Crystal structure and Hirshfeld surface analysis of 1-[(benzyldimethylsilyl)methyl]-1-ethylpiperidin-1-ium ethanesulfonate
2022 ◽
Vol 78
(2)
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Keyword(s):
The title molecular salt, C17H30NSi+·C2H5O4S−, belongs to the class of a-aminosilanes and was synthesized by the alkylation of 1-[(benzyldimethylsilyl)methyl]piperidine using diethyl sulfate. This achiral salt crystallizes in the chiral space group P21. One of the Si—C bonds in the cation is unusually long [1.9075 (12) Å], which correlates with the adjacent quaternary N+ atom and was verified by quantum chemical calculations. In the crystal, the components are linked by weak C—H...O hydrogen bonds: a Hirshfeld surface analysis was performed to further investigate these intermolecular interactions and their effects on the crystal packing.
2020 ◽
Vol 76
(11)
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pp. 1794-1798
2019 ◽
Vol 75
(2)
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pp. 237-241
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Keyword(s):
2021 ◽
Vol 77
(1)
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pp. 1-4
2019 ◽
Vol 75
(1)
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pp. 81-85
2019 ◽
Vol 75
(6)
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pp. 721-727
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2021 ◽
Vol 77
(6)
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pp. 672-676
2021 ◽
Vol 77
(4)
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pp. 356-359
Keyword(s):
2018 ◽
Vol 74
(11)
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pp. 1674-1677
2018 ◽
Vol 74
(3)
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pp. 385-389
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2018 ◽
Vol 74
(12)
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pp. 1746-1750
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