Sintering Bi2O3–B2O3–ZnO ternary low temperature glass by hydration device to solidify iodine containing silver-coated silica gel

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Wenhong Han ◽  
Guilin Wei ◽  
Yi Liu ◽  
Xirui Lu ◽  
Shunzhang Chen ◽  
...  
Keyword(s):  
Silica Gel ◽  
Radioactive Iodine ◽  
Sintering Temperature ◽  
Glass Network ◽  
Solidification Process ◽  
Iodine Content ◽  
Sample Surface ◽  
Sintered Sample ◽  
Ft Ir ◽  
Sintering Method

Abstract A new glass solidification process aims at radioactive iodine waste was explored in order to reduce the possible harm to environment. Samples with different iodine content in silver-coated silica gel were pretreated by hydration device at 300 °C and then sintered at relatively low temperatures (500, 550 and 600 °C). XRD results show that AgI is mainly chemically fixed in the glass network with some AgI particles being physically wrapped by the glass. Moreover, as the sintering temperature reached to 550 °C, B element crystallized. SEM-EDS results show that Ag and I elements are enriched, while the other elements are evenly distributed. AFM results showed that the sample surface becomes rougher as the iodine content increases in the silver coated silica gel. The FT-IR results show that the structure of the sintered sample is mainly composed of [BiO3], [BiO6] and [BO3]. This study provides a new sintering method by hydration device for the treatment of radioactive iodine waste.

scholarly journals Effect of Sintering Temperature on Microstructure and Mechanical Properties of Hot-Pressed Fe/FeAl2O4 Composite

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 422
Author(s):  
Kuai Zhang ◽  
Yungang Li ◽  
Hongyan Yan ◽  
Chuang Wang ◽  
Hui Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Bending Strength ◽  
Sintering Temperature ◽  
Raw Materials ◽  
Hot Press ◽  
Microstructure And Mechanical Properties ◽  
Powder Particles ◽  
Hot Press Sintering ◽  
Sintering Method

An Fe/FeAl2O4 composite was prepared with Fe-Fe2O3-Al2O3 powder by a hot press sintering method. The mass ratio was 6:1:2, sintering pressure was 30 MPa, and holding time was 120 min. The raw materials for the powder particles were respectively 1 µm (Fe), 0.5 µm (Fe2O3), and 1 µm (Al2O3) in diameter. The effect of sintering temperature on the microstructure and mechanical properties of Fe/FeAl2O4 composite was studied. The results showed that Fe/FeAl2O4 composite was formed by in situ reaction at 1300 °C–1500 °C. With the increased sintering temperature, the microstructure and mechanical properties of the Fe/FeAl2O4 composite showed a change law that initially became better and then became worse. The best microstructure and optimal mechanical properties were obtained at 1400 °C. At this temperature, the grain size of Fe and FeAl2O4 phases in Fe/FeAl2O4 composite was uniform, the relative density was 96.7%, and the Vickers hardness and bending strength were 1.88 GPa and 280.0 MPa, respectively. The wettability between Fe and FeAl2O4 was enhanced with increased sintering temperature. And then the densification process was accelerated. Finally, the microstructure and mechanical properties of the Fe/FeAl2O4 composite were improved.

Properties of Artificial Lightweight Aggregates (ALAs) Made of Dredged Soil Mixed with Waste Catalyst Slag

2012 ◽  
Vol 174-177 ◽  
pp. 1079-1085 ◽  
Author(s):  
Si Nae Jo ◽  
Yoo Tack Kim ◽  
Seung Gu Kang ◽  
Chang Sam Kim
Keyword(s):  
Specific Gravity ◽  
Water Absorption ◽  
Lightweight Concrete ◽  
Sintering Temperature ◽  
Thermal Power ◽  
Lightweight Aggregates ◽  
Dredged Soil ◽  
Porous Carriers ◽  
Black Core ◽  
Sintering Method

The artificial lightweight aggregates (ALAs) were manufactured using dredged soil produced at thermal power plant and waste catalyst slag by direct sintering method at 1050~1250°C for 10min. The ALAs of 100% dredged soil showed the black core phenomenon even at the low sintering temperature as 1050°C and become lightened by bloating pores in black core area with sintering temperature. On the other hand, the aggregates with 100% waste catalyst slag did not showed black coring and bloating phenomenon and had the low forming ability and many cracks inside. Adding the dredged soil to the waste catalyst slag decrease the specific gravity by promoting the black coring and bloating inside. The water absorption(%) of ALAs decreased with sintering temperature. The ALAs fabricated in this study showed the specific gravity of 0.8~2.0 and water absorption of 2~16% so it could be applied to various fields such as the lightweight concrete or the field of the porous carriers for purification of a contaminated soil or water.

Decrease of sintering temperature by CuO doping of the 0.8Pb(Mg1/3Nb2/3)O3-0.2PbTiO3 ceramics prepared by reaction-sintering method

2011 ◽  
Vol 209 (2) ◽  
pp. 254-261 ◽  
Author(s):  
Bijun Fang ◽  
Na Jiang ◽  
Chenlu Ding ◽  
Qingbo Du ◽  
Jianning Ding
Keyword(s):  
Sintering Temperature ◽  
Reaction Sintering ◽  
Sintering Method

Preparation and Electrical Property of Calcia Stabilized Zirconia Ceramics

2014 ◽  
Vol 616 ◽  
pp. 157-165 ◽  
Author(s):  
Chang Lian Chen ◽  
Hong Quan Wang ◽  
Jia You Ji ◽  
Ma Ya Luo ◽  
Bo Wu ◽  
...  
Keyword(s):  
Grain Size ◽  
Electrical Property ◽  
Arrhenius Equation ◽  
Sintering Temperature ◽  
Raw Materials ◽  
Cubic Phase ◽  
Pressureless Sintering ◽  
Stabilized Zirconia ◽  
Zirconia Ceramics ◽  
Sintering Method

In this paper, using ZrO2 and Ca (NO3)•4H2O as raw materials, we prepared a series of calica stabilized zirconia (CSZ) ceramics by pressureless sintering method. The results show that the relative densities of all sintered samples are above 90%, and the sintered samples are composed of cubic, tetragonal and monoclinic ZrO2, and the main phase is cubic ZrO2 and tetragonal ZrO2. The content of cubic phase increases with the increase of sintering temperature and adding CaO content. The grain size of the sintered samples is relatively uniform and some pores exist. Increasing the additive amount of CaO, the conductivity first rises and then decreases, and the conductivity value of the sample containing 5wt% CaO is the maximum. When the sintering temperature is up to 1600 oC, the conductivity of the sample containing 5wt% CaO is up to 0.016S•cm-1 at 800 oC. Furthermore, the conductivity of sintered samples is increasing with the increase of test temperature according to the Arrhenius equation.

Preparation and Microstructure of Pressureless Sintered Si2ON2-SiC Ceramic

2011 ◽  
Vol 335-336 ◽  
pp. 699-703
Author(s):  
Hui Hui Tan ◽  
Zhu Xing Tang ◽  
Xia Zhao ◽  
He Zhang
Keyword(s):  
Bulk Density ◽  
Sintering Temperature ◽  
Pressureless Sintering ◽  
Nitriding Temperature ◽  
X Ray Diffraction ◽  
X Ray ◽  
Effect Of Additives ◽  
Sic Ceramic ◽  
Sintering Method ◽  
Scanning Electron

This paper introduces Si2ON2-SiC ceramic fabricated by pressureless sintering method and studies the effect of additives, nitriding temperatures on bulk density, porosity, phase composition and microstructure. It is discovered that additives MgO, CeO2 can increase the densities of Si2ON2-SiC ceramic apparently, and MgO additive has a better effect than CeO2. Nitriding temperature also is an important factor. The bulk density of the specimen with MgO additive reaches maximum at 1.91 g/cm3 when sintered at 1450 °C, and the bulk density of specimen with CeO2 additive is 1.86 g/cm3 at the same condition while the bulk density of the specimen without additive is only 1.75 g/cSuperscript textm3. The X-ray diffraction and scanning electron microscopy of the specimens show that the amount of Si2ON2 increase with the sintering temperature increase. But when the temperature is higher than 1500 °C the Si2ON2 grains will decompose into Si3N4, and Si2ON2 will vanish at 1550 °C

Preparation and Investigation on Properties of the MgTiO3-CaTiO3 Microwave Ceramic Materials

2014 ◽  
Vol 997 ◽  
pp. 419-423 ◽  
Author(s):  
Li Dong ◽  
Gui Xia Dong ◽  
Yuan Yuan Li ◽  
Xi Zhang
Keyword(s):  
Dielectric Constant ◽  
Sintering Temperature ◽  
Ceramic Materials ◽  
Volume Density ◽  
Second Phase ◽  
Pressureless Sintering ◽  
Solid Reaction ◽  
Reaction Method ◽  
Microwave Ceramic ◽  
Sintering Method

The MgTiO3 and CaTiO3 powders were synthesized by solid reaction method, and MgTiO3-CaTiO3 ceramic was prepared using pressureless sintering method. The experiment prepared MgTiO3-CaTiO3 ceramics with high compactness and stable permittivity by the way of changing the mole ratio of MgTiO3 and CaTiO3 to investigate the effect of CaTiO3 on the performances of MgTiO3-CaTiO3 ceramics. The results show that Mg2TiO4 formed as second phase during sintering. Volume density and dielectric constant of MgTiO3-CaTiO3 ceramics with 10%mol CaTiO3 reach maximum of 3.612g/cm3 and 17.8, respectively, under 1460°C sintering temperature. And for the MgTiO3-CaTiO3 ceramics with 5%mol CaTiO3 the maximum values which are 3.5g/cm3 and 16.6, respectively, appear under 1510°C sintering temperature.

Preparation and Properties of Ti, Eu Co-Doped Y2O2S:0.06Ti,0.08Eu Phosphor with Red Long Afterglow

2007 ◽  
Vol 336-338 ◽  
pp. 600-603
Author(s):  
Qui Ping Huang ◽  
Zhang Lian Hong ◽  
Peng Yue Zhang ◽  
Xian Ping Fan
Keyword(s):  
Sintering Temperature ◽  
Energy Transfer Process ◽  
Great Influence ◽  
Luminescence Spectra ◽  
Yellow Emission ◽  
Long Afterglow ◽  
To Come ◽  
Sintering Method ◽  
Yellow Emission Band ◽  
Co Doped

Ti,Eu co-doped Y2O2S:0.06Ti,0.08Eu phosphor with red long afterglow emission from Eu ions was synthesized via traditional sintering method. Results showed that sintering temperature has great influence on the crystal structure, luminescence and afterglow property of the phosphors. The best luminescence and afterglow properties were obtained for the phosphors sintered at 1200°C for 2.5h. Furthermore, only emissions originated from charge transition of Eu3+ was found in the luminescence spectra whereas the afterglow spectra were composed of two sets of emissions: a broad yellow emission band around 565nm and a group of narrow peaks in the wavelength range above 530 nm. The origin of afterglow spectra was discussed: the former is likely related to emission from Ti related traps and the latter is supposed to come from the Eu3+ through an energy transfer process from Ti emission to Eu3+.

scholarly journals Crystallization Kinetics and Consolidation of Al82La10Fe4Ni4 Glassy Alloy Powder by Spark Plasma Sintering

Metals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 812
Author(s):  
Nguyen Viet ◽  
Nguyen Oanh ◽  
Ji-Soon Kim ◽  
Alberto Jorge
Keyword(s):  
Nucleation Rate ◽  
Glassy Alloy ◽  
Intermetallic Phase ◽  
Three Dimensional ◽  
Sample Surface ◽  
Sintered Sample ◽  
Amorphous Structure ◽  
Mechanically Alloyed ◽  
Plasma Sintering ◽  
Spark Plasma

The mechanically alloyed Al82La10Ni4Fe4 glassy powder displays a two-step devitrification characterized by the precipitation of fcc-Al together with small amounts of the intermetallic Al11La3 phase in the first crystallization. The interface-controlled growth mechanism governed the first crystallization event. Calculations of the activation energy, using the methods of Kissinger, Ozawa, and Augis-Bennett gave values of 432.33, 443.2, and 437.76 kJ/mol, respectively. The calculated Avrami exponent (n) for the first crystallization peak was about 1.41, suggesting an almost zero nucleation rate. On the other hand, the value of n for the second peak related to the residual amorphous phase completely transformed into the intermetallic phase Al11La3 was about 3.61, characterizing diffusion controlled three-dimensional crystal growth with an increasing nucleation rate. Samples sintered at 573 K kept an amorphous structure and exhibited a high compressive strength of 650 MPa with a maximum elongation of 2.34% without any plastic deformation. The failure morphology of the sintered sample surface presented a transparticle fracture mechanism, indicating the efficiency of the sintering processing.

scholarly journals Effect of Sintering Temperature on Property of Low-Density Ceramic Proppant Adding Coal Gangue

2019 ◽  
Vol 26 (1) ◽  
pp. 94-98
Author(s):  
Jianying HAO ◽  
Huilan HAO ◽  
Yunfeng GAO ◽  
Xianjun LI ◽  
Mei QIN ◽  
...  
Keyword(s):  
Solid Waste ◽  
Bulk Density ◽  
Apparent Density ◽  
Sintering Temperature ◽  
Coal Gangue ◽  
Low Density ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sintering Method ◽  
Waste Coal

Calcined flint clay (45.6 wt.% Al2O3) and solid waste coal gangue were used to prepare low-density ceramic proppant by solid state sintering method. The density and breakage ratio of the ceramic proppant were systematically investigated as a function of sintering temperature. The morphology and phase composition of the ceramic proppant were examined by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results show that the ceramic proppant is composed of rod-like mullite and granular cristobalite. Bulk density and apparent density of the proppant first rise and then slightly decrease with increasing the sintering temperature, while breakage ratios under 35 MPa and 52 MPa pressure gradually decrease and then increase. As the sintering temperature increases up to 1400 °C, the ceramic proppant shows denser microstructure. The proppant sintered at 1400 °C have the best performance with 1.27 g/cm3 of bulk density, 2.79 g/cm3 of apparent density, 3.27 % of breakage ratio under 35 MPa closed pressure and 8.36 % of breakage ratio under 52 MPa closed pressure, which conform to the requirement of low-density ceramic proppant. The addition of solid waste can greatly reduce the preparation cost of the ceramic proppant.

Sign in / Sign up

Export Citation Format

Share Document