Inhibitory effect of thyme oil as an antioxidant for waste cooking oil biodiesel crystallization

2021 ◽  
pp. 0958305X2110613
Author(s):  
Gediz Uguz
Keyword(s):  
Oxidation Stability ◽  
Solid Fat Content ◽  
Waste Cooking Oil ◽  
Inhibitory Effect ◽  
Butylated Hydroxytoluene ◽  
Time Data ◽  
Antioxidant Power ◽  
Thyme Oil ◽  
Cooking Oil ◽  
Oil Extract

The effects of thyme oil extract as an antioxidant on crystallization properties of waste cooking oil biodiesel were investigated. The inhibitory effect was determined for ASTM D7545 standard method for biodiesel added with 1000, 2000, and 3000 ppm of additives by using oxifast device and compared with the chemical antioxidant butylated hydroxytoluene (BHT). Inhibition time data were determined by converting the oxidation stability analysis results. The crystallization temperatures (Tcr) of the samples were determined by using a Differential Scanning Calorimetry (DSC) technique. Tcr values of samples with antioxidants were decreased compared to the non-antioxidant biodiesel sample (B100). The order of antioxidant power was B100<B100T1<B100T2 = B100BHT1<B100BHT2<B100T3<B100BHT3. The solid fat content (SFC %) values were determined with different antioxidant concentrations versus different times. The minimum SFC % was determined in B100T3 and B100BHT3 in 3000 ppm antioxidant concentrations in 720 min. DSC results show that the crystallization onset temperatures for B100, B100T3, and B100BHT3 were −51.83 °C, −53.59 °C, and −54.15 °C, respectively. The kinetics of crystallization was determined and k and n values were calculated. The addition of thyme oil extract as a natural antioxidant has a positive effect on biodiesel oxidative stability for all concentrations.

Novel approaches for the production of bio-diesel using waste vegetable oil

2014 ◽  
Vol 3 (10) ◽  
pp. 3419
Author(s):  
Mohan Reddy Nalabolu* ◽  
Varaprasad Bobbarala ◽  
Mahesh Kandula
Keyword(s):  
Diesel Fuel ◽  
Oxidation Stability ◽  
Acid Value ◽  
Waste Cooking Oil ◽  
Flash Point ◽  
Carbon Residue ◽  
Fuel Properties ◽  
Present Moment ◽  
Total Acid ◽  
Cooking Oil

At the present moment worldwide waning fossil fuel resources as well as the tendency for developing new renewable biofuels have shifted the interest of the society towards finding novel alternative fuel sources. Biofuels have been put forward as one of a range of alternatives with lower emissions and a higher degree of fuel security and gives potential opportunities for rural and regional communities. Biodiesel has a great potential as an alternative diesel fuel. In this work, biodiesel was prepared from waste cooking oil it was converted into biodiesel through single step transesterification. Methanol with Potassium hydroxide as a catalyst was used for the transesterification process. The biodiesel was characterized by its fuel properties including acid value, cloud and pour points, water content, sediments, oxidation stability, carbon residue, flash point, kinematic viscosity, density according to IS: 15607-05 standards. The viscosity of the waste cooking oil biodiesel was found to be 4.05 mm2/sec at 400C. Flash point was found to be 1280C, water and sediment was 236mg/kg, 0 % respectively, carbon residue was 0.017%, total acid value was 0.2 mgKOH/g, cloud point was 40C and pour point was 120C. The results showed that one step transesterification was better and resulted in higher yield and better fuel properties. The research demonstrated that biodiesel obtained under optimum conditions from waste cooking oil was of good quality and could be used as a diesel fuel.

A comprehensive review on biodiesel cold flow properties and oxidation stability along with their improvement processes

RSC Advances ◽  
2015 ◽  
Vol 5 (105) ◽  
pp. 86631-86655 ◽  
Author(s):  
I. M. Monirul ◽  
H. H. Masjuki ◽  
M. A. Kalam ◽  
N. W. M. Zulkifli ◽  
H. K. Rashedul ◽  
...  
Keyword(s):  
Oxidation Stability ◽  
Waste Cooking Oil ◽  
Fatty Acid Esters ◽  
Flow Properties ◽  
Cold Flow ◽  
Animal Fats ◽  
Cooking Oil ◽  
Cold Flow Properties ◽  
Different Sources ◽  
Acid Esters

Biodiesel, which comprises fatty acid esters, is derived from different sources, such as vegetable oils from palm, sunflower, soybean, canola, Jatropha, and cottonseed sources, animal fats, and waste cooking oil.

scholarly journals Influence of Graphene Nano Particles and Antioxidants with Waste Cooking Oil Biodiesel and Diesel Blends on Engine Performance and Emissions

Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4306
Author(s):  
Sandeep Krishnakumar ◽  
T. M. Yunus Khan ◽  
C. R. Rajashekhar ◽  
Manzoore Elahi M. Soudagar ◽  
Asif Afzal ◽  
...  
Keyword(s):  
Volume Fraction ◽  
Volume Ratio ◽  
Waste Cooking Oil ◽  
Nano Particles ◽  
Butylated Hydroxytoluene ◽  
Superior Performance ◽  
Nano Particle ◽  
Compression Ignition Engine ◽  
Performance And Emission ◽  
Cooking Oil

The main reason for the limited usage of biodiesel is it tends to oxidize when exposed to air. It is anticipated that the addition of an antioxidant along with graphene nano particle improves combustion of diesel-biodiesel blend. In the present research biodiesel made from the transesterification of waste cooking oil is used. Three synthetic antioxidants butylated hydroxytoluene (BHT), 2(3)-t-butyl-4-hydroxyanisole (BHA) and tert butylhydroquinone (TBHQ) along with 30 ppm of graphene nano particle were added at a volume fraction of 1000 ppm to diesel–biodiesel blends (B20). The performance and emission tests were performed at constant engine speed of 1500 rpm. Because of the inclusion of graphene nano particles, surface area to the volume ratio of the fuel is augmented enhancing the mixing ability and chemical responsiveness of the fuel during burning causing superior performance, combustion and emission aspects of compression ignition engine. The results revealed that there was a slight increase in brake power and brake thermal efficiency of about 0.29%, 0.585%, 0.58% and 6.22%, 3.11%, 3.31% for B20GrBHT10000, B20GrBHA1000 and B20GrTBHQ1000, respectively, compared to B20. Additionally, BSFC, HC and NOx emissions were reduced to considerable levels for the reformed fuel.

Estimation of Recoverable Household Waste Cooking Oil and Life Cycle Analysis of Biodiesel Fuel Production

2008 ◽  
Vol 4 (4) ◽  
pp. 318-323 ◽  
Author(s):  
Hirotsugu KAMAHARA ◽  
Shun YAMAGUCHI ◽  
Ryuichi TACHIBANA ◽  
Naohiro GOTO ◽  
Koichi FUJIE
Keyword(s):  
Life Cycle ◽  
Life Cycle Analysis ◽  
Waste Cooking Oil ◽  
Household Waste ◽  
Biodiesel Fuel ◽  
Fuel Production ◽  
Cooking Oil

Synthesis and Characterization of Heterogeneous Solid Acid Catalyst from Alstonia Scolaris Stalks for Biodiesel Production using Waste Cooking Oil

2020 ◽  
Vol 10 ◽  
Author(s):  
Charishma Venkata Sai Anne ◽  
Karthikeyan S. ◽  
Arun C.
Keyword(s):  
Reaction Time ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Wood Biomass ◽  
Waste Wood ◽  
X Ray ◽  
Cooking Oil

Background: Waste biomass derived reusable heterogeneous acid based catalysts are more suitable to overcome the problems associated with homogeneous catalysts. The use of agricultural biomass as catalyst for transesterification process is more economical and it reduces the overall production cost of biodiesel. The identification of an appropriate suitable catalyst for effective transesterification will be a landmark in biofuel sector Objective: In the present investigation, waste wood biomass was used to prepare a low cost sulfonated solid acid catalyst for the production of biodiesel using waste cooking oil. Methods: The pretreated wood biomass was first calcined then sulfonated with H2SO4. The catalyst was characterized by various analyses such as, Fourier-transform infrared spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray Spectroscopy (EDS) and X-ray diffraction (XRD). The central composite design (CCD) based response surface methodology (RSM) was applied to study the influence of individual process variables such as temperature, catalyst load, methanol to oil molar ration and reaction time on biodiesel yield. Results: The obtained optimized conditions are as follows: temperature (165 ˚C), catalyst loading (1.625 wt%), methanol to oil molar ratio (15:1) and reaction time (143 min) with a maximum biodiesel yield of 95 %. The Gas chromatographymass spectrometry (GC-MS) analysis of biodiesel produced from waste cooking oil was showed that it has a mixture of both monounsaturated and saturated methyl esters. Conclusion: Thus the waste wood biomass derived heterogeneous catalyst for the transesterification process of waste cooking oil can be applied for sustainable biodiesel production by adding an additional value for the waste materials and also eliminating the disposable problem of waste oils.

Sign in / Sign up

Export Citation Format

Share Document