Thermal and optical behavior of novel phosphate-based inorganic mixtures containing Fe and Na and their application as solar reflective coating

2021 ◽  
pp. 1-19
Author(s):  
Akash Kumar Sahu ◽  
Rudrarapu Aravind ◽  
Gouri Sankhar Brahma ◽  
Trilochan Swain

Abstract Herein, the synthesis of the novel and inexpensive phosphate mixtures (calcined and non-calcined) of iron (Fe) and sodium (Na) and their application as reflective coating with building envelope materials is reported. The main objective of this work is to determine the effect of hydrated mixtures as a reflective coating. To obtain different hydrated mixtures, samples were synthesized as both calcined and non-calcined mixtures. Various measurement techniques were used to characterize and study the thermal behavior of mixtures. From the thermal behavior of the mixtures, it is noticed that the mixtures can be used as heat-dissipating materials. The average crystallite size was found 40.18 nm and 25.48 nm for the calcined and the non-calcined mixtures, respectively. The calculated band gap for the calcined mixture is 3.71 eV and the non-calcined mixture is 3.73 eV. According to Reddy's equation, the refractive index of the calcined and the non-calcined mixtures is 2.61 and 2.60, respectively. Both the calcined (1A) and the non-calcined (1B) mixtures were fabricated with commercial white paint to develop aesthetic light gray coatings. Both coatings were painted and tested on two building material slabs separately. Then, the highest reflective coating material between these two was painted on a house prototype and tested against commercial gray paint available in the market. An average temperature reduction of 3.8 K was observed in modified gray coating compared to commercial building paint. The reflective coating of the calcined mixture blended with white paint was observed to be better than the non-calcined mixture blended with white paint.

2020 ◽  
Vol 176 (3-4) ◽  
pp. 349-384
Author(s):  
Domenico Cantone ◽  
Marianna Nicolosi-Asmundo ◽  
Daniele Francesco Santamaria

In this paper we consider the most common TBox and ABox reasoning services for the description logic 𝒟ℒ〈4LQSR,x〉(D) ( 𝒟 ℒ D 4,× , for short) and prove their decidability via a reduction to the satisfiability problem for the set-theoretic fragment 4LQSR. 𝒟 ℒ D 4,× is a very expressive description logic. It combines the high scalability and efficiency of rule languages such as the SemanticWeb Rule Language (SWRL) with the expressivity of description logics. In fact, among other features, it supports Boolean operations on concepts and roles, role constructs such as the product of concepts and role chains on the left-hand side of inclusion axioms, role properties such as transitivity, symmetry, reflexivity, and irreflexivity, and data types. We further provide a KE-tableau-based procedure that allows one to reason on the main TBox and ABox reasoning tasks for the description logic 𝒟 ℒ D 4,× . Our algorithm is based on a variant of the KE-tableau system for sets of universally quantified clauses, where the KE-elimination rule is generalized in such a way as to incorporate the γ-rule. The novel system, called KEγ-tableau, turns out to be an improvement of the system introduced in [1] and of standard first-order KE-tableaux [2]. Suitable benchmark test sets executed on C++ implementations of the three mentioned systems show that in several cases the performances of the KEγ-tableau-based reasoner are up to about 400% better than the ones of the other two systems.


Sensors ◽  
2018 ◽  
Vol 18 (9) ◽  
pp. 3120 ◽  
Author(s):  
Shanshan Hu ◽  
Huaiyang Wang ◽  
Yong Wang ◽  
Zhengshi Liu

A novel elastic body design idea of six-axis wrist force sensor with a floating beam was raised based on the analysis of the robot six-axis wrist force sensor with a floating beam. The design ideas improve the sensor’s dynamic performance significantly, while not reducing its sensitivity. First, the design ideas were described in detail, which were analyzed by mechanical modeling and were verified by finite element analysis. Second, the static simulation analysis of the novel elastomer of sensor was carried out. According to the strain distribution performance, the position of the strain gauges pasted and the connection mode of the full-bridge circuits were decided, which can achieve theoretical decoupling. Finally, the comparison between the static and dynamic performance of the novel sensor and the original sensor with floating beams was done. The results show that the static and dynamic performance of the novel six-axis wrist sensor are all better than the original sensor.


2021 ◽  
Author(s):  
Ivan L. Pinto

The objective of this project was to provide an overview of Life Cycle Assessment (LCA) and to demonstrate its application as a tool to provide a scientific comparison of alternative construction options for a commercial building in the Canadian context. The work entailed a quantitative assessment of the embodied environmental impacts of typical office buildings using a steel frame, and a concrete frame alternative (and associated components) in Toronto. Through the use of four assessment strategies, this study has indicated that the steel framed building performs better than the concrete building in most impact indicators, excepting primary energy and eutrophication potential. However, additional buildings should be assessed in order to confirm this finding. Furthermore, it was found that the manufacturing phase represents over 90% of the embodied impacts of the whole building. The study also advises caution when comparing different LCA studies and identifies its difficulties.


Author(s):  
Kanchi Isswani

The novel Coronavirus was something that nobody was prepared for. It was that part of the syllabus which was always neglected. The contagious disease which started in the Wuhan region of China had started to settle in various parts of the World. The outbreak of this disease has reached such a huge number that all the countries witnessed lockdown in some form or the other. Some people have witnessed destruction of mankind while some have even leisured this time to their fullest but as it has been always said “Prevention is better than cure”. Prevention of covid 19 in all the nations was one of the major steps which was taken in the year 2020. In India it all started in the year of 2019 December when the first ever case of covid 19 was reported in the state of Kerala followed by Rajasthan, Maharashtra and Delhi. Following such a situation and then sudden increase in the no of cases all over the country a major decision was taken that was of Complete lockdown excluding the emergency and essential services. Before taking the step of lockdown, as a gesture of respect to the frontline workers, government of India announced Tali Bajao movement. In the period of lockdown Certain norms were even made mandatory that were wearing a mask, maintenance of hand sanitation and following social distancing of 1.5 meters in public places. All the educational institutes and teachings were even suspended during the time period of lockdown as it could have become a hub for the virus to spread. With time, the restrictions which were laid down in lockdown were started to be reduced in the phase wise manner and finally India noticed its very first Unlock period. In all this scenario mankind has dealt with various situations and have emerged to be a better person. All these steps were crucial to control the spread of Novel Coronavirus and prevention from the already spread cases.


Author(s):  
Nana Kutsia ◽  
Miranda Todua ◽  
Marine Turava

“Moon`s Abduction” by Konstantine Gamsakhurdia is a very important text written in the Soviet Georgia. The writer created monumental literary landscape in the period of so called “socialist realism” literary style. The novel makes a great demand on the reader`s erudition, on his capacity to understand the complex allusions, literary, philosophical and mythological, that characterize Gamsakhurdia`s prose. The present article deals with the world-outlook of Soviet and Post-Soviet literary critique – on the background of the publicistic letters of the outstanding critics Beso Zhghenti and Soso Sigua. The novel clears up the writer`s attitude to the revolution, socialism, collectivization of agriculture, person`s role as a member of society. The Soviet and Post-Soviet critics world-outlooks are absolutely different. By the Soviet critic (Beso Zhghenti) the novel is an excessive apologia of Soviet system, of Soviet state-building, a positive character (hero) is Arzakan Zvambaia, the security officer, the ossicial of Cheka, Bolshevism is better than traditional life of Georgia, civilization is better than culture. By the Post-Soviet world-outlook (Soso Sigua) the novel is a reflection of tragedy of the Georgian nation (because of negation of Georgian traditions, unique Georgian culture), a positive character is a prince Tarash Emkhvari, cultural and well-educated person; Bolshevizm is tragedy. Literary, philosophical and mythological allusions characterize Gamsakhurdias literary heritage (verses, short-stories, novels). The article deals with the world-outlook of the author. The official of Cheka Arzakan is a patricide, another official Arlan cut the centuries-old sacral tree - Bolhevizm hates roots and traditions. There are a lot of mythological characters reflected in the novel (Aramkhutu-Amirani, Sacral-tree, Mezir – Sacral serpant…). A reader feels the influence of Nitcze and Bergson world-outlook, passages from Hesiod`s “Theogony” and Appolonios from Rodoss “Argonautica.”The novel of Konstantine Gamsakhurdia is one of the best reflections and the best samples of Georgian novel of the 30s of the 20th century epoch.


Marine Drugs ◽  
2020 ◽  
Vol 18 (3) ◽  
pp. 165 ◽  
Author(s):  
Feng-Yu Du ◽  
Guang-Lin Ju ◽  
Lin Xiao ◽  
Yuan-Ming Zhou ◽  
Xia Wu

Soil-borne pathogens, including phytopathogenic fungi and root-knot nematodes, could synergistically invade vegetable roots and result in serious economic losses. The genus of Trichoderma has been proven to be a promising reservoir of biocontrol agents in agriculture. In this study, the search for antagonistic metabolites from a marine-derived fungus, Trichoderma longibrachiatum, obtained two structural series of sesquiterpenes 1–6 and cyclodepsipeptides 7–9. Notably, the novel 1 was a rare norsesquiterpene characterized by an unprecedented tricyclic-6/5/5-[4.3.1.01,6]-decane skeleton. Their structures were elucidated by extensive spectroscopic analyses, while the absolute configuration of novel 1 was determined by the comparison of experimental and calculated ECD spectra. The novel 1 and known 2 and 3 showed significant antifungal activities against Colletotrichum lagrnarium with MIC values of 8, 16, and 16 μg/mL respectively, even better than those of the commonly used synthetic fungicide carbendazim with 32 μg/mL. They also exhibited antifungal potential against carbendazim-resistant Botrytis cinerea. Cyclodepsipeptides 7–9 showed moderate nematicidal activities against the southern root-knot nematode (Meloidogyne incognita). This study constitutes the first report on the antagonistic effects of metabolites from T. Longibrachiatum against soil-borne pathogens, also highlighting the integrated antagonistic potential of marine-derived T. Longibrachiatum as a biocontrol agent.


2019 ◽  
Vol 2 ◽  
pp. 106-116
Author(s):  
Bhanu Bhakta Sharma Khandal

Sumnima, a novel written by Bishweshwar Prasad Koirala (BP Koirala in short), has raised voice for social integration through harmonious relationship among the ethnic groups. But it is read as the presentation of binary between Aryan and Kirat cultures, highlighting differences in belief systems, rites, rituals, and day to day lifestyle that create misunderstanding, conflict, and problems among the people of different cultural groups. The main objective of studying the novel, in this article, is to find how the novelist offers an opportunity to the readers to realize the ideas and benefits of harmony among the divergent ethnic communities living in Nepal or elsewhere through understanding differences and celebrating the diversity. Theoretical insights of ethnicity have been used to analyze the primary text. The article argues, taking the reference of the novel, that ethnic misunderstandings and conflicts can be solved by understanding cultural norms and values of others. The article also examines and analyzes how the relations without understanding cannot prosper even within the same ethnic group but love and understanding makes the life beautiful no matter which tribe or ethnicity the people belong to. The implicit intention of the novelist in the novel is that in a culturally diverse society, mutual understanding, compromise, and respect of difference make the society a ‘salad bowl’ that works better than trying to make it a ‘melting pot’.


2020 ◽  
Vol 16 (1) ◽  
pp. 104-118 ◽  
Author(s):  
Shi-Chao He ◽  
Hui-Zhen Zhang ◽  
Hai-Juan Zhang ◽  
Qing Sun ◽  
Cheng-He Zhou

Objective: Due to the incidence of resistance, a series of sulfonamide-derived 1,2,4- triazoles were synthesized and evaluated. Method: The novel sulfonamide-derived 1,2,4-triazoles were prepared starting from commercial acetaniline and chlorosulfonic acid by sulfonylation, aminolysis, N-alkylation and so on. The antimicrobial activity of the synthesized compounds were evaluated in vitro by two-fold serial dilution technique. Results: In vitro antimicrobial evaluation found that 2-chlorobenzyl sulfonamide 1,2,4-triazole 7c exhibited excellent antibacterial activities against MRSA, B. subtilis, B. typhi and E. coli with MIC values of 0.02−0.16 μmol/mL, which were comparable or even better than Chloromycin. The preliminary mechanism suggested that compound 7c could effectively bind with DNA, and also it could bind with human microsomal heme through hydrogen bonds in molecular docking. Computational chemical studies were performed on compound 7c to understand the structural features that are essential for activity. Additionally, compound 7c could generate a small amount of reactive oxygen species (ROS). Conclusion: Compound 7c could serve as a potential clinical antimicrobial candidate.


BioTechniques ◽  
2020 ◽  
Vol 69 (2) ◽  
pp. 108-112 ◽  
Author(s):  
Bijun Cheng ◽  
Tianjiao Li

The outbreak of viral pneumonia caused by the novel coronavirus SARS-CoV-2 that began in December 2019 caused high mortality. It has been suggested that the main protease (Mpro) of SARS-CoV-2 may be an important target to discover pharmaceutical compounds for the therapy of this life-threatening disease. Remdesivir, ritonavir and chloroquine have all been reported to play a role in suppressing SARS-CoV-2. Here, we applied a molecular docking method to study the binding stability of these drugs with SARS-CoV-2 Mpro. It appeared that the ligand–protein binding stability of the alliin and SARS-CoV-2 Mpro complex was better than others. The results suggested that alliin may serve as a good candidate as an inhibitor of SARS-CoV-2 Mpro. Therefore, the present research may provide some meaningful guidance for the prevention and treatment of SARS-CoV-2.


2012 ◽  
Vol 518 ◽  
pp. 238-245 ◽  
Author(s):  
Joanna Iwaniec ◽  
Marek Iwaniec

In the paper there are discussed the most interesting methods dedicated to frescos structural health monitoring. In the further part two methods and devices for fresco delamination detection developed by authors are presented. In order to enable future automation of developed measurement techniques and autonomic detection of fresco structural defects, the novel measures quantifying the probability of critical condition appearance (the lack of adhesive force) were introduced. Finally, the results of measurements of dynamic characteristics of healthy and delaminated structures are presented.


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