Salts and Complexes Containing the Decachloro-closo-Decaborate Anion

2021 ◽  
Vol 47 (8) ◽  
pp. 519-545
Author(s):  
V. V. Avdeeva ◽  
E. A. Malinina ◽  
K. Yu. Zhizhin ◽  
N. T. Kuznetsov
Keyword(s):  
Closo Decaborate Anion

Features of Formation of Mononuclear and Binuclear Copper(II) Complexes with 2,2'-Bipyridyl and closo-Decaborate Anion

2020 ◽  
Vol 65 (9) ◽  
pp. 1343-1350
Author(s):  
E. A. Malinina ◽  
V. V. Avdeeva ◽  
S. E. Korolenko ◽  
S. E. Nefedov ◽  
L. V. Goeva ◽  
...  
Keyword(s):  
Binuclear Copper ◽  
Closo Decaborate Anion

Features of the formation of zinc(II) and cadmium(II) complexes with the inner-sphere and outer-sphere position of the decahydro-closo-decaborate anion in the presence of azaheterocyclic ligands

2021 ◽  
Vol 520 ◽  
pp. 120315
Author(s):  
Svetlana E. Korolenko ◽  
Aleksey S. Kubasov ◽  
Lyudmila V. Goeva ◽  
Varvara V. Avdeeva ◽  
Elena A. Malinina ◽  
...  
Keyword(s):  
Outer Sphere ◽  
Inner Sphere ◽  
Closo Decaborate Anion

Fifty years of the closo-decaborate anion chemistry

2010 ◽  
Vol 75 (11) ◽  
pp. 1149-1199 ◽  
Author(s):  
Igor B. Sivaev ◽  
Alexander V. Prikaznov ◽  
Daoud Naoufal
Keyword(s):  
Oxidation Reactions ◽  
Hydrogen Atoms ◽  
Main Attention ◽  
First Report ◽  
General Stability ◽  
Closo Decaborate Anion

The review covers the fifty-year period of chemistry of the closo-decaborate anion [B10H10]2– from the first report by Hawthorne and Pitochelli. The main attention is paid to reactions of substitution of various atoms and groups for hydrogen atoms. The general stability of the closo-decaborate cage, including its protonation, cage-opening and cage oxidation reactions, is considered as well. A review with 242 references.

Nickel(II) Complexes with Azaheterocyclic Ligands and 2-Hydroxy-closo-Decaborate Anion [2-B10H9OH]2–

2021 ◽  
Vol 66 (2) ◽  
pp. 187-192
Author(s):  
E. Yu. Matveev ◽  
I. V. Novikov ◽  
A. S. Kubasov ◽  
V. M. Retivov ◽  
K. Yu. Zhizhin ◽  
...  
Keyword(s):  
Closo Decaborate Anion

scholarly journals Silver(I) and Copper(I) Complexation with Decachloro-Closo-Decaborate Anion

Crystals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 389
Author(s):  
Varvara V. Avdeeva ◽  
Grigoriy A. Buzanov ◽  
Elena A. Malinina ◽  
Nikolay T. Kuznetsov ◽  
Anna V. Vologzhanina
Keyword(s):  
Complexation Reaction ◽  
Similar Reaction ◽  
Cluster Anions ◽  
X Ray Diffraction ◽  
Reaction Conditions ◽  
Boron Cluster ◽  
Composition And Structure ◽  
Coinage Metals ◽  
Closo Decaborate Anion ◽  
Complexation Reactions

A series of complexation reactions of silver(I) and copper(I) in the presence of a polyhedral weakly coordinating [B10Cl10]2− anion has been carried out. The effect of the solvent and the presence of Ph3P on the composition and structure of the reaction product were studied. Eight novel complexes were obtained and characterized by 11B Nuclear magnetic resonance, Infra-Red, and Raman spectroscopies as well as powder and single-crystal X-ray diffraction techniques. The [B10Cl10]2− anion demonstrated weaker coordinating ability towards coinage metals than [B10H10]2− at similar reaction conditions. The [B10Cl10]2− anion remains unreacted in the copper(I) complexation reaction, while in the absence of competing ligands, we obtained the first complexes containing decachloro-closo-decaborate anion directly coordinated by the metal atom. The bonding between metal atoms and the boron cluster anions was studied using the atomic Hirshfeld surfaces. Besides edge and face coordination of the polyhedral anion, this method allowed us to reveal the Ag–Ag bond in crystal of {Ag2(DMF)2[B10Cl10]}n, the presence of which was additionally supported by the Raman spectroscopy data.

Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type

2018 ◽  
Vol 483 (1) ◽  
pp. 263-265 ◽  
Author(s):  
A. S. Kubasov ◽  
E. Yu. Matveev ◽  
E. S. Turyshev ◽  
I. N. Polyakova ◽  
A. Yu. Bykov ◽  
...  
Keyword(s):  
Closo Decaborate Anion

A new method for the synthesis of carboxonium derivatives of the closo-decaborate anion [2,6-B10H8(O2CR)]–, where R = CH3, C2H5

2017 ◽  
Vol 62 (11) ◽  
pp. 1479-1482 ◽  
Author(s):  
I. N. Klyukin ◽  
A. P. Zhdanov ◽  
A. Yu. Bykov ◽  
G. A. Razgonyaeva ◽  
M. S. Grigor’ev ◽  
...  
Keyword(s):  
New Method ◽  
Closo Decaborate Anion ◽  
Derivatives Of

Decachloro-closo-decaborate anion in copper(II) complexation reactions with N-donor ligands: 35Cl NQR and X-ray studies

Polyhedron ◽  
2017 ◽  
Vol 127 ◽  
pp. 238-247 ◽  
Author(s):  
V.V. Avdeeva ◽  
E.A. Kravchenko ◽  
A.A. Gippius ◽  
A.V. Vologzhanina ◽  
E.A. Malinina ◽  
...  
Keyword(s):  
Donor Ligands ◽  
X Ray ◽  
35Cl Nqr ◽  
Closo Decaborate Anion ◽  
Complexation Reactions

Thermal oxidation of the decahydro-closo-decaborate anion B10H 10 2− in a silicate matrix

2015 ◽  
Vol 51 (5) ◽  
pp. 498-502 ◽  
Author(s):  
V. K. Skachkova ◽  
L. V. Goeva ◽  
A. V. Grachev ◽  
V. V. Avdeeva ◽  
E. A. Malinina ◽  
...  
Keyword(s):  
Thermal Oxidation ◽  
Silicate Matrix ◽  
Closo Decaborate Anion
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