A scale-up nanoporous membrane centrifuge for reverse osmosis desalination without fouling
A scale-up nanoporous membrane centrifuge is designed and modeled. It can be used for nanoscale scale separation including reverse osmosis desalination. There are micron-size pores on the wall of the centrifuge and nanoscale pores on local graphene membrane patches that cover the micron-size pores. In this work, we derived the critical angular velocity required to counter-balance osmosis force, so that the reverse-osmosis (RO) desalination process can proceed. To validate this result, we conducted a large scale (four million atoms) full atom molecular dynamics (MD) simulation to examine the critical angular velocity required for reverse osmosis at nanoscale. It is shown that the analytical results derived based on fluid mechanics and the simulation results observed in MD simulation are consistent and well matched. The main advantage of such nanomaterial based centrifuge is its intrinsic anti-fouling ability to clear [Formula: see text] and [Formula: see text] ions accumulated at the vicinity of the pores due to the Coriolis effect. Analyses have been conducted to study the relation between osmotic pressure, centrifugal pressure, and water permeability.