Siliconic and Acrylic Resins Dispersed in Water as Protectives for Stone Surface

1992 ◽  
Vol 267 ◽  
Author(s):  
Guido Biscontin ◽  
P. Maravelaki ◽  
E. Zendri ◽  
A. Glisenti
Keyword(s):  
Contact Angle ◽  
Protective Effect ◽  
Water Absorption ◽  
Water Repellency ◽  
Point Of View ◽  
General Effect ◽  
Pore Filling ◽  
Complete Wetting ◽  
Vapour Permeability ◽  
Acrylic Resins

The aim of the present work is to compare the protective effect of solvent and water dispersed products on marble, Lecce and Istria stones. This choice is justified by the need of products effective also from the ecological and toxicological point of view. To obtain these informations two tests have been chosen: contact angle and water absorption. The contact angle may, in theory, be considered a measure of the water repellency, since complete wetting implies a contact angle of 0° and absolutely no wetting an angle of 180°. This does not apply to the water absorption by capillarity test because the absorption variation may be caused by either the water repellency action of the treatments or by the pore filling. However this test may give practical information about the general effect of the treatments. Moreover, the effect of treatments on permeability was investigated by vapour permeability test. Protective effect was studied after application of the products and at various stages of artificial weathering.

Effect of temperature on composite films made with activated carbon, graphite, or graphene oxide (GO) in a gelatin matrix

BioResources ◽  
2020 ◽  
Vol 16 (1) ◽  
pp. 77-95
Author(s):  
Siqiao Yang ◽  
Haichao Li
Keyword(s):  
Contact Angle ◽  
Activated Carbon ◽  
Water Absorption ◽  
Composite Films ◽  
Effect Of Temperature ◽  
Gelatin Matrix ◽  
Vapour Permeability ◽  
Blending Method ◽  
The Matrix ◽  
Different Temperatures

Activated carbon, graphite, and GO/gelatin composite films were prepared by the blending method. The properties of composites were characterized by tensile strength (TS), elongation at break (EB), water vapour permeability (WVP), water-absorption ability, contact angle, scanning electron microscopy (SEM), and moisture at different temperatures. The properties of GO/gelatin composite films were better when each of three kinds of carbon materials were used as reinforcement phases and added into the matrix gelatin. The results showed that EB and TS of GO/gelatin composite films were both excellent. The moisture of GO/gelatin composite films was greater than the others. SEM micrographs showed that GO had better compatibility and dispersibility with gelatin than activated carbon and graphite. The water absorption of GO/gelatin composite films were low, at 15 °C and 25 °C, and the WVP was low at 35 °C. The WVP of GO/gelatin composite films was lower than the others at different temperatures. The contact angle of GO/gelatin composite films was larger than the others.

scholarly journals Ultrahydrophobic Textiles Using Nanoparticles: Lotus Approach

2008 ◽  
Vol 3 (4) ◽  
pp. 155892500800300 ◽  
Author(s):  
Karthik Ramaratnam ◽  
Swaminatha K. Iyer ◽  
Mark K. Kinnan ◽  
George Chumanov ◽  
Phillip J. Brown ◽  
...  
Keyword(s):  
Contact Angle ◽  
Water Contact Angle ◽  
Contact Angle Hysteresis ◽  
Water Repellency ◽  
Textile Material ◽  
Water Repellent ◽  
Complete Wetting ◽  
Water Contact ◽  
Lotus Effect ◽  
Textile Materials

It is well established that the water wettability of materials is governed by both the chemical composition and the geometrical microstructure of the surface.1 Traditional textile wet processing treatments do indeed rely fundamentally upon complete wetting out of a textile structure to achieve satisfactory performance.2 However, the complexities introduced through the heterogeneous nature of the fiber surfaces, the nature of the fiber composition and the actual construction of the textile material create difficulties in attempting to predict the exact wettability of a particular textile material. For many applications the ability of a finished fabric to exhibit water repellency (in other words low wettability) is essential2 and potential applications of highly water repellent textile materials include rainwear, upholstery, protective clothing, sportswear, and automobile interior fabrics. Recent research indicates that such applications may benefit from a new generation of water repellent materials that make use of the “lotus effect” to provide ultrahydrophobic textile materials.3,4 Ultrahydrophobic surfaces are typically termed as the surfaces that show a water contact angle greater than 150°C with very low contact angle hysteresis.4 In the case of textile materials, the level of hydrophobicity is often determined by measuring the static water contact angle only, since it is difficult to measure the contact angle hysteresis on a textile fabric because of the high levels of roughness inherent in textile structures.

Application Studies on Silane Hydrophobic Agents for Concrete Protection

2014 ◽  
Vol 1053 ◽  
pp. 297-302
Author(s):  
Ning Cai ◽  
Yao Xia Li ◽  
Da Xiang Cui
Keyword(s):  
Contact Angle ◽  
Protective Effect ◽  
Water Absorption ◽  
Hydrophobic Property ◽  
Water Contact ◽  
Static Water Contact Angle ◽  
Static Water ◽  
Hydrophobic Agent ◽  
Depth Water ◽  
Better Than

In this paper, the function of silane hydrophobic agents to protect concretes under different varieties and different concentrations were studied. Penetration depth, water absorption ratio and contact angle were measured and compared, the influences of silane hydrophobic agents on the concretes protection under different condition were investigated. Results showed that silane hydrophobic agents exhibit better properties on concretes protection. 24h water absorption ratios of all silane hydrophobic agents surpassed the trade standard JC/T 902-2002 Silicone hydrophobic agent for construction surfaces, and all of the samples showed excellent static water contact angle and hydrophobic property. The protective effect of silane hydrophobic agent B is better than silane hydrophobic agent A.

scholarly journals Research and Prediction of Wettability of Irregular Square Column Structure on Polymethyl Methacrylate (PMMA) Surface Prepared by Femtosecond Laser

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 529
Author(s):  
Bangfu Wang ◽  
Juan Song
Keyword(s):  
Contact Angle ◽  
Femtosecond Laser ◽  
Prediction Model ◽  
Polymethyl Methacrylate ◽  
Groove Width ◽  
Complete Wetting ◽  
Column Structure ◽  
Pmma Surface ◽  
Incomplete Wetting ◽  
Wetting Model

Based on the contact angle prediction model of a traditional square column structure, the prediction models for wettability of a parallelogram square column structure (PSCS) on polymethyl methacrylate (PMMA) surface prepared by femtosecond laser were established. An experiment was conducted to analyze the rationality of the established complete wetting model and incomplete wetting model. It was found that the incomplete wetting prediction model of the square column structure was more in line with the actual situation. For PSCS, the length of both the long and short sides of the boss and the width of the groove exerted an impact on the contact angle prediction results. Under the condition that the length of the long and short sides of the boss remained unchanged and the groove width increased, the contact angle increased under complete wetting and incomplete wetting. In contrast, under the condition that the long side length of the boss and the groove width remained unchanged and the short side length of the boss increased, the contact angle increased under complete wetting but decreased under incomplete wetting. The maximum contact angle reached 135.65°, indicating that PSCS on PMMA surface enhanced the surface hydrophobicity of the material.

scholarly journals Water uptake of various electrospun nonwovens

2020 ◽  
Vol 6 (3) ◽  
pp. 155-158
Author(s):  
Katharina Wulf ◽  
Volkmar Senz ◽  
Thomas Eickner ◽  
Sabine Illner
Keyword(s):  
Contact Angle ◽  
Surface Modification ◽  
Water Absorption ◽  
Water Uptake ◽  
Biomedical Applications ◽  
High Surface ◽  
Volume Ratio ◽  
Polymer Composition ◽  
Water Wetting ◽  
Morphology Changes

AbstractIn recent years, nanofiber based materials have emerged as especially interesting for several biomedical applications, regarding their high surface to volume ratio. Due to the superficial nano- and microstructuring and the different wettability compared to nonstructured surfaces, the water absorption is an important parameter with respect to the degradation stability, thermomechanic properties and drug release properties, depending on the type of polymer [1]. In this investigation, the water absorption of different non- and plasma modified biostable nanofiber nonwovens based on polyurethane, polyester and polyamide were analysed and compared. Also, the water absorption by specified water wetting, the contact angle and morphology changes were examined. The results show that the water uptake is highly dependent on the surface modification and the polymer composition itself and can therefore be partially changed.

scholarly journals Ecofriendly Preparation and Characterization of a Cassava Starch/Polybutylene Adipate Terephthalate Film

Processes ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 329
Author(s):  
Tan Yi ◽  
Minghui Qi ◽  
Qi Mo ◽  
Lijie Huang ◽  
Hanyu Zhao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Contact Angle ◽  
Water Vapor ◽  
Composite Film ◽  
Water Absorption ◽  
Composite Films ◽  
Thermoplastic Starch ◽  
Light Transmittance ◽  
Infrared Spectrometry ◽  
Nano Zno

Composite films of polybutylene adipate terephthalate (PBAT) were prepared by adding thermoplastic starch (TPS) (TPS/PBAT) and nano-zinc oxide (nano-ZnO) (TPS/PBAT/nano-ZnO). The changes of surface morphology, thermal properties, crystal types and functional groups of starch during plasticization were analyzed by scanning electron microscopy, synchronous thermal analysis, X-ray diffraction, infrared spectrometry, mechanical property tests, and contact Angle and transmittance tests. The relationship between the addition of TPS and the tensile strength, transmittance, contact angle, water absorption, and water vapor barrier of the composite film, and the influence of nano-ZnO on the mechanical properties and contact angle of the 10% TPS/PBAT composite film. Experimental results show that, after plasticizing, the crystalline form of starch changed from A-type to V-type, the functional group changed and the lipophilicity increased; the increase of TPS content, the light transmittance and mechanical properties of the composite membrane decreased, while the water vapor transmittance and water absorption increased. The mechanical properties of the composite can be significantly improved by adding nano-ZnO at a lower concentration (optimum content is 1 wt%).

New sustainable mortars for stone restoration in the context of climate change

2021 ◽  
Author(s):  
Jose Diaz-Basteris
Keyword(s):  
Physical Properties ◽  
Moisture Absorption ◽  
Raw Materials ◽  
Point Of View ◽  
Salt Crystallization ◽  
Glass Waste ◽  
Vapour Permeability ◽  
James Bond ◽  
S Waves ◽  
Environmental Agents

<p>Restoration mortars are a designated group of products made to repair damaged masonry. They must be compatible with the former support of stones and bricks, and protect original materials from environmental agents; aesthetical and historic aspects must not be neglected. </p><p>To improve the ecological footprint of the restoration mortars while keeping their efficiency, we have tested several combinations of lime with aggregates and additives. Recycled and natural materials were used as additives such as pinecone resin, semi-milled cones of pine, milled glass waste, brick production residue.</p><p>For research purposes different physical properties have been measured in prepared mortars: porosity, density, capillarity absorption, moisture absorption, water vapour permeability. We have also tested the mechanical properties and the P and S waves velocities (from which dynamic Young's modulus and Poisson’s ratio were inferred). The durability of mortars has been estimated by salt crystallization and frost/thaw cycles.</p><p>The life cycle analysis (LCA) of such mortars allows us to understand the carbon footprint of each manufacturing process. Considering this we selected the raw materials, from an environmental and commercial point of view, to produce mortars fulfilling sustainability requirements. As a result, the developed mortars are compatible with aged stones, minimize environmental impact, and use minimum natural resources.</p><p> Twenty mortar formulations with three different types of limes (NHL5, NHL3.5, CL90) and two different aggregates (siliceous and calcareous) have been studied using the LCA. Currently, five new formulations are being selected to be tested on Euville limestone. Adhesive strength (James Bond test), and physical properties will be measured on these mortars. </p>

scholarly journals USE OF SLUDGE FROM SANITARY SEWAGE TREATMENT PLANTS (S.T.P) AND THEIR USE AS RAW MATERIAL IN THE MANUFACTURE OF BRICKS

2019 ◽  
Vol 16 (33) ◽  
pp. 823-840
Author(s):  
M. K. TARABAI ◽  
S. G. de AZEVEDO
Keyword(s):  
Compressive Strength ◽  
Water Absorption ◽  
Sewage Treatment ◽  
Point Of View ◽  
Test Method ◽  
Raw Material ◽  
Environmental Preservation ◽  
Ceramic Block ◽  
Environmental Requirements ◽  
The One

This paper discusses a possible solution regarding the final disposal of sludge from Sanitary Sewage Treatment Stations (ET), aiming at environmental preservation. The solid waste generated after the wastewater treatment processes is highly contaminating and detrimental to the area in which it is deposited. Given this, the use of sludge with the application of reuse techniques becomes pertinent, both from the economic point of view and from the ecological point of view. By replacing the use of aggregates from mineral deposits, the main clay raw material in the manufacture of ceramic products (Vieira, 2000), by the treated sludge of WWTP we will save on the sources of granular materials. Aiming its reintegration to the production cycle through the introduction of sludge as raw material incorporated in the ceramic mass in the manufacture of hollow bricks, the viability of use was verified through performance analysis, compared to the control brick made of pottery, without the addition of sludge. Specimens were prepared with three types of samples: 90% clay and 10% sludge; 80% clay and 20% sludge; 70% clay and 30% sludge. Mass loss, water absorption index and compressive strength tests were performed. As for the tests, the specimens with 10% and 20% of sludge were the ones that had better adaptation to the technical requirements, but because it is a larger volume of the residue for the application of reuse techniques, the brick with 20% sludge dosage. is the most suitable. NBR7.171, November 1992: Ceramic Block for masonry; Specification NBR 6.461, June 1983: Masonry Ceramic Block - Compressive Strength Check: Test Method; NBR 8.947, November 1992: Ceramic Tile- Determination of Mass and Water Absorption: Test Method. As for the tests, the specimen with 20% of sludge was the one that had the best adaptation to technical and environmental requirements. The present article approaches a possible solution regarding the destination of the sludge coming from Sanitary Sewage Treatment Stations, aiming at environmental preservation. Aiming at its reintegration into the productive cycle through applications of reuse techniques, the sludge became raw material when the ceramic mass was incorporated into the brick fabrication. Three types of samples were elaborated: 90% of clay and 10% of mud; 80% clay and 20% sludge; 70% clay and 30% sludge. As for the tests, the test specimen with 20% of sludge was the one that had more adequacy to the technical and environmental requirements.

scholarly journals A Novel Method for nZEB Internal Coverings Design Based on Neural Networks

Coatings ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 288 ◽  
Author(s):  
José A. Orosa ◽  
Diego Vergara ◽  
Ángel M. Costa ◽  
Rebeca Bouzón
Keyword(s):  
Building Materials ◽  
International Energy Agency ◽  
Construction Materials ◽  
Real Data ◽  
Point Of View ◽  
Building Construction ◽  
Sampled Data ◽  
Energy Agency ◽  
Vapour Permeability ◽  
Weather Changes

Research from the International Energy Agency about indoor ambiences and nearly zero energy buildings (nZEB) in the past has been centred on different aspects such as the prediction of indoor conditions as a function of the weather using laboratory material properties for simulations and real sampled data for validation. Thus, it is possible to use real data for defining behavioural groups of indoor ambiences as a function of real vapour permeability of internal coverings. However, this method is not suitable for modelling it and predicting its behaviour under weather changes, which is of interest to improve the method of selection and use of building construction materials. In this research, artificial intelligence procedures were employed as the first model of permeable coverings material behaviour to provide a newer understanding of building materials and applications for the generation of new control procedures between the mechanical and electronic point of view of building construction materials.

Strophiolar Water Conduction in Seeds of the Trifolieae Induced by Action on the Testa at Non-Strophiolar Sites

1976 ◽  
Vol 3 (4) ◽  
pp. 465 ◽  
Author(s):  
LAT Ballard
Keyword(s):  
Mechanical Properties ◽  
Water Absorption ◽  
Water Repellency ◽  
Integrated System ◽  
Legume Seeds ◽  
Water Conduction

When impermeable legume seeds are made permeable to water by mechanical treatments that make strophioles conductive, it is not known whether the strophioles themselves must be acted on directly. To investigate this question the testas of individual seeds from the genera Medicago, Stylosanthes and Trifolium were either broken through completely by cutting, filing or piercing, or stressed by squeezing or striking, at sites remote from the strophioles. As determined by serial photography, 30-90 % of the previously impermeable seeds became conductive at the strophiole. These results indicate that the strophiole can become conductive without being acted on directly. They also suggest that the strophiole and general testa should be regarded as an integrated system in which both water-repellency and mechanical properties of the testa are important in the control of water absorption.

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