Pengembangan Novel Grafik Elektronik pada Materi Reaksi Radikal Bebas sebagai Media Suplemen Pembelajaran

2022 ◽  
Vol 16 (1) ◽  
pp. 8-15
Author(s):  
Fransiskus Sabianto ◽  
Husna Amalya Melati ◽  
Rini Muharini
Keyword(s):  
Organic Chemistry ◽  
Free Radical ◽  
Chemistry Education ◽  
Daily Life ◽  
Radical Reaction ◽  
Graphic Novel ◽  
Free Radical Reaction ◽  
High Category ◽  
Good Potential ◽  
Very High

This research was aimed to produce a valid electronic graphic novel on free radical reaction subject and to find out the student’s response to the developed product. This research employed Research & Development (R&D) method by using Thiagarajan’s 4D model with modification, in which applied only three of four steps in 4D model.  The developed product was validated by experts. The responses toward developed product were collected from the students of Chemistry Education FKIP Untan who have taken organic chemistry course.  Data collection tools used were validation sheets and student’s response questionnaires on the developed product.  The validation’s result from the experts showed that the developed product was very proper in terms of content, presentation, linguistic, and graphic aspects with consecutive total scores of 94.0%, 95.0%, 89.0%, and 100,00% respectively. The results of the student’s responses in small group trials and in large group trials were of 82.5% with high category and of 83.2% with very high category, respectively.  Thus, this electronic graphic novel on radical reaction has very good potential as a learning media to attract students to learn free radical reaction and its application in daily life.

scholarly journals Development of Constructivism-Based Student Worksheets on Free Radical Reaction Material

2019 ◽  
Vol 3 (2) ◽  
pp. 162
Author(s):  
Okma Rahmatya ◽  
Susilawati Susilawati ◽  
Maria Erna
Keyword(s):  
Organic Chemistry ◽  
Free Radical ◽  
Radical Reaction ◽  
Free Radical Reaction ◽  
Design Development ◽  
Teaching Materials ◽  
Chemistry Teaching ◽  
Study Program ◽  
Validity Criteria ◽  
Limited Testing

Organic Chemistry is one of the difficult subjects, especially in reaction and strechochemical mechanisms. One effort to reduce it is to utilize teaching materials. This study aims to develop organic chemistry teaching materials on free radical reaction material in the form of constructivism-based student worksheets (LKM). The research method used research and development research design with a 4D development model which consists of the stages of define, design, development, and disseminate. Development of LKM was assessed based on validity criteria and limited trials. The validity of LKM was achieved and assessed by three validators. Limited trials were conducted for the 6th semester students of the chemical education study program totaling 15 people and also three organic chemistry lecturers to see the appropriateness of developed LKM from the lecturers' perspective. The overall LKM results of its validity showed that the LKM has 95.05% valid. The results of limited trials based on the responses of students and lecturers each obtained a percentage of 84.02% and 87.22%, respectively. Based on the results of validation and limited testing of constructivism-based LKM on the material of free radical reaction developed it is included in the category of valid and can be used in the learning process.

Kinetics of the Production of Castor Oil Maleate through the Autocatalyzed Thermal Reaction and the Free Radical Reaction

2017 ◽  
Vol 50 (2) ◽  
pp. 112-121 ◽  
Author(s):  
Dayanne L. H. Maia ◽  
Elenilson G. Alves Filho ◽  
Antonino F. Barros Junior ◽  
Fabiano A. N. Fernandes
Keyword(s):  
Free Radical ◽  
Castor Oil ◽  
Radical Reaction ◽  
Thermal Reaction ◽  
Free Radical Reaction ◽  
Kinetics Of

Manganese(III)-based oxidative free-radical reaction of α-allyl-β-keto ester with molecular oxygen

1993 ◽  
Vol 34 (52) ◽  
pp. 8509-8512 ◽  
Author(s):  
Takashi Ohshima ◽  
Mikiko Sodeoka ◽  
Masakatsu Shibasaki
Keyword(s):  
Free Radical ◽  
Molecular Oxygen ◽  
Radical Reaction ◽  
Free Radical Reaction ◽  
Keto Ester

scholarly journals Gasification Pathways and Reaction Mechanisms of Primary Alcohols in Supercritical Water

2019 ◽  
Author(s):  
Brian Pinkard ◽  
John Kramlich ◽  
Igor V. Novosselov
Keyword(s):  
Free Radical ◽  
Supercritical Water ◽  
Reaction Mechanisms ◽  
Radical Reaction ◽  
Water Environment ◽  
Waste To Energy ◽  
Reaction Pathways ◽  
Free Radical Reaction ◽  
Reaction Products ◽  
Primary Alcohols

<div> <p></p><p>Supercritical water gasification is a promising waste-to-energy technology with the ability to convert aqueous and/or heterogeneous organic feedstocks to high-value gaseous products. Reaction behavior of complex molecules in supercritical water can be inferred through knowledge of the reaction pathways of model compounds in supercritical water. In this study methanol, ethanol, and isopropyl alcohol are gasified in a continuous supercritical water reactor at temperatures between 500 and 560 °C, and for residence times between 3 and 8 s. <i>In situ</i> Raman spectroscopy is used to rapidly identify and quantify reaction products. The results suggest the dominance of chain-branching, free radical reaction mechanisms that are responsible for decomposing primary alcohols in the supercritical water environment. The presence of a catalytic surface is proposed to be highly significant for initiating radical reactions. Global reaction pathways are proposed, and mechanisms for free radical reaction initiation, propagation, and termination are discussed in light of these and previously published experimental results.</p><br><p></p></div>

scholarly journals Gasification Pathways and Reaction Mechanisms of Primary Alcohols in Supercritical Water

2019 ◽  
Author(s):  
Brian Pinkard ◽  
John Kramlich ◽  
Igor V. Novosselov
Keyword(s):  
Free Radical ◽  
Supercritical Water ◽  
Reaction Mechanisms ◽  
Radical Reaction ◽  
Water Environment ◽  
Waste To Energy ◽  
Reaction Pathways ◽  
Free Radical Reaction ◽  
Reaction Products ◽  
Primary Alcohols

<div> <p></p><p>Supercritical water gasification is a promising waste-to-energy technology with the ability to convert aqueous and/or heterogeneous organic feedstocks to high-value gaseous products. Reaction behavior of complex molecules in supercritical water can be inferred through knowledge of the reaction pathways of model compounds in supercritical water. In this study methanol, ethanol, and isopropyl alcohol are gasified in a continuous supercritical water reactor at temperatures between 500 and 560 °C, and for residence times between 3 and 8 s. <i>In situ</i> Raman spectroscopy is used to rapidly identify and quantify reaction products. The results suggest the dominance of chain-branching, free radical reaction mechanisms that are responsible for decomposing primary alcohols in the supercritical water environment. The presence of a catalytic surface is proposed to be highly significant for initiating radical reactions. Global reaction pathways are proposed, and mechanisms for free radical reaction initiation, propagation, and termination are discussed in light of these and previously published experimental results.</p><br><p></p></div>

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