scholarly journals Sensitized Photolysis of Thioglycolic Acid in Aquatic Environment

2021 ◽  
Author(s):  
Angela Lis ◽  
Viorica Gladchi ◽  
Gheorghe Duca ◽  
Sergey Travin
Keyword(s):  
Aquatic Environment ◽  
Natural Waters ◽  
Thioglycolic Acid ◽  
Active Oxygen Species ◽  
Weather Conditions ◽  
Positive Influence ◽  
Time Of Day ◽  
Model Systems ◽  
Oxygen Species ◽  
Photochemical Transformations

The photochemical transformations of thioglycolic acid using model systems was studied by varying the irradiation sources and the kinetic parameters were determined. It was found that thioglycolic acid undergoes destruction on induced photolysis in the presence of humic substances, and its half-life can be estimated as 10-14 days, depending on weather conditions (cloudiness, time of day, season etc.). Results obtained in the course of this study on model systems were transferred to natural waters, and it was concluded that thioglycolic acid has a positive influence on the chemical self-purification processes of water, in the natural aquatic environment. This is manifested by increasing the self-purification capacity of water, due to the generation of active oxygen species, which lead to the degradation not only of this thiol, but of other pollutants present in aquatic environment, as well. At the same time, the products of the transformations are harmless to the aquatic environment and hydrobionts.

Characterization and functional properties of new everbearing strawberry (Fragaria x ananasa Duch.) cultivar, ‘Summertiara’ berries

2014 ◽  
Vol 4 (1) ◽  
pp. 1 ◽  
Author(s):  
Takeshi Nagai ◽  
Misuzu Tamai ◽  
Masato Sato ◽  
Yasuhiro Tanoue ◽  
Norihisa Kai ◽  
...  
Keyword(s):  
Vitamin C ◽  
Sensory Evaluation ◽  
Functional Properties ◽  
Active Oxygen Species ◽  
Active Oxygen ◽  
Antihypertensive Activity ◽  
Oxygen Species ◽  
Total Anthocyanins ◽  
Strawberry Cultivar ◽  
The Stability

Background: In recent years, a new everbearing strawberry cultivar, ‘Summertiara’ was cultivated to supply the strawberries in pre-harvest season from July to October in Japan. For highly research and development of processing of this cultivar, ‘Summertiara’ berries, the objective of this study was to characterize these berries, with relation to chemical parameters, total phenols, total flavonoids, total vitamin C, and total anthocyanins, and was to investigate the solubility and the stability of anthocyanins from the berries. Moreover, the functional properties such as antioxidative activity, active oxygen species scavenging activity, and antihypertensive activity were also evaluated.Methods: Chemical analysis, colour measurement, and sensory evaluation of new everbearing strawberry cultivar, ‘Summertiara’ berries were performed. Next, the solubility of anthocyanins from the berries and stability of these against pH, temperature, and an incandescent lighting were investigated. Moreover, functional properties of the extracts prepared from berries were elucidated using 5 different methods.Results: The contents of water, proteins, lipids, carbohydrates, and ash were the same as those of other cultivar berries. The sugar-acid ratio in the berries was low; these were acidulous. By sensory evaluation, the main factors were vivid red colour, aroma, and acidity. The berries were rich in phenols, flavonoids, vitamin C, and anthocyanins. The anthocyanins of the berries became unstable by heat treatment and light exposures such as visible rays. On the other hand, the extracts prepared from the berries showed the functionalities such as antioxidant activity, active oxygen species scavenging activities, and antihypertensive activity.  Conclusions: The strawberry cultivar, ‘Summertiara’ berries were the most suitable for processing ingredient of strawberry-derived products with superior health promoting functionalities.Keywords: Summertiara, everbearing strawberry cultivar, characterization, sensory evaluation, color and storage, functional property

REAL CONDITION AND PROSPECTS OF DEVELOPMENT OF THE RADAR STATIONS OF THE COUNTER BATTERY FIGHTINGV

2019 ◽  
Vol 1 (12) ◽  
pp. 30-40
Author(s):  
V. Нolovan ◽  
V. Gerasimov ◽  
А. Нolovan ◽  
N. Maslich
Keyword(s):  
Comparative Analysis ◽  
Real Time ◽  
Weather Conditions ◽  
Time Of Day ◽  
Current Position ◽  
Real Condition ◽  
Leading Role ◽  
Artillery Shell

Fighting in the Donbas, which has been going on for more than five years, shows that a skillful counter-battery fight is an important factor in achieving success in wars of this kind. Especially in conditions where for the known reasons the use of combat aviation is minimized. With the development of technical warfare, the task of servicing the counter-battery fight began to rely on radar stations (radar) to reconnaissance the positions of artillery, which in modern terms are called counter-battery radar. The principle of counter-battery radar is based on the detection of a target (artillery shell, mortar mine or rocket) in flight at an earlier stage and making several measurements of the coordinates of the current position of the ammunition. According to these data, the trajectory of the projectile's flight is calculated and, on the basis of its prolongation and extrapolation of measurements, the probable coordinates of the artillery, as well as the places of ammunition falling, are determined. In addition, the technical capabilities of radars of this class allow you to recognize the types and caliber of artillery systems, as well as to adjust the fire of your artillery. The main advantages of these radars are:  mobility (transportability);  inspection of large tracts of terrain over long distances;  the ability to obtain target's data in near real-time;  independence from time of day and weather conditions;  relatively high fighting efficiency. The purpose of the article is to determine the leading role and place of the counter-battery radar among other artillery instrumental reconnaissance tools, to compare the combat capabilities of modern counter-battery radars, armed with Ukrainian troops and some leading countries (USA, China, Russia), and are being developed and tested in Ukraine. The method of achieving this goal is a comparative analysis of the features of construction and combat capabilities of modern models of counter-battery radar in Ukraine and in other countries. As a result of the conducted analysis, the directions of further improvement of the radar armament, increasing the capabilities of existing and promising counter-battery radar samples were determined.

scholarly journals Ambient base-free glycerol oxidation over bimetallic PdFe/SiO2 by in situ generated active oxygen species

2021 ◽  
Author(s):  
Ricci Underhill ◽  
Mark Douthwaite ◽  
Richard J. Lewis ◽  
Peter J. Miedziak ◽  
Robert D. Armstrong ◽  
...  
Keyword(s):  
Heterogeneous Catalysts ◽  
Bimetallic Catalyst ◽  
Electron Paramagnetic Resonance Spectroscopy ◽  
Active Oxygen Species ◽  
Catalytic Performance ◽  
Resonance Spectroscopy ◽  
Oxygen Species ◽  
Paramagnetic Resonance ◽  
Temperature Oxidation

AbstractLow temperature oxidation of alcohols over heterogeneous catalysts is exceptionally challenging, particularly under neutral conditions. Herein, we report on an efficient, base-free method to oxidise glycerol over a 0.5%Pd-0.5%Fe/SiO2 catalyst at ambient temperature in the presence of gaseous H2 and O2. The exceptional catalytic performance was attributed to the in situ formation of highly reactive surface-bound oxygenated species, which promote the dehydrogenation on the alcohol. The PdFe bimetallic catalyst was determined to be significantly more active than corresponding monometallic analogues, highlighting the important role both metals have in this oxidative transformation. Fe leaching was confirmed to occur over the course of the reaction but sequestering experiments, involving the addition of bare carbon to the reactions, confirmed that the reaction was predominantly heterogeneous in nature. Investigations with electron paramagnetic resonance spectroscopy suggested that the reactivity in the early stages was mediated by surface-bound reactive oxygen species; no homogeneous radical species were observed in solution. This theory was further evidenced by a direct H2O2 synthesis study, which confirmed that the presence of Fe in the bimetallic catalyst neither improved the synthesis of H2O2 nor promoted its decomposition over the PdFe/SiO2 catalyst.

Identifying the Active Oxygen Species in SnO2 Based Gas Sensing Materials: An Operando IR Spectrsocopy Study

2015 ◽  
Vol 119 (21) ◽  
pp. 11792-11799 ◽  
Author(s):  
David Degler ◽  
Susanne Wicker ◽  
Udo Weimar ◽  
Nicolae Barsan
Keyword(s):  
Gas Sensing ◽  
Active Oxygen Species ◽  
Active Oxygen ◽  
Oxygen Species ◽  
Ir Spectrsocopy

Chromosome damage caused by enzymically generated active oxygen species

1983 ◽  
Vol 18 ◽  
pp. 47
Author(s):  
B.J. Phillips ◽  
T.E.B. James ◽  
D. Anderson
Keyword(s):  
Active Oxygen Species ◽  
Active Oxygen ◽  
Chromosome Damage ◽  
Oxygen Species

The influence and importance of daily weather conditions in the supply of chloride, sulphate and other ions to fresh waters from atmospheric precipitation

1958 ◽  
Vol 244 (1236) ◽  
pp. 140-140
Keyword(s):  
Sulphuric Acid ◽  
Atmospheric Pollution ◽  
Natural Waters ◽  
Sea Water ◽  
Atmospheric Precipitation ◽  
Weather Conditions ◽  
Sea Spray ◽  
Lake District ◽  
The South ◽  
Soil Weathering

This paper deals with chemical analyses for hydrogen, sodium, potassium, calcium, chloride, sulphate and nitrate ions in daily precipitation samples collected in the English Lake District, and examines the correlations of these analyses with ( a ) one another, ( b ) the amount of precipitation, ( c ) wind direction, ( d ) wind velocity, and ( e ) temperature. Highly significant correlations are found between estimates for H, K, Ca, NO 3 and SO 4 ions, and atmospheric pollution appears to supply much of the sulphate in Lake District rain, since it comes largely as sulphuric acid from the south-east. The correlation between Na and Cl is also extremely close, with the proportion between the two ions very similar to that in sea water. Since these two ions are supplied mainly from the south-west, in amounts which are greatly increased by high winds, sea spray may be inferred as the principal source. Nevertheless, evidence is presented for some small supply from atmospheric pollution, and it is furthermore suggested that mixed droplets of sea salt and sulphuric acid may, upon abstraction of moisture by freezing or evaporation, release gaseous hydrogen chloride to the air and so alter the balance of Na and Cl in precipitation. The supply of Na and Cl is also considerably higher in cold than in warm weather, a phenomenon possibly connected with stormier conditions and greater evaporation over the Atlantic Ocean. The atmospheric contribution of ions to natural waters via precipitation is shown to be of great importance, in particular to bog pools, to upland tarns on hard rocks, and to the soil solution in highly organic mor humus layers overlying heavily leached hillside soils. Sodium and chloride in most surface waters appears to be almost wholly supplied by sea spray, while calcium and magnesium bicarbonates are the main products of soil weathering. A net loss of rain acids is evident in all soil waters, although some may be more acid than normal rain water owing to considerable concentration by evaporation. The soil waters are relatively rich in potassium, presumably supplied from decaying vegetation.

Nitric oxide and active oxygen species in severe sepsis and surgically stressed patients

Surgery Today ◽  
1995 ◽  
Vol 25 (9) ◽  
pp. 774-777 ◽  
Author(s):  
Katsuhisa Tanjoh ◽  
Atsuyuki Shima ◽  
Mitsuhiro Aida ◽  
Ryouichi Tomita ◽  
Yasuhiko Kurosu
Keyword(s):  
Nitric Oxide ◽  
Severe Sepsis ◽  
Active Oxygen Species ◽  
Active Oxygen ◽  
Oxygen Species
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