scholarly journals Using Of Different Electrocoagulation Cell Configuration Parameters for Treating of Abu-Ghraib Dairy Products Wastewater

2022 ◽  
Vol 961 (1) ◽  
pp. 012059
Author(s):  
Sara Mohannad Abd Al-Hamza ◽  
Hayder Mohammed Abd Al-Hamed

Abstract One of the most significant issues that people throughout the world will confront in the future years is a lack of clean and safe water. Anthropogenic activities, in particular, are polluting water systems. With rising population, urbanization, and climate change, water reuse has become a requirement in some areas of the globe, putting pressure on the development of effective water treatment methods for a range of contaminants. High biological oxygen demand (BOD), chemical oxygen demand (COD), oil-grease, and other pollutant loads define dairy sector effluent. Improved technology is required to address these issues. Electrocoagulation is a new type of therapy. It’s simple to use, ecologically friendly, and removes a wide range of contaminants from a variety of water types. The goal of this study was to see how operational factors such applied voltage, number of electrodes, distance between electrodes, electrode shape, and reaction time affected the electrocoagulation of actual dairy effluent. Aluminum and iron electrodes are used for this purpose. It was discovered that raising the applied voltage, reaction time, and decreasing the distance between electrodes improved COD, BOD, EC, TDS, color, and oil-grease removal efficiency. Moreover, switch between square, triangular electrodes and perforated cylindrical. The data show that electrocoagulation is effective at the maximum COD, BOD removal efficiency of first electrode at 20 holes of cylindrical shape is (88.03) %, (87.97) %, respectively. Second triangle shape is (100) %, (100) % respectively. Third square shape is (99.38) %, (99.42) % respectively. the maximum removal of TDS, EC efficiency of first electrode at 20 holes of cylindrical shape is (67.57) %, (62.34) %, respectively. Second triangle shape is (77.45) %, (67.68) % respectively. Third square shape is (81.96) %, (71.25) % respectively. The maximum color and oil-grease removal efficiency of first electrode at 20 holes of cylindrical shape is (100) %, (100) %, respectively. Second triangle shape is (100) %, (100) % respectively. Third square shape is (100) %, (100) % respectively. Electrocoagulation methods for the treatment of dairy wastewaters were shown to be successful in the research. Finally, the findings indicated that electrocoagulation is a technically feasible method for removing contaminants from dairy wastewaters.

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Edris Bazrafshan ◽  
Hossein Moein ◽  
Ferdos Kord Mostafapour ◽  
Shima Nakhaie

Dairy industry wastewater is characterized by high biochemical oxygen demand (BOD5), chemical oxygen demand (COD), and other pollution load. The purpose of this study was to investigate the effects of the operating parameters such as applied voltage, number of electrodes, and reaction time on a real dairy wastewater in the electrocoagulation process. For this purpose, aluminum electrodes were used in the presence of potassium chloride as electrolytes. It has been shown that the removal efficiency of COD, BOD5, and TSS increased with increasing the applied voltage and the reaction time. The results indicate that electrocoagulation is efficient and able to achieve 98.84% COD removal, 97.95% BOD5removal, 97.75% TSS removal, and >99.9% bacterial indicators at 60 V during 60 min. The experiments demonstrated the effectiveness of electrocoagulation techniques for the treatment of dairy wastewaters. Finally, the results demonstrated the technical feasibility of electrocoagulation process using aluminum electrodes as a reliable technique for removal of pollutants from dairy wastewaters.


2018 ◽  
Vol 78 (6) ◽  
pp. 1260-1267 ◽  
Author(s):  
Mohammad Malakootian ◽  
Mohammad Reza Heidari

Abstract Phenol and its derivatives are available in various industries such as refineries, coking plants, steel mills, drugs, pesticides, paints, plastics, explosives and herbicides industries. This substance is carcinogenic and highly toxic to humans. The purpose of the study was to investigate the removal of phenol from wastewater of the steel industry using the electrocoagulation–photo-Fenton (EC-PF) process. Phenol and chemical oxygen demand (COD) removal efficiency were investigated using the parameters pH, Fe2+/H2O2, reaction time and current density. The highest removal efficiency rates of phenol and COD were 100 and 98%, respectively, for real wastewater under optimal conditions of pH = 4, current density = 1.5 mA/cm2, Fe2+/H2O2 = 1.5 and reaction time of 25 min. Combination of the two effective methods for the removal of phenol and COD, photocatalytic electrocoagulation photo-Fenton process is a suitable alternative for the removal of organic pollutants in industry wastewater because of the low consumption of chemicals, absence of sludge and other side products, and its high efficiency.


Electrocoagulation (EC) process uses direct electric current source between metal electrode submerged in the effluent that results in electrode dissolution, with a suitable pH, metal ion can form a wide range of metal hydroxide and coagulated species that destabilized and dissolved contaminants absorbed. Electrocoagulation (EC) has been working for the percentage removal of BOD (Biochemical oxygen demand)/ chemical oxygen demand (COD) ratio, Color and COD on leachate in a batch Electrocoagulation reactor using stainless steel (SS) electrode. EC technology depends on so many factors such as electrode material, initial pH, applied voltage, inter-electrode distance, and electrolysis time. From the experimental work, results reveal that the maximum percentage of removal achieved were COD and Color 73.5% and 65.0% respectively and increasing BOD/COD ratio 0.11 to 0.62. The optimum inter-electrode distance 1cm with electrode surface area 35 cm2 and optimum electrolysis time of 120 min at optimum applied voltage 12V, stirring speed 250 rpm and pH 9.8. These results proved that the EC process is an appropriate and proficient approach for treating the landfill leachate.


2014 ◽  
Vol 69 (5) ◽  
pp. 1080-1087 ◽  
Author(s):  
Xianzhong Cao ◽  
Huiqing Lou ◽  
Wei Wei ◽  
Lijuan Zhu

In this study, the Box-Benkhen design and response surface method (RSM) were applied to evaluate and optimize the operating variables during the treatment of tetrahydrofuran (THF) wastewater by Fenton process. The four factors investigated were initial pH, Fe2+ dosage, H2O2 dosage and reaction time. Statistical analysis showed the linear coefficients of the four factors and the interactive coefficients such as initial pH/Fe2+ dosage, initial pH/H2O2 dosage and Fe2+ dosage/H2O2 dosage all significantly affected the removal efficiency. The RSM optimization results demonstrated that the chemical oxygen demand (COD) removal efficiency could reach up to 47.8% when initial pH was 4.49, Fe2+ dosage was 2.52 mM, H2O2 dosage was 20 mM and reaction time was 110.3 min. Simultaneously, the biodegradability increased obviously after the treatment. The main intermediates of 2-hydroxytetrahydrofuran, γ-butyrolactone and 4-hydroxybutanoate were separated and identified and then a simple degradation pathway of THF was proposed. This work indicated that the Fenton process was an efficient and feasible pre-treatment method for THF wastewater.


2019 ◽  
Vol 80 (12) ◽  
pp. 2422-2429 ◽  
Author(s):  
Yahya Esfandyari ◽  
Keivan Saeb ◽  
Ahmad Tavana ◽  
Aptin Rahnavard ◽  
Farid Gholamreza Fahimi

Abstract The present study evaluated the treatment of hospital wastewater by the electrocoagulation process using aluminum and iron electrodes. The effects of pH, voltage and reaction time on the removal efficiencies of the antibiotic cefazolin, chemical oxygen demand (COD) and turbidity were investigated. The results showed that by increasing reaction time and input voltage, the removal efficiency of pollutants was increased. The highest removal efficiency of cefazolin, COD, and turbidity occurred at neutral pH, which may have been related to the formation of aluminum hydroxide (Al(OH)3) flocs through the combination of aluminum released from the surface of the electrode and the hydroxide ions present in the solution. The conductivity of the treated wastewater at neutral to alkaline pH decreased compared to acidic pH, which may have been due to the adsorption of anions and cations from the solution by the Al(OH)3 flocs. The electrode and energy consumption in the present study was higher than in other studies, which may have been due to the high concentration of COD in and the turbidity of the solution.


2019 ◽  
Vol 83 ◽  
pp. 01015
Author(s):  
Jie Lei ◽  
Xiaodong Zhang ◽  
Zhenglin Zhou ◽  
Shaohui Fan ◽  
Bo Jiang ◽  
...  

The mixed wastewater of 1, 4 butanediol was tested with iron filings and carbon powder as catalyst by aeration to provide oxygen. The effects of carbon powder, pH value and reaction time on wastewater treatment were studied. The optimal experimental condition was that the mesh number of activated carbons was 20, the pH value was 5, the reaction time was 30min, and the Chemical Oxygen Demand (COD) removal efficiency reached 36.2%. At the same time, The response surface method was used to analyze and optimize the experimental results, and the relation formula of each influencing factor on removal efficiency was established, and the order of influence degree of each factor on removal efficiency (pH> activated carbon mesh number > reaction time) was obtained, in which pH had the greatest influence on the treatment rate of ferro-carbon micro-electrolysis treatment of 1, 4-butanediol wastewater.


2021 ◽  
Author(s):  
Sushma lavudya ◽  
maneesha vodnala ◽  
Bhagawan Dheeravath ◽  
kiran kumar Panga ◽  
Vijaya krishna saranga ◽  
...  

Abstract Landfill leachate contains organic, inorganic compounds, heavy metals, ammonia, and xenobiotic compounds which are considered unsafe for discharging into surface water which requires to be treated before its discharge into the water. In this paper, preliminary studies are reported on the application of Fenton, Struvite, and Electrooxidation processes for the removal of Chemical Oxygen Demand (COD) and ammonia from landfill leachate. Various operational parameters like pH, dosage, reaction time, and applied voltage were optimized in laboratory batch experiments and evaluated for removal of COD and ammonia. Results demonstrated that the Fenton process could effectively remove COD and ammonia by 75% and 23% respectively at 210 min for Fe+2:H2O2: 1:5 at a fixed pH 3. The Struvite process has been effective in the removal of ammonia by 74% at pH 9 with the dosage of Mg+2:PO43-:NH4+ at 1:1:1 ratio. Results from Electrooxidation for COD and ammonia were observed as 58.25% and 44% respectively at the applied voltage 8 V for a reaction time of 60 min. The efficiency of treatment processes was also evaluated in Sequential processes for COD and ammonia i.e., Sequence-I (Fenton-Electrooxidation-Struvite) and Sequence-II (Fenton-Struvite) at pre-optimized conditions. The sequential processes have been depicted, the removal efficiencies of COD and ammonia of 89% and 82% by Sequence-I; 76.77%, and 77% by Sequence-II respectively. The present study demonstrates that Fenton followed by Electrooxidation and Struvite is an effective treatment process that can enhance the treatment of landfill leachate.


2021 ◽  
Vol 2021 ◽  
pp. 1-13
Author(s):  
Phuong Thi Thanh Nguyen ◽  
Hieu Trung Nguyen ◽  
Uyen Nhat Phuoc Tran ◽  
Ha Manh Bui

Hospital wastewater contains a complex mixture of bioactive substances and microorganisms that are deleterious to humans and aquatic animals. In this study, four antibiotics, namely, ofloxacin, ciprofloxacin, cefuroxime, and amoxicillin, respectively, from the wastewater of seven hospitals in Ho Chi Minh City, Vietnam, were monitored. The results revealed that the wastewater from these hospitals is contaminated with at least one of the antibiotics. In addition, the degradation capacity of the antibiotics by the wastewater treatment plant at one of the hospitals by the cold plasma technique was investigated. Furthermore, effects of the variation in pH, interelectrode distance, applied voltage, and reaction time on the removal efficiency were investigated in terms of the reduction in antibiotics concentration, COD, and ammonia. Ciprofloxacin, cefuroxime, COD, and ammonia were almost eliminated, while ofloxacin and amoxicillin were reduced by more than 72% under optimum conditions (initial pH of 10, reaction time of 15 min, applied voltage of 30 kV, and interelectrode distance of 10 mm). All of these factors affected the removal efficiency. The removal efficiency was most robust in the first 5 min, and it increased with the increase in the reaction time. However, the removal efficiency tended to saturate over time, while it decreased with the increase in the reaction time. With an applied voltage of 30 kV onwards, the removal efficiency was not significantly different. Most of the pollutants were predominately eliminated under slightly alkaline conditions (pH of ∼10). In addition, primary oxidants in the aqueous phase, such as O3, H2O2, and ⋅OH, were generated. Besides, the obtained results also revealed that the decomposition of ciprofloxacin and cefuroxime follows the first-order reaction kinetics; meanwhile, the third-order reaction kinetics was most likely for the decomposition of ofloxacin and amoxicillin.


2021 ◽  
Vol 8 (3) ◽  
pp. 237-244
Author(s):  
Abdoliman Amouei ◽  
Mehdi Pouramir ◽  
Hosseinali Asgharnia ◽  
Mahmoud Mehdinia ◽  
Mohammad Shirmardi ◽  
...  

Background: Leachate contains toxic and non-biodegradable substances that are not easily treated by conventional treatment methods. This study investigated the effect of pH, current density, and reaction time parameters on the removal of cyanide (CN- ), nitrate (NO3- ), turbidity, and chemical oxygen demand (COD) from leachate by electrocoagulation process. Methods: This study was an experimental one with direct current using four parallel bipolar aluminum electrodes with 90% purity. The length, width, and thickness of the electrodes were 5 cm, 10 cm, and 2 mm, respectively. There were 6 holes with a diameter of 0.7 cm on each of the electrodes. The samples were prepared from the old leachate of solid waste landfill in Ghaemshahr, Iran. Results: In this study, at a current density of 33 mA/cm2 and a time of 60 minutes, the optimum removal efficiency of cyanide (100 %) was obtained at pH 5.5 and pH 10. Moreover, the maximum removal of nitrate (99.65 %) and turbidity (86.41 %) were at pH 5.5 and pH 8.3, respectively and the highest removal efficiency of COD (83.14 %) was obtained at pH 10. Conclusion: The results showed that the removal of cyanide, nitrate, turbidity, and COD increases with increasing current density and reaction time. Due to the proper removal of nitrate and cyanide from leachate by electrocoagulation, nitrate and cyanide amounts were less than the allowable contamination level. Based on the results, electrocoagulation is considered an efficient and effective method for removing nitrate and cyanide from old leachate of municipal solid wastes.


2012 ◽  
Vol 3 (1) ◽  
pp. 38-42 ◽  
Author(s):  
Huu Tap Van ◽  
Van Tuyen Trinh ◽  
Xuan Hien Dang

The landfill leachate is commonly treated for non-biodegradable organic matters, ammonia and colour. Experimental investigations using polyaluminium chlorite (PAC) and UV/O3 have been conducted for the determination of optimal pH value, reaction time and PAC concentration for the removal of chemical oxygen demand (COD) and colour. In pre-treatment coagulation stages, the highest COD and colour removal efficiencies were observed at the concentration of PAC ≥ 3,000 mglG1 and pH values between 7 and 8. However, these experiments also indicated significant removal efficiency for PAC starting with concentrations of 1,500 mglG1. The efficiency of COD and colour removal were approximately 30% and 70%, respectively. Similar efficiencies have been observed also during the second treatment stage where UV/O3 processes were used to treat coagulated leachate. After UV/O3 application, the pH of leachate reached the optimum value of 7.5 whereas the highest COD and colour removal efficiency was 55% and 72%, respectively, and the optimal reaction time was achieved after 80 min. Nước rỉ rác sinh ra từ bãi chôn lấp chất thải rắn cần được xử lý các thành phần chất hữu cơ khó phân hủy sinh học, xử lí amoni và độ màu. Một số kết quả thử nghiệm về xử lý COD và màu của nước rỉ rác bằng việc sử dụng phương pháp keo tụ vớiPAC và quá trình UV/O3 đã được thực hiện cùng với việc xác định các giá trị pH tối ưu, thời gian phản ứng và nồng độ PAC tối ưu. Hiệu suất xử lý cao nhất đạt được khi nồng độ của PAC ≥ 3.000 mg/l, pH trong khoảng từ 7 đển 8 trong giai đoạn tiền xửlý. Tuy nhiên, hiệu quả loại bỏ COD và màu bắt đầu tăng rõ khi nồng độ PAC từ 1.500 mg/l trở lên. Hiệu quả loại bỏ COD và màu tương ứng là khoảng 30% và 70%. Các giá trị pH này phù hợp cho quá trình phản ứng UV/O3 được sử dụng sau giai đoạn keo tụ. Sau quá trình xử lý bằng hệ UV/O3, pH của nước rỉ rác tối ưu được xác định là 7,5 (hiệu suất xử lý COD và màu cao nhất tương ứng là 55% và 72%), thời gian phản ứng tối ưu là 80 phút.


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