A preliminary study of improving the MICP effects via the extractions from seashell nacre

2022 ◽  
Vol 12 (1) ◽  
pp. 1-20
Author(s):  
X. Xu ◽  
H. Guo ◽  
M. Li ◽  
H. Fu

In microbially induced calcium carbonate precipitation (MICP) process, it is the precipitated CaCO3 that cements loose sand particles together to improve their mechanical properties. Seashell nacre composed of CaCO3 is a natural product, which is worth researching for its great hardness, strength, and toughness. However, there is no study connecting this natural nacre mineralization with MICP. Therefore, a precedent herein is established to modify the MICP process via the water-soluble matrix (WSM) extracted from nacre, where WSM contributes to the great mechanical properties of nacre. Correspondingly, this study examines the effects of WSM with different concentrations on urease activity and strength as well as microstructure of bio-cemented sand samples. The experimental results show that a small number of WSM (50mg/L) can improve the average strength of bio-cemented sand samples 1.5 times. This is because 50mg/L WSM can significantly improve the urease activity of bacteria meanwhile increasing the Ca2+ utilization rate. Thus, more CaCO3 crystals are precipitated, and the higher UCS of bio-cemented sand samples is achieved. Moreover, the XRD results indicate that the precipitated CaCO3 is almost calcite, and only a little aragonite is detected when the concentration of WSM increases to 100mg/L. Additionally, the SEM images demonstrate that WSM involvement can affect the shapes and sizes of CaCO3 crystals. Overall, this work is an unprecedented exploration imitating nacre that hopefully paves way for future studies.

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 830
Author(s):  
Julio Cesar Martinez-Garcia ◽  
Alexandre Serraïma-Ferrer ◽  
Aitor Lopeandía-Fernández ◽  
Marco Lattuada ◽  
Janak Sapkota ◽  
...  

In this work, the effective mechanical reinforcement of polymeric nanocomposites containing spherical particle fillers is predicted based on a generalized analytical three-phase-series-parallel model, considering the concepts of percolation and the interfacial glassy region. While the concept of percolation is solely taken as a contribution of the filler-network, we herein show that the glassy interphase between filler and matrix, which is often in the nanometers range, is also to be considered while interpreting enhanced mechanical properties of particulate filled polymeric nanocomposites. To demonstrate the relevance of the proposed generalized equation, we have fitted several experimental results which show a good agreement with theoretical predictions. Thus, the approach presented here can be valuable to elucidate new possible conceptual routes for the creation of new materials with fundamental technological applications and can open a new research avenue for future studies.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Hua Na ◽  
Guocheng Lv ◽  
Lijuan Wang ◽  
Libing Liao ◽  
Dan Zhang ◽  
...  

AbstractThe improper handling of smelting slag will seriously pollute the environment, and the unfilled roof of the goaf of the mine will threaten the safety of the mine. Expansion materials have attracted more and more attention because of their excellent properties. In this paper, copper-nickel smelting slag that has some active ingredients of gelling is used instead of traditional aggregate and some part of cement in order to reduce its pollution to the environment and its costs. For safety reasons, hydrogen peroxide was chosen as the foaming agent. Sodium silicate and hexadecyl trimethyl ammonium bromide (CTAB) are used as additives. Our results showed that after 28 days of curing, the material has better mechanical properties and the early compressive strength of the material was enhanced by sodium silicate. The efficiency of foaming was improved by CTAB. It also proves that copper–nickel smelting slag can be used in expansion material. At the same time, the utilization rate of the copper–nickel smelting slag of this formula can reach 70%, reduce its pollution to the environment.


Cellulose ◽  
2021 ◽  
Author(s):  
Marjo Määttänen ◽  
Maria Gunnarsson ◽  
Helena Wedin ◽  
Sara Stibing ◽  
Carina Olsson ◽  
...  

AbstractRecycling of textiles is of importance due to the large amount of waste generated from the increasing consumption and use worldwide. Cotton-rich pre-consumer textiles are considered as potential raw material for production of man-made regenerated fibres, but demands purification from the blends with synthetic fibres as well as the dyes and finishing chemicals. In this study we explore the use of different pre-treatments of pre-consumer textiles to meet specific parameters for production of fibres in the cold NaOH(aq) or cellulose carbamate process. The pre-treatments consisted of different bleaching sequences and were performed on both uncoloured and coloured pre-consumer textiles. For the uncoloured textile, degree of polymerisation and amount of inorganic content was efficiently reduced making the material suitable for both the cold NaOH(aq) and the cellulose carbamate process. In case of the coloured textile, the pre-treatments were able to remove the dye and decrease the inorganic content as well as reduce the degree of polymerisation but only sufficiently enough for production of fibres in the cellulose carbamate process. The work was able to prove a fibre-to-fibre concept while further optimisation of the regeneration steps is expected to improve the mechanical properties of the produced fibres in future studies.


Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 241
Author(s):  
Thangavel Ponrasu ◽  
Bei-Hsin Chen ◽  
Tzung-Han Chou ◽  
Jia-Jiuan Wu ◽  
Yu-Shen Cheng

The fast-dissolving drug delivery systems (FDDDSs) are developed as nanofibers using food-grade water-soluble hydrophilic biopolymers that can disintegrate fast in the oral cavity and deliver drugs. Jelly fig polysaccharide (JFP) and pullulan were blended to prepare fast-dissolving nanofiber by electrospinning. The continuous and uniform nanofibers were produced from the solution of 1% (w/w) JFP, 12% (w/w) pullulan, and 1 wt% Triton X-305. The SEM images confirmed that the prepared nanofibers exhibited uniform morphology with an average diameter of 144 ± 19 nm. The inclusion of JFP in pullulan was confirmed by TGA and FTIR studies. XRD analysis revealed that the increased crystallinity of JFP/pullulan nanofiber was observed due to the formation of intermolecular hydrogen bonds. The tensile strength and water vapor permeability of the JFP/pullulan nanofiber membrane were also enhanced considerably compared to pullulan nanofiber. The JFP/pullulan nanofibers loaded with hydrophobic model drugs like ampicillin and dexamethasone were rapidly dissolved in water within 60 s and release the encapsulants dispersive into the surrounding. The antibacterial activity, fast disintegration properties of the JFP/pullulan nanofiber were also confirmed by the zone of inhibition and UV spectrum studies. Hence, JFP/pullulan nanofibers could be a promising carrier to encapsulate hydrophobic drugs for fast-dissolving/disintegrating delivery applications.


2021 ◽  
Vol 11 (7) ◽  
pp. 3032
Author(s):  
Tuan Anh Le ◽  
Sinh Hoang Le ◽  
Thuy Ninh Nguyen ◽  
Khoa Tan Nguyen

The use of fluid catalytic cracking (FCC) by-products as aluminosilicate precursors in geopolymer binders has attracted significant interest from researchers in recent years owing to their high alumina and silica contents. Introduced in this study is the use of geopolymer concrete comprising FCC residue combined with fly ash as the requisite source of aluminosilicate. Fly ash was replaced with various FCC residue contents ranging from 0–100% by mass of binder. Results from standard testing methods showed that geopolymer concrete rheological properties such as yield stress and plastic viscosity as well as mechanical properties including compressive strength, flexural strength, and elastic modulus were affected significantly by the FCC residue content. With alkali liquid to geopolymer solid ratios (AL:GS) of 0.4 and 0.5, a reduction in compressive and flexural strength was observed in the case of geopolymer concrete with increasing FCC residue content. On the contrary, geopolymer concrete with increasing FCC residue content exhibited improved strength with an AL:GS ratio of 0.65. Relationships enabling estimation of geopolymer elastic modulus based on compressive strength were investigated. Scanning electron microscope (SEM) images and X-ray diffraction (XRD) patterns revealed that the final product from the geopolymerization process consisting of FCC residue was similar to fly ash-based geopolymer concrete. These observations highlight the potential of FCC residue as an aluminosilicate source for geopolymer products.


2019 ◽  
Vol 299 ◽  
pp. 06007
Author(s):  
Mircea Aurelian Antoniu Rusu ◽  
Sever-Adrian Radu ◽  
Catalin Moldovan ◽  
Codruta Sarosi ◽  
Ionela Amalia Mazilu (Moldovan) ◽  
...  

Although polyethylene terephthalate (PET) is a champion of recycling, intense research is being done to find new solutions for using recycled plastic. This study aims to characterize the mechanical andstructural properties (SEM- scanning electron microscopy) of products made from recycled metal swarf or mesh wire with recycled plastic (PET) in comparison with virgin plastic. Samples manufactured from virgin and recycled PET are made by pressing and high temperature. The loss of mechanical properties ofproducts made from recycled plastic is a major drawback that influences their use. SEM images confirm that the dispersion and distribution of the PET phase is not very uniform. By addition of virgin plastic in various compositions with recycled plastic, processing parameters and mechanical properties can be optimized.


2019 ◽  
Vol 16 (1) ◽  
pp. 27-30 ◽  
Author(s):  
Paiman Bawon ◽  
Seng Hua Lee ◽  
Nurul Fatiha Osman ◽  
Muhamad Suriadi Mohd Atkhar ◽  
Zaidon Ashaari

Author(s):  
Yangping Li ◽  
Yangyi Liu ◽  
Sihua Luo ◽  
Zi Wang ◽  
Ke Wang ◽  
...  

Abstract The attractive mechanical properties of nickel-based superalloys primarily arise from an assembly of γ′ precipitates with desirable size, volume fraction, morphology and spatial distribution. In addition, the solutioning cooling rate after super solvus heat treatment is critical for controlling the features of γ′ precipitates. However, the correlation between these multidimensional parameters and mechanical hardness has not been well established to date. Scanning electron microscope (SEM) images with different γ′ precipitates were investigated in this study, and artificial neural network (ANN) method was used to build a microstructure-mechanical property model. The critical step in this work is to extract different microstructural features from hundreds of SEM images. In order to improve the accuracy of prediction, the cooling rate was also considered as the input. In this work, the methodology was proved to be capable of bridging microstructural features and mechanical properties under the inspiration of material genome spirit.


Author(s):  
Sagar Sarkar ◽  
Cheruvu Siva Kumar ◽  
Ashish Kumar Nath

One of the most popular additive manufacturing processes is laser based direct metal laser sintering process which enables us to make complex three dimensional parts directly from CAD models. Due to layer by layer formation, parts built in this process tend to be anisotropic in nature. Suitable heat treatment can reduce this anisotropic behaviour by changing the microstructure. Depending upon the applications, a wide range of mechanical properties can be achieved between 482–621° C temperature for precipitation-hardened stainless steels. In the present study effect of different heat treatment processes, namely solution annealing, ageing and overaging, on tensile strength, hardness and wear properties has been studied in detail. Suitable metallurgical and mechanical characterization techniques have been applied wherever required, to support the experimental observations. Results show H900 condition gives highest yield strength and lowest tensile strain at break whereas solution annealing gives lowest yield strength and as-built condition gives highest tensile strain at break. SEM images show that H900 and H1150 condition produces brittle and ductile morphology respectively which in turn gives highest and lowest hardness value respectively.XRD analysis shows presence of austenite phases which can increase hardness at the cost of ductility. Average wear loss for H900 condition is highest whereas it is lowest for solution annealed condition. Further optical and SEM images have been taken to understand the basic wear mechanism involved.


2010 ◽  
Vol 36 (5) ◽  
pp. 357-362 ◽  
Author(s):  
Young-Seok Park ◽  
Seung-Pyo Lee ◽  
Chong-Hyun Han ◽  
Joo Hyun Kwon ◽  
Young-Chul Jung

Abstract This study was undertaken to evaluate the effect of microthread geometry of scalloped design implant on marginal bone resorption. Four types of scalloped design titanium implant specimens were prepared. The type 1 implant had a machined scalloped collar, type 2 had a sandblasted and acid-etched scalloped collar, type 3 had horizontal microthreads, and type 4 had parabolic microthreads, which are parallel with the scalloped conical margin. Two implants of a type were randomly installed immediately after extraction in the mandible of a beagle dog. Definitive prostheses were delivered immediately after surgery. After 12 weeks of healing, the dog was sacrificed and microtomography was performed. Type 4 specimens showed a marginal bone loss pattern definitively analogous to the scalloped margin. In this preliminary study, microthread geometry affected the marginal bone resorption pattern of scalloped design implants. However, additional specimens and more controlled conditions should be applied in future studies to confirm these results.


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