Kinetic Study of Degradation of Basic Turquise Blue X-GB and Basic Blue X-GRRL using Advanced Oxidation Process

2020 ◽  
Vol 234 (11-12) ◽  
pp. 1803-1817 ◽  
Author(s):  
Naeem-Ul-Haq Khan ◽  
Haq Nawaz Bhatti ◽  
Munawar Iqbal ◽  
Arif Nazir ◽  
Hiratul Ain
Keyword(s):  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Uv Light ◽  
Correlation Coefficients ◽  
Advanced Oxidation ◽  
Optimum Conditions ◽  
Oxidation Treatment ◽  
First Order ◽  
Fenton Oxidation Process ◽  
Maximum Decolorization

AbstractThis study focuses on application of advanced oxidation (Photo-Fenton) processes to decolorize Basic Turquise Blue (BTB) X-GB 250% and Basic Blue (BB) X-GRRL 250% dyes. The percent decolorization was studied in terms of effect of variation in intensity of UV light at optimum conditions of all the parameters (pH = 3.0, H2O2 = 4.8 mM, FeSO4 = 1.6 mM, temperature = 50 °C, time = 80 min for BTB X-GB, and pH = 5.0, H2O2 = 5.6 mM, FeSO4 = 2.0 mM, temperature = 40 °C, time = 60 min for BB X-GRRL). Maximum decolorization was obtained at maximum intensity (15660 counts/min) of UV light as 96.17% for BTB X-GB and 88.48% for BB X-GRRL. First order, 2nd order and BMG kinetic models were used to analyze the data obtained for intensity of UV light. BMG model gives us the higher values of correlation coefficients for all data of both the dyes. The results have shown that Photo-Fenton oxidation process is the beneficial and effective for oxidation treatment of waste water effluents containing dyes as main pollutants.

UV Based Advanced Oxidation Process for Degradation of Ciprofloxacin: Reaction Kinetics, Effects of Interfering Substances and Degradation Product Identification

2021 ◽  
Author(s):  
Bijoli Mondal ◽  
Shib Sankar Basak ◽  
Arnab Das ◽  
Sananda Sarkar ◽  
Asok Adak
Keyword(s):  
Organic Compounds ◽  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Uv Light ◽  
Degradation Products ◽  
Irradiation Time ◽  
Advanced Oxidation ◽  
Quantum Yields ◽  
Photon Flux ◽  
First Order

Abstract In the photochemical UV-H2O2 advanced oxidation process, H2O2 absorbs UV light and is decomposed to form hydroxyl radicals (OH·), which are highly excited and reactive for electron-rich organic compounds and hence can degrade organic compounds. In the present work, the UV-H2O2 process was investigated to degrade ciprofloxacin (CIP), one of India's widely used antibiotics, from aqueous solutions using a batch type UV reactor having photon flux = 1.9 (± 0.1) ×10-4 Einstein L-1 min-1. The effects of UV irradiation time on CIP degradation were investigated for both UV and UV-H2O2 processes. It was found that about 75% degradation of CIP was achieved within 60 s with initial CIP concentration and peroxide concentration of 10 mg L-1 and 1 mol H2O2/ mol CIP, respectively, at pH of 7(±0.1) and fluence dose of 113 mJ cm-2. The experimental data were analyzed by the first-order kinetics model to find out the time- and fluence-based degradation rate constants. Under optimized experimental conditions (initial CIP concentration, pH and H2O2 dose of 10 mg L-1, 7(±0.1) and 1.0 mol H2O2 / mol CIP, respectively), the fluence-based pseudo-first-order rate constant for the UV and UV-H2O2 processes were determined to be 1.28(±0.0) ×10-4 and 1.20(±0.04) ×10-2 cm2 mJ-1 respectively. The quantum yields at various pH under direct UV were calculated. The impacts of different process parameters such as H2O2 concentration, solution pH, initial CIP concentration, and wastewater matrix on CIP degradation were also investigated in detail. CIP degradation was favorable in acidic conditions. Six degradation products of CIP were identified. Results clearly showed the potentiality of the UV-H2O2 process for the degradation of antibiotics in wastewater.

Decolorization of Basic Turquise Blue X-GB and Basic Blue X-GRRL by the Fenton’s Process and its Kinetics

2019 ◽  
Vol 233 (3) ◽  
pp. 361-373 ◽  
Author(s):  
Naeem-Ul-Haq Khan ◽  
Haq Nawaz Bhatti ◽  
Munawar Iqbal ◽  
Arif Nazir
Keyword(s):  
Waste Water ◽  
Water Pollution ◽  
Oxidation Process ◽  
Human Life ◽  
Correlation Coefficients ◽  
Fenton Process ◽  
Optimum Conditions ◽  
Oxidation Treatment ◽  
Textile Industries ◽  
Life On Earth

Abstract Textile industries use dyes to color their products and release waste water containing dyes, causing water pollution which is a serious problem for survival of human life on earth. The decolorization of basic turquise blue X-GB (BTB X-GB) 250% and basic blue X-GRRL (BB X GRRL) 250% dyes was examined by advanced (Fenton process) oxidation process. The effects of different parameters (initial dye concentration, pH, concentrations of hydrogen peroxide (H2O2) and reaction time) have been examined and optimum conditions were determined. It has been noted that percentage decolorization of both dyes (50 mg/L) increases with increase in concentration of H2O2. At optimum conditions (pH=3.0, H2O2=4.8 mM, temperature=50°C, time=80 min of BTB X-GB, and pH=5.0, H2O2=5.6 mM, temperature=40°C, time=60 min of BB X-GRRL) the decolorization obtained by Fenton process was 85.83% of BTB X-GB and 74.98% for BB X-GRRL. 1st order, 2nd order and BMG kinetic models were used to analyze the data. BMG model gives us the higher values of correlation coefficients for all data. Results showed that Fe2+/H2O2 are most effective for oxidation treatment of waste water effluents containing dyes as main pollutants.

scholarly journals Advanced Oxidation of Segregated Streams for Effective Color Removal from Denim Processing Effluents

2021 ◽  
Vol 12 (1) ◽  
pp. 391-404
Keyword(s):  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Advanced Oxidation ◽  
Fenton Oxidation ◽  
Color Removal ◽  
Color Treatment ◽  
Footprint Analysis ◽  
Optimum Reaction ◽  
Composite Mixture ◽  
Fenton Oxidation Process

The study introduced footprint analysis as a new methodology and focused on differentiating wastewater streams with the highest color content and optimizing the advanced oxidation process for the segregated streams for effective color removal from denim processing. Experiments were implemented to four segregated streams rather than the entire plant effluent. A flow proportional composite mixture of segregated streams was used for color removal experiments using the advanced oxidation process with ozone and hydrogen peroxide and Fenton oxidation as other alternatives. The latter yielded the best results achieving total removal of color below visual detection limit after an optimum reaction time of 10 minutes. The Fenton oxidation process was also applied to a representative sample from the plant effluent after the physical-chemical treatment sequence, where color absorbance levels were lowered at all wavelengths below 1.0 m-1. The merit of the new footprint approach was confirmed by the results, which provided a conclusive indication that color treatment at source, implemented on selected segregated wastewater streams, presented concrete advantages over the end of pipe treatment of the overall effluent.

ZnO/UV/H2O2 Based Advanced Oxidation of Disperse Red Dye

2020 ◽  
Vol 234 (1) ◽  
pp. 129-143 ◽  
Author(s):  
Aneela Jamil ◽  
Tanveer Hussain Bokhari ◽  
Munawar Iqbal ◽  
Muhammad Zuber ◽  
Iftikhar Hussain Bukhari
Keyword(s):  
Water Quality ◽  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Irradiation Time ◽  
Advanced Oxidation ◽  
Quality Parameters ◽  
Process Variables ◽  
Optimum Conditions ◽  
Initial Concentration ◽  
Red Dye

AbstractIn view of promising efficiency of advanced oxidation process, ZnO/UV/H2O2 based advanced oxidation process (AOP) was employed for the degradation of Disperse Red-60 (DR-60) in aqueous medium. The process variables such as concentration of catalysts, reaction time, pH, dye initial concentration and H2O2 dose were evaluated for maximum degradation of dye. The maximum degradation of 97% was achieved at optimum conditions of H2O2 (0.9 mL/L), ZnO (0.6 g/L) at pH 9.0 in 60 min irradiation time. The analysis of treated dye solution revealed the complete degradation under the effect of ZnO/UV/H2O2 treatment. The water quality parameters were also studied of treated and un-treated dye solution and up to 79% COD and 60% BOD reductions were achieved when dye was treated with at optimum conditions. The dissolved oxygen increased up to 85.6% after UV/H2O2/ZnO treatment. The toxicity was also monitored using hemolytic and Ames tests and results revealed that toxicity (cytotoxicity and mutagenicity) was also reduced significantly. In view of promising efficiency of UV/H2O2/ZnO system, it could possibly be used for the treatment of wastewater containing toxic dyes.

scholarly journals Degradation of Paracetamol by an UV/Chlorine Advanced Oxidation Process: Influencing Factors, Factorial Design, and Intermediates Identification

2018 ◽  
Vol 15 (12) ◽  
pp. 2637 ◽  
Author(s):  
Yen Dao ◽  
Hai Tran ◽  
Thien Tran-Lam ◽  
Trung Pham ◽  
Giang Le
Keyword(s):  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
High Resolution Mass Spectrometry ◽  
Advanced Oxidation ◽  
Transformation Products ◽  
Solution Ph ◽  
Operational Conditions ◽  
First Order ◽  
First Order Kinetics ◽  
Degradation Rate Constant

The combination of a low-pressure mercury lamp and chlorine (UV/chlorine) was applied as an emerging advanced oxidation process (AOP), to examine paracetamol (PRC) degradation under different operational conditions. The results indicated that the UV/chlorine process exhibited a much faster PRC removal than the UV/H2O2 process or chlorination alone because of the great contribution of highly reactive species (•OH, •Cl, and ClO•). The PRC degradation rate constant (kobs) was accurately determined by pseudo-first-order kinetics. The kobs values were strongly affected by the operational conditions, such as chlorine dosage, solution pH, UV intensity, and coexisting natural organic matter. Response surface methodology was used for the optimization of four independent variables (NaOCl, UV, pH, and DOM). A mathematical model was established to predict and optimize the operational conditions for PRC removal in the UV/chlorine process. The main transformation products (twenty compound structures) were detected by liquid chromatography coupled to high-resolution mass spectrometry (LC-HRMS).

Influence of mineral water constituents, organic matter and water matrices on the performance of the H2O2/IO4−-advanced oxidation process

2019 ◽  
Vol 5 (11) ◽  
pp. 1985-1992 ◽  
Author(s):  
Nor Elhouda Chadi ◽  
Slimane Merouani ◽  
Oualid Hamdaoui ◽  
Mohammed Bouhelassa ◽  
Muthupandian Ashokkumar
Keyword(s):  
Organic Matter ◽  
Water Treatment ◽  
Mineral Water ◽  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Advanced Oxidation ◽  
Water Constituents

We have recently reported that the reaction of H2O2/IO4− could be a new advanced oxidation process for water treatment [N. E. Chadi, S. Merouani, O. Hamdaoui, M. Bouhelassa and M. Ashokkumar, Environ. Sci.: Water Res. Technol., 2019, 5, 1113–1123].

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