Critically Evaluated Propagation Rate Coefficients for Radical Polymerizations: Acrylates and Vinyl Acetate in Bulk (IUPAC Technical Report)

2021 ◽  
Author(s):  
Robin A. Hutchinson ◽  
Sabine Beuermann
Keyword(s):  
Vinyl Acetate ◽  
Propagation Rate ◽  
Rate Coefficients ◽  
Technical Report ◽  
Radical Polymerizations

scholarly journals Critically evaluated propagation rate coefficients for radical polymerizations: acrylates and vinyl acetate in bulk (IUPAC Technical Report)

2019 ◽  
Vol 91 (11) ◽  
pp. 1883-1888
Author(s):  
Robin A. Hutchinson ◽  
Sabine Beuermann
Keyword(s):  
Vinyl Acetate ◽  
Propagation Rate ◽  
Size Exclusion ◽  
Rate Coefficients ◽  
Data Sets ◽  
Chromatography Method ◽  
Benchmark Data ◽  
Technical Report ◽  
Exclusion Chromatography ◽  
Secondary Radical

Abstract Arrhenius parameters capturing the temperature dependence of radical polymerization propagation rate coefficients, kp, for methyl acrylate, butyl acrylate, and vinyl acetate in bulk are reported, based on the fitting of benchmark data sets compiled from independent laboratories using the pulsed-laser polymerization/size exclusion chromatography method. The reported kp values for acrylates hold for secondary-radical propagation and are needed to calculate effective propagation rate coefficients in situations where there is a significant population of mid-chain acrylate radicals resulting from backbiting, as will be the case at technically relevant temperatures. The results are compared to those previously reported for styrene and methacrylates to highlight the large differences in kp values seen between the major monomer families.

scholarly journals Critically Evaluated Rate Coefficients in Radical Polymerization - 8. Propagation Rate Coefficients for Vinyl Acetate in Bulk

2016 ◽  
Vol 218 (1) ◽  
pp. 1600357 ◽  
Author(s):  
Christopher Barner-Kowollik ◽  
Sabine Beuermann ◽  
Michael Buback ◽  
Robin A. Hutchinson ◽  
Thomas Junkers ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Propagation Rate ◽  
Rate Coefficients
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