Thermotectonic events recorded by U-Pb geochronology and Zr-in-rutile thermometry of Ti oxides in basement rocks along the P2 fault, eastern Athabasca Basin, Saskatchewan, Canada

Author(s):  
E. Adlakha ◽  
K. Hattori

Basement rocks below the Athabasca Basin, Saskatchewan, have been intensely altered through paleoweathering and multiple hydrothermal events, including the formation of world-class unconformity-type uranium deposits. Here, we demonstrate the utility of Ti-oxide thermochronology for identifying thermotectonic events in these altered rocks leading to uranium mineralization along basement structures. Rutile grains along the P2 fault, a major fault in the eastern Athabasca Basin, exhibit 207Pb/206Pb ages of ca. 1850−1700 Ma, with a weighted mean of 1757 ± 6 Ma (mean square of weighted deviation [MSWD] = 1.4, n = 116). The older ages (>1770 Ma) record regional metamorphism reaching a temperature of 875 °C during the Trans-Hudson orogeny. Pb diffusion modeling indicates that metamorphic rutile should exhibit cooling ages of 1760−1750 Ma. Rutile grains showing young ages, <1750 Ma, reflect isotopic resetting during regional asthenospheric upwelling between 1770 and 1730 Ma related to the emplacement of the Kivalliq igneous suite to the north. This thermotectonic event (temperature > 550 °C) promoted hydrothermal activity to produce silicified rocks, i.e., “quartzite,” along the P2 fault, which later focused mineralizing fluids for unconformity-type uranium deposits. The young rutile ages also indicate that the basement rocks remained hot until 1700 Ma, providing the maximum age for the deposition of the Athabasca sediments. Anatase yields a concordia age of 1569 ± 31 Ma (MSWD = 0.30, n = 5), which is within uncertainty of the oldest ages for uraninite of the McArthur River deposit. This age corresponds to the incursion of basinal fluids in the basement along the P2 fault during uranium mineralization.

2020 ◽  
Vol 105 (12) ◽  
pp. 1875-1888
Author(s):  
Erin E. Adlakha ◽  
Keiko Hattori ◽  
Mitchell J. Kerr ◽  
Brandon M. Boucher

Abstract Titanium oxide minerals along the P2 fault in the eastern Athabasca Basin are characterized to constrain their origin and the geological history of the area. Two types of rutile are recognized in the basement rocks. Early rutile is disseminated in graphitic metapelite and quartzite, and it formed during regional metamorphism and post-metamorphic hydrothermal activity. Late rutile occurs as a needle-like alteration product of mica and likely formed during retrogression of the basement. In graphitic metapelite, early rutile commonly occurs with an assemblage of oxy-dravite, quartz, graphite, zircon, pyrite, biotite, and muscovite. In quartzite, rutile occurs with quartz, sillimanite, muscovite, and zircon. Metamorphic rutile is characterized by high Nb/Ta ratios (up to 47) with high concentrations of U (up to 126 ppm) and V4+ (up to 1.44 wt%; V valance calculated from EPMA data). Hydrothermal rutile contains distinctly low Nb/Ta (as low as 4.80) with high Ta (≤3050 ppm), and relatively low V (as V 3+; as low as 0.02 wt%) and U (as low as 9.06 ppm), reflecting fluids in reduced oxidation conditions. Anatase forms small anhedral (rarely coarse and euhedral) grains in the basal sandstones and altered basement rocks. In sandstones, anatase occurs with the late diagenetic mineral assemblage, whereas in basement rocks it commonly occurs with the clay-sized minerals related to uranium mineralization. In both rocks, anatase likely formed through the dissolution of rutile and/or other Ti-bearing minerals. Anatase is characterized by variably high Fe (up to 0.99 wt%; possibly contributed by hematite micro-or nanoinclusions) and U (up to 180 ppm). The mineral assemblages and composition of anatase suggest its protracted crystallization from relatively low temperature, oxidizing, acidic, uraniferous fluids of the sandstones during late diagenesis and hydrothermal activity. Therefore, the occurrence of anatase records the incursion of basin fluids into the basement, and the interaction of basement rocks with fluids responsible for the formation of the McArthur River uranium deposit. The results of this study confirm that Ti-oxides are useful in unraveling the geological history of an area that underwent prolonged hydrothermal activity.


2020 ◽  
pp. geochem2020-030
Author(s):  
Dillon Johnstone ◽  
Kathryn Bethune ◽  
Colin Card ◽  
Victoria Tschirhart

The Patterson Lake corridor is situated along the southwest margin of the Athabasca Basin and contains several basement-hosted uranium deposits and prospects. Drill core investigations during this study have determined that granite, granodiorite, mafic and alkali intrusive basement rocks are entrained in a deep-seated northeast-striking subvertical heterogeneous high-strain zone defined by anastomosing ductile to semi-brittle shears and brittle faults. The earliest phases of ductile deformation (D1/2), linked with Taltson (1.94–1.92 Ga) orogenesis, involved interference between early fold sets (F1/2) and development of an associated ductile transposition foliation (S1/2). During subsequent Snowbird (ca. 1.91–1.90 Ga) tectonism, this composite foliation was re-folded (D3) by northeast-trending buckle-style folds (F3), including a regional fold centered on the Clearwater aeromagnetic high. In continuum with D3, a network of dextral-reverse chloritic-graphitic shears, with C-S geometry, formed initially (D4a) and progressed to more discrete, spaced semi-brittle structures (D4b; ca. 1.900–1.819 Ga). Basin development (D5a; <ca. 1.819 Ga) was marked by a set of north-striking normal faults and related east- and northeast-striking transfer faults that accommodated subsidence. Primary uranium mineralization (D5b; ∼1.45 Ga) was facilitated by brittle reactivation of northeast-striking basement shears in response to west-southwest - east-northeast-directed compressional stress (σ1). Uraninite was emplaced along σ1-parallel extension fractures and dilational zones formed at linkages between northeast- and east-northeast-striking dextral strike-slip faults. Uranium remobilization (D5c) occurred after σ1 shifted to west-northwest – east-southeast, giving rise to regional east- and southeast-striking conjugate faults, along which mafic dykes (1.27 Ga and 1.16 Ga) intruded.Thematic collection: This article is part of the Uranium Fluid Pathways collection available at: https://www.lyellcollection.org/cc/uranium-fluid-pathways


Author(s):  
Daniel Peter Ferguson ◽  
Guoxiang Chi ◽  
Charles Normand ◽  
Patrick Ledru ◽  
Odile Maufrais-Smith

The Athabasca Basin in northern Saskatchewan is host to many world-class uranium deposits associated with the unconformity between the Paleoproterozoic sandstone of the basin and the underlying crystalline basement (Jefferson et al., 2007).  While the style and tonnage of these deposits vary, the current genetic model for unconformity-related uranium deposits has been a practical tool for exploration in the Athabasca Basin. However, the factors which control the location and formation of these deposits is still not fully understood. A paragenetic and petrographic study of mineralization along the Midwest Trend, located on the northeastern margin of the Athabasca Basin, aims to refine the current model and to address the general problem: What are the factors which control mineralization and non-mineralization? The Midwest Trend will be used as a "modèle réduit" for uranium mineralization, as it displays many features characteristic of unconformity type deposits. The Midwest Trend comprises three mineral leases that encompass two uranium deposits, the Midwest Main and Midwest A (Allen et al., 2017a, b). Mineralization occurs along a NE-trending graphitic structure, and is hosted by the sandstone, at the unconformity, and in much lesser amounts in the underlying basement rocks. Petrographic observations aided by the use of RAMAN spectroscopy and SEM-EDS, have been used to create a paragenetic sequence of mineralization (Fig.1). Future work will focus on fluid inclusion studies using microthermometry, LA-ICP-MS, and mass spectrometry of contained gases. References:Allen, T., Quirt, D., Masset, O. (2017a). Midwest A Uranium Deposit, Midwest Property, Northern Mining District, Saskatchewan, NTS Map Area 741/8: 2017 Mineral Resource Technical Report. AREVA Resources Canada Inc. Internal Report No. 17-CND-33-01. Allen, T., Quirt, D., Masset, O. (2017b). Midwest Main Uranium Deposit, Midwest Property, Northern Mining District, Saskatchewan, NTS Map Area 741/8: 2017 Mineral Resource Technical Report. AREVA Resources Canada Inc. Internal Report No. 17-CND-33-01. Jefferson, C.W., Thomas, D.J., Gandhi, S.S., Ramaekers, P., Delaney, G., Brisbin, D., Cutts, C., Portella, P., and Olson, R.A., 2007: Unconformity-associated uranium deposits of the Athabasca Basin, Saskatchewan and Alberta. Geological Survey of Canada, Bulletin 588, p. 23–67.


1993 ◽  
Vol 30 (4) ◽  
pp. 653-673 ◽  
Author(s):  
P. Bruneton

The Cigar Lake uranium deposit occurs within the Athabasca Basin of northern Saskatchewan, Canada. Like other major uranium deposits of the basin, it is located at the unconformity separating Helikian sandstones of the Athabasca Group from Aphebian metasediments and plutonic rocks of the Wollaston Group. The Athabasca Group was deposited in an intra-continental sedimentary basin that was filled by fluviatile terrestrial quartz sandstones and conglomerates. The group appears undeformed and its actual maximum thickness is about 1500 m. On the eastern side of the basin, the detrital units correspond to the Manitou Falls Formations where most of the uranium deposits are located. The Lower Pelitic unit of the Wollaston Group, which lies directly on the Archean basement, is considered to be the most favourable horizon for uranium mineralization. During the Hudsonian orogeny (1800–1900 Ma), the group underwent polyphase deformation and upper amphibolite facies metamorphism. The Hudsonian orogeny was followed by a long period of erosion and weathering and the development of a paleoweathering profile.On the Waterbury Lake property, the Manitou Falls Formation is 250–500 m thick and corresponds to units MFd, MFc, and MFb. The conglomeratic MFb unit hosts the Cigar Lake deposit. However, the basal conglomerate is absent at the deposit, wedging out against an east–west, 20 m high, pre-Athabasca basement ridge, on top of which is located the orebody.Two major lithostructural domains are present in the metamorphic basement of the property: (1) a southern area composed mainly of pelitic metasediments (Wollaston Domain) and (2) a northern area with large lensoid granitic domes (Mudjatik Domain). The Cigar Lake east–west pelitic basin, which contains the deposit, is located in the transitional zone between the two domains. The metamorphic basement rocks in the basin consist mainly of graphitic metapelitic gneisses and calcsilicate gneisses, which are inferred to be part of the Lower Pelitic unit. Graphite- and pyrite-rich "augen gneisses," an unusual facies within the graphitic metapelitic gneisses, occur primarily below the Cigar Lake orebody.The mineralogy and geochemistry of the graphitic metapelitic gneisses suggest that they were originally shales. The abundance of magnesium in the intercalated carbonates layers indicates an evaporitic origin.The structural framework is dominated by large northeast–southwest lineaments and wide east–west mylonitic corridors. These mylonites, which contain the augen gneisses, are considered to be the most favourable features for the concentration of uranium mineralization.Despite the presence of the orebody, large areas of the Waterbury Lake property remain totally unexplored and open for new discoveries.


1995 ◽  
Vol 32 (6) ◽  
pp. 787-805 ◽  
Author(s):  
W. G. Powell ◽  
D. M. Carmichael ◽  
C. J. Hodgson

Regional metamorphism, ranging in grade from the subgreenschist-facies to the greenschist–amphibolite-facies transition, affects all Archean supracrustal rocks (>2677 Ma) in the Rouyn–Noranda area. Contact metamorphic minerals associated with the posttectonic Preissac–Lacorne batholith (2643 Ma) show no evidence of a regional retrograde event. Accordingly, the age of regional metamorphism can be bracketed between 2677 and 2643 Ma. Three reaction isograds were mapped in subgreenschist-facies metabasites, dividing the low-grade rocks into three metamorphic zones: the pumpellyite–actinolite zone, the prehnite–pumpellyite zone, and the prehnite–epidote zone. In addition, the pumpellyite–actinolite–epidote–quartz bathograd, corresponding to a pressure of approximately 200 MPa, occurs on both sides of the Porcupine–Destor fault. Low-pressure regional metamorphism is also indicated both by the occurrence of an actinolite–oligoclase zone, and the persistence of pre-regional-metamorphic andalusite. The coincidence of andalusite and the actinolite-oligoclase zone indicates that pressure was <330 MPa at the greenschist-amphibolite transition. The geothermal gradient during metamorphism was approximately 30 °C/km. Regionally, isograds dip shallowly to the north and trend subparallel to lithological and structural trends. Metamorphic minerals in metabasites define tectonic fabrics only near major fault zones and in zones of CO2 metasomatism. In biotite zone metasedimentary rocks the schistosity is defined by mica and amphibole. These textures indicate that metamorphism and fabric development were coeval. However, the actinolite–epidote isograd cuts the Porcupine–Destor fault, indicating that regional metamorphism postdates movement along this fault. The strong fabrics associated with the Porcupine–Destor and Larder Lake–Cadillac faults must have developed through a process dominated by flattening strain.


2019 ◽  
Vol 109 ◽  
pp. 426-447 ◽  
Author(s):  
Yin Chen ◽  
Ruoshi Jin ◽  
Peisen Miao ◽  
Jianguo Li ◽  
Hu Guo ◽  
...  

2002 ◽  
Vol 39 (1) ◽  
pp. 113-132 ◽  
Author(s):  
C Renac ◽  
T K Kyser ◽  
K Durocher ◽  
G Dreaver ◽  
T O'Connor

The Paleoproterozoic Thelon Basin, located on the border between Nunavut and the Northwest Territories of Canada, is a contemporaneous analog of the uranium-rich Paleoproterozoic Athabasca Basin in Canada. Early diagenesis resulted in precipitation of extensive hematite on the surfaces of detrital quartz grains throughout the Thelon Formation and minor hydroxy-phosphate in veins locally. Continued diagenesis then resulted in syntaxial quartz cementation of detrital quartz at 130°C from fluids having ca. 17 wt.% equivalent NaCl, similar to the Athabasca Basin. Cementation of this type is most pronounced in fine-grained sequences in the Thelon Basin. A period of extensive desilicification during continued burial was followed by formation, at ca. 200°C, of peak-diagenetic illite having Ar–Ar ages of ca. 1400–1690 Ma in the Thelon Formation. This illite was associated with fluids with δ18O and δD values of ca. 6‰ and –50‰, respectively, similar to those during peak diagenesis of the Athabasca Basin. Although the timing, salinity, and isotopic composition of the peak-diagenetic fluids in the Thelon and Athabasca Basins are similar, the peak-diagenetic mineral assemblage in the Athabasca Formation is dickite and illite, with minor dravite and goyasite rather than simply illite. Consequently, the fluids at peak diagenesis, which in the Athabasca Basin are synchronous with formation of world-class unconformity-type uranium deposits, had different compositions in each basin. Post-peak diagenesis in the Thelon Basin was quite distinct from that in the Athabasca Basin in that illite was replaced in the central portion of the basin by K-feldspar and then sudoite, which crystallized from saline brines at ca. 1000 Ma and 100°C. Evidence for later infiltration of these brines is absent in the Athabasca Basin, although uranium mobilization at ca. 900 Ma from fluids having the same characteristics as those at peak diagenesis was pronounced in the Athabasca Basin. Recent incursion of meteoric waters along reactivated structures into the Athabasca Basin has variably affected hydrous and uraniferous minerals, but evidence for this is lacking in the Thelon Basin. The Thelon Basin reflects less intensive fluid–rock interaction in its early history than that recorded in the basal units of the Athabasca Basin.


1992 ◽  
Vol 29 (8) ◽  
pp. 1623-1639 ◽  
Author(s):  
G. L. Cumming ◽  
D. Krstic

Age data are presented for major Athabasca Basin uranium deposits at Cigar Lake, Cluff Lake, Collins Bay, Dawn Lake, Eagle Point, McArthur River, Midwest, and Rabbit Lake, as well as for several minor or undeveloped deposits, including Hughes Lake and Nisto. The best constrained data indicate that almost all the deposits formed in a restricted time interval between about 1330 and 1380 Ma. This range of ages is believed to be real and not the result of uncertainties in the calculation of ages based on discordant data. The one major exception is the recently discovered NiAs-free deposit at McArthur River, for which a well-determined age of 1514 ± 18 Ma (2σ) has been obtained. Even this deposit yields an age in the1330–1380 Ma range for some material. Periods of reworking–redeposition occurred at ~1280, ~1000, ~575, and ~225 Ma. These may be basin-wide, affecting to some degree all the deposits that we have studied. Other times of redeposition are less well determined, but may be present as well. No ages that approach the ~1700 Ma age of the Athabasca Group have been found to date for unconformity-related deposits, and the Athabasca Basin mineralization is unrelated to the ~1750 Ma pitchblende vein deposits in the Beaverlodge Lake area.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-30
Author(s):  
Antonio Benedicto ◽  
Maher Abdelrazek ◽  
Patrick Ledru ◽  
Cameron MacKay ◽  
Dwayne Kinar

The occurrence of unconformity-related uranium mineralization requires the combination of three components: fluids with the right composition, geochemical traps with the right agents that produce precipitation, and structural traps with the right geometry. In the Athabasca Basin unconformity-related uranium deposits, while basinal brines are commonly accepted as the principal mineralized fluids and graphite and gases (CH4, CO2, and H2S) are well known as the reductants, only few case studies describing structural traps are published. A number of recent works, including numerical modelling, have improved the understanding of the role of inherited shear zones on fluid flow and the development of uranium deposits at a micro- and regional-scale. Nevertheless, there is still a lack of knowledge about the meso- or deposit-scale structural controls that lead to the present (and potentially predictive) localization of uranium deposits along a given shear zone. The present work examines new structural data from drill holes and deals with (i) the identification of mesoscale structural traps that lead to the formation of the Athabasca unconformity-related uranium deposits hosted within the basement and (ii) with the understanding of the role and mode of reactivation of the inherited shear zones. The Sue deposits (McClean Project), the Tri-Island showing (Martin Lake Project) in the Eastern Athabasca, and the Spitfire prospect (Hook Lake Project) in the Western Athabasca have been selected for a detailed analysis of structures and related uranium mineralization. The structural analysis performed brings new insights about the mesoscale structural controls, the role the inherited ductile fabric had on the mode of brittle reactivation and to trap mineralization, and the tectonic regime to which basement-hosted uranium deposits may be associated in the Athabasca Basin.


2020 ◽  
Vol 57 (11) ◽  
pp. 1312-1323
Author(s):  
Brandi M. Shabaga ◽  
Mostafa Fayek ◽  
David Quirt ◽  
Patrick Ledru

The Thelon Basin is temporally and spatially related to the Athabasca Basin in Saskatchewan, Canada, which hosts the highest-grade unconformity-related uranium deposits in the world. Several uranium deposits occur within the Aberdeen sub-basin of the Thelon Basin, and it has been suggested that they may also be unconformity-related deposits. However, the genesis of the deposits is still debated and the age of the uranium mineralization event remains loosely constrained. In this study, we use secondary ion mass spectrometry to measure three sulphur (S) isotopes in pyrite from the Kiggavik deposit to constrain the sources of sulphur. We use this information to determine whether these sulphides, if dated by the Re–Os method, would provide a better constraint on the timing of uranium mineralization. The Kiggavik deposit comprises three zones (Main, Centre, and East) that formed from ∼200 °C fluids at ∼1600 Ma. Non-hydrothermal pyrite and galena from all three zones have a wide range of δ34S values, from −41.2‰ to +37.4‰. The Δ33S values (>0‰) indicate recycling of mass independent fractionation sulphur, suggesting that pyrite from the Kiggavik deposit derived sulphur from the Neoarchean metagraywacke host rock. The preservation of these anomalous Δ33S values suggests that the pyrite formed from low-temperature processes rather than hydrothermal processes. Low-temperature, high-latitude fluids may have been involved in the formation of the pyrite because some of these sulphides are also associated with uranium minerals that are devoid of Pb and contain corroded calcite. Based on these data, Re–Os geochronology of these sulphides would not yield an age that would constrain the timing of hydrothermal uranium mineralization.


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