Capacity Fading Machanism for Both Electrodes in Prismatic Lithium Ion Batteries with Long Calendar Life

2015 ◽  
Vol 89 (5) ◽  
pp. 894-897 ◽  
Author(s):  
Liu-Qun Zheng ◽  
Shu-Jun Li ◽  
Deng-Feng Zhang ◽  
Hai-Jun Lin ◽  
Yan-Yue Miao ◽  
...  

2013 ◽  
Vol 32 ◽  
pp. 31-34 ◽  
Author(s):  
Xingcheng Xiao ◽  
Dongjoon Ahn ◽  
Zhongyi Liu ◽  
Jung-Hyun Kim ◽  
Peng Lu

2015 ◽  
Vol 162 (10) ◽  
pp. A1935-A1939 ◽  
Author(s):  
Christopher J. Pelliccione ◽  
Yujia Ding ◽  
Elena V. Timofeeva ◽  
Carlo U. Segre

2020 ◽  
Vol 56 (3) ◽  
pp. 2347-2359
Author(s):  
Hao Liu ◽  
Ruikai Yang ◽  
Wen Yang ◽  
Changjiang Bai ◽  
Yong-Chun Li ◽  
...  

2015 ◽  
Vol 3 (20) ◽  
pp. 10715-10719 ◽  
Author(s):  
Yong-keon Ahn ◽  
Junwoo Park ◽  
Dalwoo Shin ◽  
Sanghun Cho ◽  
Si Yun Park ◽  
...  

Nanoporous anodic aluminium oxide (AAO) enables the direct utilization of lithium metal as an ideal anode, owing to a uniform current distribution. The electrochemical performance of the AAO separator is superior to commercial polypropylene, in terms of ionic conductivity, discharge capacity, and capacity fading.


2020 ◽  
Vol 20 (11) ◽  
pp. 7051-7056
Author(s):  
Jungwon Heo ◽  
Anupriya K. Haridas ◽  
Xueying Li ◽  
Rakesh Saroha ◽  
Younki Lee ◽  
...  

Transition metal oxide materials with high theoretical capacities have been studied as substitutes for commercial graphite in lithiumion batteries. Among these, SnO2 is a promising alloying reaction-based anode material. However, the problem of rapid capacity fading in SnO2 due to volume variation during the alloying/dealloying processes must be solved. The lithiation of SnO2 results in the formation of a Li2O matrix. Herein, the volume variation of SnO2 was suppressed by controlling the voltage window to 1 V to prevent the delithiation reaction between Li2O and Sn. Using this strategy the unreacted Li2O matrix was enriched with metallic Sn particles, thereby providing a pathway for lithium ions. The specific capacity decay in the voltage window of 0.05–3 V was 1.8% per cycle. However, the specific capacity decay was improved to 0.04% per cycle after the voltage window was restricted (in the range of 0.05–1 V). This strategy resulted in a specific capacity of 374.7 mAh g−1 at 0.1 C after 40 cycles for the SnO2 anode.


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