Ultrafast photophysical studies and femtosecond third-order nonlinear optical properties of a Soret-band excited zinc phthalocyanine

2020 ◽  
Author(s):  
Naga Krishnakanth Katturi ◽  
Venkata Suman Krishna Jonnadula ◽  
Chinmoy Biswas ◽  
Sai Santosh Kumar Raavi ◽  
Lingamallu Giribabu ◽  
...  
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Soret Band ◽  
Nonlinear Optical Properties ◽  
Zinc Phthalocyanine ◽  
Third Order ◽  
Photophysical Studies

Optical, electrochemical, third-order nonlinear optical, and excited state dynamics studies of thio-zinc phthalocyanine

2014 ◽  
Vol 18 (04) ◽  
pp. 305-315 ◽  
Author(s):  
Debasis Swain ◽  
Varun K. Singh ◽  
Narra V. Krishna ◽  
L. Giribabu ◽  
S. Venugopal Rao
Keyword(s):  
Optical Properties ◽  
Excited State ◽  
Nonlinear Optical ◽  
Radiative Decay ◽  
Nonlinear Optical Properties ◽  
Zinc Phthalocyanine ◽  
Closed Aperture ◽  
Third Order ◽  
Pump Probe ◽  
Excited State Dynamics

Zinc phthalocyanine with S-aryl groups at α-positions have been synthesized and its optical, emission, electrochemical and third-order nonlinear optical properties were investigated. Both the Soret and Q-bands were red-shifted and obeyed Beer–Lambert's law. Electrochemical properties indicated that both oxidation and reduction processes were ring centered. Emission spectra were recorded in different solvents and the fluorescence yields obtained were in the range of 0.02 while time-resolved fluorescence data revealed lifetimes of typically few ns. Excited state dynamics in this novel thio-zinc phthalocyanine molecule has been investigated using femtosecond (fs) degenerate pump-probe spectroscopy. Nonlinear optical properties of this molecule have been examined using the Z-scan technique with picosecond (ps) and fs pulses. Both open and closed aperture Z-scan curves were recorded with ~2 ps/~150 fs laser pulses at a wavelength of 800 nm and nonlinear optical coefficients were extracted from both the studies. Degenerate pump-probe data performed at 600 nm suggested a single long lifetime of ~300 ps, possibly originating from the non-radiative decay of S1 state.

Synthesis, characterization and third order nonlinear optical properties of trans-A2B-tpye cobalt corroles

2021 ◽  
Author(s):  
Guifen Lu ◽  
Peng Zhang ◽  
Yuanyuan Fang ◽  
Yongjie Gao ◽  
Qikang Hu
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Para Position ◽  
Third Order

A series of trans-A2B cobalt corroles, represented as [Cor(p-RPh)2(p-NO2Ph)]Co(PPh3) (1-5), where Cor is trianion of corrole, R is a CN, F, CH3, C(CH3)3 or PhCH2O on the para-position of the...

Optical, electrochemical and third-order nonlinear optical studies of triphenylamine substituted zinc phthalocyanine

2016 ◽  
Vol 20 (08n11) ◽  
pp. 1173-1181 ◽  
Author(s):  
Narra Vamsi Krishna ◽  
Puliparambil Thilakan Anusha ◽  
S. Venugopal Rao ◽  
L. Giribabu
Keyword(s):  
Nonlinear Optical ◽  
Emission Spectra ◽  
Optical Emission ◽  
Soret Band ◽  
Laser Pulses ◽  
Zinc Phthalocyanine ◽  
Third Order ◽  
Time Resolved ◽  
Nlo Properties ◽  
Scan Data

Zinc phthalocyanine possessing triphenylamine at its peripheral position has been synthesized and its optical, emission, electrochemical and third-order nonlinear optical (NLO) properties were investigated. Soret band was broadened due to the presence of triphenylamine moiety. Electrochemical properties indicated that both oxidation and reduction processes were ring centered. Emission spectra were recorded in different solvents and the fluorescence yields obtained were in the range of 0.02–0.17 while the time-resolved fluorescence data revealed radiative lifetimes of typically few ns. Third-order NLO properties of this molecule have been examined using the Z-scan technique with picosecond (ps) and femtoseocnd (fs) pulses. Closed and open aperture Z-scan data were recorded with 2 ps/1 50 fs laser pulses at a wavelength of 800 nm and NLO coefficients were extracted from both the data. Our data clearly suggests the potential of this molecule for photonics applications.

Physical origin of the third-order nonlinear optical properties of polyenes

2005 ◽  
Vol 52 (14) ◽  
pp. 1933-1945 ◽  
Author(s):  
I. Fuks-Janczarek ◽  
I. V. Kityk * ◽  
J. Berdowski ◽  
B. Sahraoui ◽  
C. Andraud
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Physical Origin ◽  
Third Order ◽  
The Third

Heterometallic copper(II) vanadates: synthesis, crystal structures and third-order nonlinear optical properties

2014 ◽  
Vol 57 (9) ◽  
pp. 1235-1245 ◽  
Author(s):  
FaQian Liu ◽  
Lei Wang ◽  
JiXi Guo ◽  
WeiHua Li ◽  
ChaoQin Li ◽  
...  
Keyword(s):  
Optical Properties ◽  
Crystal Structures ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Third Order
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