Activity coefficients of NaNO3 in (Mg, Ca, Sr, and Ba)(NO3)2 + H2O systems at 298 K by EMF methods

1993 ◽  
Vol 71 (3) ◽  
pp. 384-389 ◽  
Author(s):  
Stephen N. Smith ◽  
S. Sarada ◽  
Ramamurthy Palepu
Keyword(s):  
Free Energy ◽  
Ionic Strength ◽  
Gibbs Free Energy ◽  
Activity Coefficients ◽  
Interaction Parameters ◽  
Excess Gibbs Free Energy ◽  
Experimental Activity ◽  
Energy Of Mixing ◽  
Total Ionic Strength ◽  
Free Energy Of Mixing

The activity coefficients of NaNO3 in Mg(NO3)2, Ca(NO3)2, Sr(NO3)2 and Ba (NO3)2 were determined at constant total ionic strength of 0.1, 0.5, 0.75, 1.0, 1.5, and 2.0 mol kg−1 at 298 K using EMF methods. The experimental activity coefficients were analyzed using four different formalisms, namely, Reilly–Wood–Robinson, Scatchard, Pitzer, and Harned equations, and the interaction parameters were evaluated. Excess Gibbs free energy of mixing and trace activity coefficients were calculated and the results are discussed.

scholarly journals Thermodynamic, structural, surface and transport properties of Au-Ni liquid alloy at 1150 K

BIBECHANA ◽  
2021 ◽  
Vol 18 (1) ◽  
pp. 184-192
Author(s):  
S K Yadav ◽  
N Chaudhary ◽  
D Adhikari
Keyword(s):  
Free Energy ◽  
Transport Properties ◽  
Gibbs Free Energy ◽  
Liquid Alloy ◽  
Concentration Fluctuation ◽  
Excess Gibbs Free Energy ◽  
Long Wavelength ◽  
Energy Of Mixing ◽  
Structural Surface ◽  
Free Energy Of Mixing

Thermodynamic, structural, surface, and transport properties of Au-Ni liquid alloy at 1150 K were computed using different theoretical approaches. The thermodynamic properties, such as excess Gibbs free energy of mixing, enthalpy of mixing, activity and excess entropy of mixing, and structural properties, such as concentration fluctuation in long-wavelength limit and Warren-Cowley short-range order parameter were computed in the framework of Flory’s model. The effect of positive and negative values of the interchange energy parameter on the excess Gibbs free energy of mixing and concentration fluctuation in the long-wavelength limit was also observed. The surface tension and surface concentration of the system were calculated using Butler’s model. In the transport property, the viscosity of the system was calculated using Kaptay and Budai-Benko-Kaptay (BBK) models. BIBECHANA 18 (2021) 184-192

THERMODYNAMICS OF COMPOUND FORMING MOLTEN Cu–In ALLOYS

2008 ◽  
Vol 22 (27) ◽  
pp. 4833-4844 ◽  
Author(s):  
Y. A. ODUSOTE
Keyword(s):  
Free Energy ◽  
Thermodynamic Properties ◽  
Gibbs Free Energy ◽  
Chemical Diffusion ◽  
Interaction Parameters ◽  
Ideal Behavior ◽  
Mixing Properties ◽  
Long Wavelength ◽  
Energy Of Mixing ◽  
Free Energy Of Mixing

A study of the thermodynamic properties of Cu in molten Cu – In alloys has been explained using a compound formation model. We use the model to deduce information on thermodynamic properties of the alloy such as the Gibbs free energy of mixing, the enthalpy and entropy of mixing. In this study, we first model the Gibbs free energy in terms of the interaction parameters. Sequel to this, the interaction parameters are utilized to quantify properties such as the concentration–concentration fluctuations in the long wavelength limit, the Warren–Cowley short-range order parameter, and the chemical diffusion. Both positive and negative deviations from Raoultian behavior and concentration-dependent asymmetry in the mixing properties of CuIn 4 liquid alloys were reported. Our analysis suggest that the liquid alloy undergoes a transformation from an ordered ( In -rich end) to segregating ( Cu -rich end) state. The system also exhibits ideal behavior at the Cu -rich end.

Calculation on the Free Energy of Mixing of some Silane Systems

2011 ◽  
Vol 391-392 ◽  
pp. 1017-1021
Author(s):  
Ru Zhang ◽  
Yan Fen Wu ◽  
Ping Hu
Keyword(s):  
Free Energy ◽  
Thermodynamic Properties ◽  
Activity Coefficients ◽  
Influence Factors ◽  
Critical Parameters ◽  
Model Parameters ◽  
Free Energies ◽  
Wilson Model ◽  
Energy Of Mixing ◽  
Free Energy Of Mixing

Six binary silane systems were chosen to calculate the activity coefficients (γ) and free energies of mixing (ΔGm). These systems included: methyldichlorosilane + methyltrichlorosilane, methyldichlorosilane + methylvinyldichlorosilane, methyldichlorosilane + toluene, methyltrichlorosilane + methylvinyldichlorosilane, methyltrichlorosilane + toluene, methylvinyldichlorosilane + toluene. Based on the Antoine constants, critical parameters of the pure components and Wilson model parameters, γ and ΔGmwere calculated. The influence factors of these thermodynamic properties were also discussed.

Activity coefficients and excess Gibbs’ free energy of some binary mixtures formed by p-cresol at 95.23kPa

2007 ◽  
Vol 39 (7) ◽  
pp. 1022-1026 ◽  
Author(s):  
T.E. Vittal Prasad ◽  
N. Venkanna ◽  
Y. Naveen Kumar ◽  
K. Ashok ◽  
N.M. Sirisha ◽  
...  
Keyword(s):  
Free Energy ◽  
Gibbs Free Energy ◽  
Binary Mixtures ◽  
Activity Coefficients ◽  
Excess Gibbs Free Energy
Sign in / Sign up

Export Citation Format

Share Document