concrete, is the compressive strength. It is influenced by different parameters such as the chemical composition of the binder materials, alkaline liquid to binder ratio, extra water content, superplasticizers dosages, binder content, fine and coarse aggregate content, sodium hydroxide and sodium silicate content, the ratio of sodium silicate to sodium hydroxide, the concentration of sodium hydroxide (molarity), curing temperature, curing durations inside oven, and specimen ages. In order to demonstrate the effects of these varied parameters on the compressive strength of the fly ash-based geopolymer concrete, a comprehensive dataset of 800 samples was gathered and analyzed. According to the findings, the curing temperature, sodium silicate content, and alkaline solution to binder ratio are the most significant independent parameters influencing the compressive strength of the fly ash-based geopolymer concrete (FA-BGPC) composites.

scholarly journals Effect of molarity of sodium hydroxide and molar ratio of alkaline activator solution on the strength development of geopolymer concrete

2021 ◽  
Vol 309 ◽  
pp. 01058
Author(s):  
V Srinivasa Reddy ◽  
Karnati Vamsi Krishna ◽  
M V Seshagiri Rao ◽  
S Shrihari
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Ash Content ◽  
Mix Design ◽  
Molar Ratio ◽  
Strength Development ◽  
Geopolymer Concrete ◽  
Synergic Effect ◽  
Alkaline Activator

In the current study, effect of SiO2/Na2O ratio in Sodium silicate (Na2SiO3) solution, Na2SiO3/NaOH ratio and molarity of NaOH on the compressive strength of geopolymer concrete. A geopolymer mix design is formulated with various mixes are casted with alkali activator solution (AAS) / fly ash (FA) =0.5 and constant fly ash content. The molar ratio of SiO2/Na2O in Na2SiO3 solution is altered from 1.50 to 3.00 for different ratios of Na2SiO3/NaOH (2.0, 2.5 and 3.0) and also for various molarities of NaOH (8M,10M,12M,14M,16M and 18M) are studied for their synergic effect on the compressive strength of geopolymer concrete. Results highlighted that the 16M NaOH yields high compressive strength when SiO2/Na2O in Na2SiO3 solution is around 2.00 to 2.40 and Na2SiO3/NaOH=2.5.

scholarly journals Study on Setting & Strength Characteristic of GGBS based Geopolymer Concrete by Blending of Fly Ash and Metakaoline

2020 ◽  
Vol 13 (1) ◽  
pp. 117-122
Author(s):  
Addepalli Mallinadh Kashyap ◽  
Tanimki Chandra Sekhar Rao ◽  
N.V. Ramana Rao
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Setting Time ◽  
Engineering Properties ◽  
Geopolymer Concrete ◽  
Conventional Concrete ◽  
New Material

Carbon dioxide is liberated in huge amounts by the manufacturing of Portland Pozzolana Cement. Normally, conventional concrete is manufactured with Portland cement, which acts as a binder. The production of cement emits CO2 into the atmosphere, which is a green house gas and causes the environmental pollution. Considering this as a serious environmental problem, there is a need to develop sustainable alternatives to Portland cement utilizing the industrial byproducts such as fly ash, ground granulated blast furnace slag and Metakaoline which are pozzolonic in nature. It has been established that fly ash can replace cement partially. In this context, a new material was developed known as ‖Geopolymer‖. In this study, the various parameters on the short term engineering properties of fresh and hardened properties of Geopolymer Mortar were studied. In the present investigation, cement is replaced by geopolymer source material and water is replaced by alkaline activator consisting of Sodium Silicate and Sodium Hydroxide of molarity (12M). The ratio of sodium silicate to sodium hydroxide adopted was 2.5. The test results showed that final setting time decreases as the GGBS content in the mix increases and also increase in compressive strength. Where as in the case of metakaoline, as the content increases, there is a decrease in compressive strength and setting times of the geopolymer concrete.

Mechanical strength variation of zeolite-fly ash geopolymer mortars with different activator concentrations

2021 ◽  
Vol 12 (3) ◽  
pp. 96
Author(s):  
Roble İbrahim Liban ◽  
Ülkü Sultan Keskin ◽  
Oğuzhan Öztürk
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Flexural Strength ◽  
Sodium Hydroxide ◽  
Sodium Hydroxide Concentration ◽  
Binding Material ◽  
Alkaline Activator ◽  
Compressive And Flexural Strengths ◽  
Mechanical Strengths ◽  
Natural Precursor

Zeolite is of a significance for geopolymers as it is a natural precursor and does not require additional heat treatment for activation. However, aluminosilicates sourced from natural sources require additional handling for the best use of exploitation. In this study, geopolymers were synthesized by binary use of zeolite and fly ash as main binding material and sodium silicate and sodium hydroxide as alkaline activator. The influence of alkaline activator ratios and sodium hydroxide concentrations on the compressive strength and flexural strength of the zeolite-fly ash based geopolymers were studied. In this research, zeolite-fly ash based geopolymer mortars were produced by using 50% of natural zeolite (clinoptilolite) and 50% of C-type fly ash. Four different activator ratios (Na2SiO3/NaOH: 1, 1.5, 2 and 2.5) and two sodium hydroxide molarities (10M and 12M) was utilized to activate zeolite and fly ash in order to determine the effect of these parameters on the mechanical strengths of the produced geopolymer mortars. The results indicated that as the alkaline activator ratio and NH molarity were increased the compressive strength of the zeolite-fly ash based geopolymers also increased. The maximum compressive and flexural strength values obtained after 28 days of curing were 20.1 MPa and 5.3 MPa respectively and corresponds when used activator ratio of 2.5 and sodium hydroxide concentration of 12 molarity. The obtained results indicated that both the alkaline activator ratio and sodium hydroxide concentration affected the compressive and flexural strengths of zeolite-fly ash based geopolymer mortar specimens.

The Effect of Dry Mix Sodium Hydroxide onto Workability and Compressive Strength of Geopolymer Paste

2020 ◽  
Vol 12 (9) ◽  
Author(s):  
A. Z. Mohd Ali ◽  
◽  
N. A. Jalaluddin ◽  
N. Zulkiflee ◽  
◽  
...  
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Alkaline Solution ◽  
High Emission ◽  
New Material ◽  
Curing Regime ◽  
Solid Form ◽  
Geopolymer Paste

The production of ordinary Portland cement (OPC) consumes considerable amount of natural resources, energy and at the same time contribute in high emission of CO2 to the atmosphere. A new material replacing cement as binder called geopolymer is alkali-activated concrete which are made from fly ash, sodium silicate and sodium hydroxide (NaOH). The alkaline solution mixed with fly ash producing alternative binder to OPC binder in concrete named geopolymer paste. In the process, NaOH was fully dissolved in water and cooled to room temperature. This study aims to eliminate this process by using NaOH in solid form together with fly ash before sodium silicate liquid and water poured into the mixture. The amount of NaOH solids were based on 10M concentration. The workability test is in accordance to ASTM C230. Fifty cubic mm of the geopolymer paste were prepared which consists of fly ash to alkaline solution ratio of 1: 0.5 and the curing regime of 80℃ for 24 hours with 100% humidity were implemented. From laboratory test, the workability of dry method geopolymer paste were decreased. The compressive strength of the dry mix of NaOH showed 55% and the workability has dropped to 58.4%, it showed strength reduction compared to the wet mix method.

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