Rubber bark dust-zeolite composite improved mechanic strength of soft paddy soil through improved microstructure

<p>Soft paddy soils are not a stable soil structure that leads to the decline of rice production in Kedah, Malaysia. The soil had high compressibility and water content, and low soil strength thus the agricultural machines could not be operated above this soil. Therefore, this study was conducted to improve the mechanical strength of soft soils in paddy fields using an organic amendment. The organic amendment used in this study was made from amended materials comprising clinoptilolite, kieserite, humic acid, and rubber bark dust. The study was carried out in the paddy field area of Alor Pudak district, Kedah, Malaysia, and it was divided into five treatments of amendment dose, i.e: 0 kg (control or P0), 125 kg (P1), 250 kg (P2), 375 kg (P3) and 500 kg (P4) with each plot size about 0.20 ha. The soil samples were then analyzed using X-ray diffraction (XRD), scanning electron microscope (SEM), and the unconsolidated undrained triaxial compression test (UU-test) to characterize their amended properties. The XRD results clearly exhibited changes in the mineralogical composition of all treated plots with an increasing smectite content (1200 to 1300 intensity). Furthermore, the SEM results showed that clay particles in the treated plots have been flocculated to form close-knit, more stable soil structures. After the organic amendment application, the mechanical strength of the treated plots increased to an optimum level (50 kPa in P2) for resisting mechanical pressure from agricultural machinery. Overall, this study of the efficacy of organic amendment offers new insight into a soft paddy soil remediation method that is more effective and economical than the conventional method.</p>

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Effect of Different Mineralization Modes on Strengthening Calcareous Sand under Simulated Seawater Conditions

Sustainability ◽

10.3390/su13158265 ◽

2021 ◽

Vol 13 (15) ◽

pp. 8265

Author(s):

Shiyu Liu ◽

Bowen Dong ◽

Jin Yu ◽

Yanyan Cai ◽

Xingqian Peng ◽

...

Keyword(s):

Mechanical Strength ◽

Construction Projects ◽

Construction Material ◽

X Ray Diffraction ◽

Calcareous Sand ◽

Sand Column ◽

Sporosarcina Pasteurii ◽

Phosphate Mineralization ◽

Filling Water ◽

Simulated Seawater

Calcareous sand, as a blow-fill or construction material, is widely used in island and reef construction projects in marine environments after treatment. When microorganism-induced mineralization is used to strengthen calcareous sand, salinity and other conditions in the marine environment will adversely affect microorganisms or their mineralization process. For this reason, the two environmental conditions created by deionized water and simulated seawater were introduced to explore their effects on the growth and urease activity of Sporosarcina pasteurii. Then, the changes in the permeability and mechanical strength of calcareous sand under different mineralization methods were compared by one-dimensional sand column tests. Finally, the reinforcement mechanism was compared and analyzed based on the results of scanning electron microscopy and X-ray diffraction tests. The results show that Sporosarcina pasteurii can induce carbonate and phosphate precipitation and mineralization to strengthen calcareous sand in simulated seawater. The mineralized products greatly reduce the permeability of calcareous sand and significantly improve the mechanical strength by wrapping calcareous sand particles, filling water seepage channels and cementing adjacent particles. The reinforcement effect of carbonate mineralization is better than that of phosphate mineralization, but phosphate mineralization has less impact on the environment during the treatment process.

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Sedimentary Clays as Geopolymer Precursor

International Journal of Engineering Research in Africa ◽

10.4028/www.scientific.net/jera.39.97 ◽

2018 ◽

Vol 39 ◽

pp. 97-111

Author(s):

F. Mostefa ◽

Nasr Eddine Bouhamou ◽

H.A. Mesbah ◽

Salima Aggoun ◽

D. Mekhatria

Keyword(s):

Sodium Hydroxide ◽

Mineralogical Composition ◽

Cementitious Materials ◽

Raw Material ◽

X Ray Diffraction ◽

Calcination Time ◽

Calorimetric Analysis ◽

X Ray ◽

Before And After ◽

Mechanical Performances

This work aims to study the feasibility of making a geopolymer cement based on dredged sediments, from the Fergoug dam (Algeria) and to evaluate their construction potential particularly interesting in the field of special cementitious materials. These sediments due to their mineralogical composition as aluminosilicates; are materials that can be used after heat treatment. Sedimentary clays were characterized before and after calcination by X-ray diffraction, ATG / ATD, spectroscopy (FTIR) and XRF analysis. The calcination was carried out on the raw material sieved at 80 μm for a temperature of 750 ° C, for 3.4 and 5 hours. The reactivity of the calcined products was measured using isothermal calorimetric analysis (DSC) on pastes prepared by mixing an alkaline solution of sodium hydroxide (NaOH) 8 M in an amount allowing to have a Na / Al ratio close to 1 (1: 1). Also, cubic mortar samples were prepared with a ratio L / S: 0.8, sealed and cured for 24 hours at 60 ° C and then at room temperature until the day they were submited to mechanical testing. to check the extent of geopolymerization. The results obtained allowed to optimize the calcination time of 5 hours for a better reactivity of these sediments, and a concentration of 8M of sodium hydroxide and more suitable to have the best mechanical performances.

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Physicochemical Properties of Handere Clays and Their Use as a Building Material

Journal of Chemistry ◽

10.1155/2015/374245 ◽

2015 ◽

Vol 2015 ◽

pp. 1-6 ◽

Cited By ~ 4

Author(s):

Yasin Erdoğan

Keyword(s):

Physicochemical Properties ◽

Building Materials ◽

Raw Materials ◽

Organic Matter Content ◽

Volcanic Glass ◽

Mineralogical Composition ◽

Matter Content ◽

Loss On Ignition ◽

X Ray Diffraction ◽

Clay Deposits

Handere clay deposits were discovered at Adana in Turkey. These clay units primarily consist of uncoloured claystone, pebbly sandstone, sandstone, siltstone, and mudstone marl and include gypsum lenses and clay levels of various thicknesses in places. The physicochemical properties of these clays have been investigated by different techniques including Scanning Electron and Elemental Analysis (SEM and EDS), mineralogical analyses, chemical and physical analyses, X-ray diffraction (XRD), thermogravimetric differential thermal analysis (TG-DTA), and Atterberg (Consistency) Limits Test. The mineralogical composition deduced from XRD is wide (smectite + palygorskite + illite ± feldspar ± chlorite ± quartz ± calcite ± serpentine) due to the high smectite contents (≈85%). SEM studies reveal that smectite minerals are composed of irregular platy leaves and show honeycomb pattern in the form of wavy leaves in places. The leaves presenting an array with surface edge contact are usually concentrated in the dissolution voids and fractures of volcanic glass. Organic matter content and loss on ignition analysis of raw materials are good for all the studied samples. In summary, Handere clays can be used as building materials in bricks, roof tiles, and cement and as a binder.

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Crystallization of simonkolleite (Zn5Cl2(OH)8 ∙ H2O) in powder samples prepared for mineral composition analysis by quantitative X-ray diffraction (QXRD)

Nafta-Gaz ◽

10.18668/ng.2021.05.02 ◽

2021 ◽

Vol 77 (5) ◽

pp. 293-298

Author(s):

Urszula Zagórska ◽

◽

Sylwia Kowalska ◽

Keyword(s):

Quantitative Analysis ◽

Internal Standard ◽

Mineralogical Composition ◽

Hydrocarbon Exploration ◽

Composition Analysis ◽

Internal Standard Method ◽

X Ray Diffraction ◽

Method Error ◽

X Ray ◽

Significant Difference

The analysis of mineralogical composition by quantitative X-ray diffraction (QXRD) is one of the standard research methods used in hydrocarbon exploration. In order to improve it and to obtain better results, the methodology of quantitative analysis used at Well Logging Department is being periodically (more or less) modified. After the introduction of the improvements, comparative analyses were performed on archival samples. Reflections from an unidentified phase which did not occur in the tested Rotliegend sandstone samples were noticed on X-ray diffractograms of archival samples. Reflections of a mineral called simonkolleite were identified in the X-ray diffraction database. Chemically it is a hydrated zinc chloride of the formula: Zn5Cl2(OH)8 × H2O. Analysis of the composition of samples in which simonkolleite crystallised, indicated that the mineral is being formed in the result of the slow reaction of zinc oxide with halite (NaCl) and water vapour. An attempt was made to determine the influence of the presence of this mineral on the results of the quantitative analysis of mineralogical composition. The above methodology was applied on a group of ten samples. The results of the quantitative analysis conducted for archival samples stored with added zincite standard containing simonkolleite and for new, freshly grinded (without artifact) samples were compared. The comparison of the obtained results showed a slight influence of this mineral on the quantitative composition of the remaining components. The difference between the results usually did not exceed the method error. At the same time a significant difference in the calculated content of the internal standard was noted – on average 1% less in archival than in new samples. This shows that the reaction occurring in the archival samples will affect the evaluation of the quality of the obtained quantitative analysis, at the same time excluding the possibility of determining the rock’s amorphous substance content with the internal standard method.

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A prototype handheld X-ray diffraction instrument

Journal of Applied Crystallography ◽

10.1107/s1600576718012943 ◽

2018 ◽

Vol 51 (6) ◽

pp. 1571-1585 ◽

Cited By ~ 1

Author(s):

Graeme Hansford

Keyword(s):

Sample Preparation ◽

Mineralogical Composition ◽

General Purpose ◽

Performance Criteria ◽

X Ray Diffraction ◽

X Ray ◽

Fine Grained ◽

Back Reflection ◽

Promising Area ◽

Sample Position

A conceptual design for a handheld X-ray diffraction (HHXRD) instrument is proposed. Central to the design is the application of energy-dispersive XRD (EDXRD) in a back-reflection geometry. This technique brings unique advantages which enable a handheld instrument format, most notably, insensitivity to sample morphology and to the precise sample position relative to the instrument. For fine-grained samples, including many geological specimens and the majority of common alloys, these characteristics negate sample preparation requirements. A prototype HHXRD device has been developed by minor modification of a handheld X-ray fluorescence instrument, and the performance of the prototype has been tested with samples relevant to mining/quarrying and with an extensive range of metal samples. It is shown, for example, that the mineralogical composition of iron-ore samples can be approximately quantified. In metals analysis, identification and quantification of the major phases have been demonstrated, along with extraction of lattice parameters. Texture analysis is also possible and a simple example for a phosphor bronze sample is presented. Instrument formats other than handheld are possible and online process control in metals production is a promising area. The prototype instrument requires extended measurement times but it is argued that a purpose-designed instrument can achieve data-acquisition times below one minute. HHXRD based on back-reflection EDXRD is limited by the low resolution of diffraction peaks and interference by overlapping fluorescence peaks and, for these reasons, cannot serve as a general-purpose XRD tool. However, the advantages ofin situ, nondestructive and rapid measurement, tolerance of irregular surfaces, and no sample preparation requirement in many cases are potentially transformative. For targeted applications in which the analysis meets commercially relevant performance criteria, HHXRD could become the method of choice through sheer speed and convenience.

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The mineralogy and firing behaviour of pottery clays of the Lake Van region, eastern Turkey

Clay Minerals ◽

10.1180/claymin.2017.052.4.04 ◽

2017 ◽

Vol 52 (4) ◽

pp. 453-468 ◽

Cited By ~ 2

Author(s):

A. Aras ◽

S. Kiliç

Keyword(s):

East Coast ◽

Chemical Characterization ◽

Mineralogical Composition ◽

Lake Van ◽

X Ray Diffraction ◽

Pottery Production ◽

X Ray ◽

Different Types ◽

Firing Shrinkage

AbstractThe present study focused on the mineralogical and chemical characterization and firing behaviour of clays from the Lake Van region and compared them with the same characteristics established for two ancient pot sherds. Four pottery clays collected from Kutki and Kuşluk in the Kesan Valley to the south, from Kavakbaşı to the southwest and from Bardakçı village on the east coast of Lake Van were analysed by X-ray diffraction to identify mineralogical composition (bulk clays and <2 μm fractions after heating at 300–500°C and ethylene glycol solvation). Further analyses were conducted to determine the size distribution, chemical composition and physical properties of test bodies derived from these clays. The in situ weathered schist forming the primary micaceous red clays which are suitable for local pottery production are characterized by large muscovite-sericite-illite and small calcite contents. In contrast, the Bardakçı clays are dominated by large smectite contents and are only used sparingly in mixtures of local pottery production because they undergo firing shrinkage and present drying and firing flaws in the fired bodies. Firing ranges of ~800–900°C were inferred from the mineralogy and colours of the two ancient sherds from Kutki. As a result of mineralogical analysis of fired and unfired test bodies of these pottery clays and pot sherds, two different types of pastes were determined for pottery production in the Lake Van region: metamorphic and volcanic paste, the former characterized by a calcite-poor and mica-sericite-rich matrix and the latter by large smectite and small calcite contents.

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The Mineralogical Composition of Samos Zeoliitic Rocks and their potential use as Feed Additives and Nutrition Supplements

Bulletin of the Geological Society of Greece ◽

10.12681/bgsg.20706 ◽

2020 ◽

Vol 56 (1) ◽

pp. 84

Author(s):

Anestis Filippidis ◽

Christina Mytiglaki ◽

Nikolaos Kantiranis ◽

Ananias Tsirambides

Keyword(s):

Clay Minerals ◽

Animal Species ◽

Mineralogical Composition ◽

Feed Additives ◽

Feed Additive ◽

X Ray Diffraction ◽

Eu Regulation ◽

Fibrous Minerals ◽

Potential Use ◽

The Eu

Fifteen (15) zeolitic rocks from Karlovassi-Marathokampos basin of Samos Island (Greece) were investigated for their mineralogical composition by X-Ray Diffraction (XRD) method. According to EU Regulation No 651/2013, clinoptilolite of sedimentary origin with ≥80 wt% clinoptilolite, ≤20 wt% clay minerals, free of fibres and quartz, can be used as feed additive for all animal species. Depending on the zeolites, the zeolitic rocks are grouped to those containing: Clinoptilolite (33-86 wt%), clinoptilolite (59 wt%) + mordenite (20-21 wt%), clinoptilolite (22 wt%) + analcime (29 wt%), clinoptilolite (17 wt%) + phillipsite (27 wt%), analcime (29-70 wt%), mordenite (62%) and chabazite (63 wt%). None of the clinoptilolite-containing rocks (10 samples) meet the requirements of the EU Regulation No 651/2013, and thus cannot be used as feed additives for all animal species and consequently as nutrition supplements, since all of them contain 2-5 wt% quartz, two of them 20-21 wt% mordenite (fibrous zeolite), nine of them <80 wt% clinoptilolite (17-73 wt%) and two of them >20 wt% clay minerals (27-42 wt%). Although the EU Regulation No 651/2013 refers to clinoptilolite of sedimentary origin, using the presence or absence of quartz and fibrous minerals, none of the five mordenite, analcime and chabazite containing zeolitic rocks, can be used as feed additives and nutrition supplements, since all of them contain 2-6 wt% quartz and one of them contains 62 wt% mordenite (fibrous zeolite).

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Brittleness Evaluation in Shale Gas Reservoirs and Its Influence on Fracability

Energies ◽

10.3390/en13020388 ◽

2020 ◽

Vol 13 (2) ◽

pp. 388 ◽

Cited By ~ 2

Author(s):

Yapei Ye ◽

Shuheng Tang ◽

Zhaodong Xi

Keyword(s):

Shale Gas ◽

Evaluation Method ◽

Triaxial Compression ◽

Horizontal Stress ◽

Brittleness Index ◽

X Ray Diffraction ◽

Elastic Parameters ◽

Gas Reservoirs ◽

Shale Gas Reservoirs ◽

Minimum Horizontal Stress

The brittleness index (BI) is a key parameter used to identify the desirable fracturing intervals of shale gas reservoirs. Its correlation with fracability is still controversial. There have been a variety of methods proposed that can estimate BI. The brittleness evaluation method based on stress-strain curves according to the energy-balanced law is the most suitable and reliable in this study. Triaxial compression test, optical microscopy and scanning electron microscopy (SEM) observation, and X-ray diffraction analysis (XRD) were performed on nine drill core samples from well SY3 located in the peripheral regions of Sichuan Basin, China. These tests further evaluated several commonly used methods (brittleness indices based on rock elastic parameters, rock mineral compositions) and determined the relationship between brittleness, rock elastic parameters, and the content of minerals. The results obtained indicate that for sedimentary rocks, a higher Young’s modulus reduces the brittleness of rock, and Poisson’s ratio weakly correlates with brittleness. Excessive amounts of quartz or carbonate minerals can increase the cohesiveness of rock, leading to poor brittleness. Furthermore, the most suitable fracturing layers possess a high brittleness index and low minimum horizontal stress.

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Geochemical Appraisal of the Mamu Shales Exposed around Igodor in the Benin Flank of the Anambra Basin, Nigeria

Journal of Applied Sciences and Environmental Management ◽

10.4314/jasem.v24i3.15 ◽

2020 ◽

Vol 24 (3) ◽

pp. 489-493

Author(s):

M.E. Okiotor ◽

E.J. Ighodaro

Keyword(s):

Inductively Coupled Plasma ◽

Mineralogical Composition ◽

Field Studies ◽

X Ray Diffraction ◽

Inductively Coupled ◽

Anambra Basin ◽

Icp Ms ◽

Edo State ◽

Depositional Setting ◽

Representative Samples

The Auchi area of Edo state which lies within the Benin flank of the Anambra Basin host shaly sediment exposures that have been classified by previous researches as units of the Mamu Formation. This study evaluated samples of this sediment from Igodor near Auchi for its geochemical and mineralogical properties, and intereted its, depositional environment and geotectonic setting. In order to achieve this, field studies were carried out and representative samples obtained for Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) analyses of major oxides, trace and rare earth elements. X-Ray Diffraction analysis was also carried out to determine the mineralogical composition. Some of the minerals determined were Aragonite and galena. Binary plots, triplots and elemental ratio plots including SiO2/, Al2O3, Th/Sc, Th/Co and La/Sc , Th-Sc-Zr, and the abundance of Cr, Ni were employed to determine the provenance. The concentration of detrital indicators such as SiO2, Al2O3 and TiO2, with averages of 51.95, 25.34 and 1.39 respectively, indicate high detrital influx into the Benin Flank of the Anambra basin. SiO2/Al2O3 ratios of 1.80-2.20, indicate that the shales were made up of pure kaolinite. The Ni and Cr abundance indicated a mafic and felsic provenance for the sediments, however, Th/Sc, Th/Co and La/Sc ratios show that the provenance was predominantly felsic, while the Th-Sc-Zr triplot shows that the depositional setting was passive.

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The manganese oxide mineral, lithiophorite, in an oxisol From Hawaii

Soil Research ◽

10.1071/sr9930051 ◽

1993 ◽

Vol 31 (1) ◽

pp. 51 ◽

Cited By ~ 19

Author(s):

DC Golden ◽

JB Dixon ◽

Y Kanehiro

Keyword(s):

Electron Microscopy ◽

Clay Fraction ◽

Hydroxylamine Hydrochloride ◽

Mineralogical Composition ◽

Soil Horizon ◽

X Ray Diffraction ◽

High Gradient Magnetic Separation ◽

X Ray ◽

Tropeptic Eutrustox ◽

Treated Sample

The mineralogical composition of the surface soil horizon (0-15 cm) of Wahiawa soil (Tropeptic Eutrustox) was investigated by X-ray diffraction (XRD), high gradient magnetic separation (HGMS), transmission electron microscopy (TEM), and infrared methods. The concentration of lithiophorite decreased with particle size and none was present in the clay fraction as indicated by XRD. Lithiophorite was further concentrated from the crushed sand-sized fraction by HGMS. Hexagonal, electron-dense, often twinned lithiophorite particles were identified by electron diffraction. Differential infrared (DIR) spectra obtained by dissolving Mn oxides in acidified hydroxylamine hydrochloride (HAHC) indicated lithiophorite as the HAHC-soluble Mn-phase. Lithiophorite compositiion, as revealed by chemical analysis of the HAHC extracts, consisted of appreciable amounts of Mn, Al, Zn, Co and Mg, and less than stoichiometric amounts of Li. Sodium hydroxide treatment apparently altered the lithiophorite, as revealed by the DIR spectrum of the hydroxylamine-soluble fraction of the NaOH-treated sample compared with the untreated sample. The high crystallinity of the lithiophorite was suggested by its resistance to chemical dissolution and narrow X-ray diffraction lines. No evidence for the presence of todorokite or birnessite was found, contrary to earlier reports. Examination of sand-sized nodules by scanning electron microscopy indicated large (2-5 �m) platy lithiophorite crystals at the surface of these nodules. Electron microprobe analysis of these platy particles indicated iron enrichment near the surface. The freshly fractured nodule surface revealed numerous unaltered platy crystals of lithiophorite filling the veins of the nodule.

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