scholarly journals Design and Manufacturing of Low Relative Humidity Chamber for Laser Processing of Lithium Metal

Author(s):  
Dongkyu Park ◽  
Dongkyoung Lee

Abstract In order to overcome the energy density limitations of lithium-ion batteries consisting of graphite anodes, studies on lithium metal batteries (LMBs) have been actively conducted. However, most LMBs related studies focus on suppressing the growth of unpredictable dendrites. Research for production processes has been rarely conducted. In the paper, laser processing is introduced to improve the drawback of conventional processing for Li metal. Moreover, a low humidity maintenance chamber is manufactured to prevent oxidation of Li metal during laser processing because Li metal easily reacts with moisture. The chamber has a closed space that does not allow outside air to enter, and a glass that allows the laser beam to pass through is installed at the upper part. In addition, silica gel is installed to maintain low relative humidity. The dew point inside the chamber drops to -17.4 ℃ in 1 hour. This result implies that the chamber can prevent Li metal oxidation. Next, we analyze the effect of transparent plate glass on laser beam with Gaussian distribution. Finally, it is confirmed through experiments that lithium metal is not contaminated by moisture during laser processing using a manufactured chamber.

2021 ◽  
Vol 910 (1) ◽  
pp. 012010
Author(s):  
Wedyan G. Nassif ◽  
Sundus H. Jaber ◽  
Salwa S. Naif ◽  
Osama T. Al-Taai

Abstract Relative humidity can be inferred from the dew point values. When the air temperature and dew point temperatures are very close, the air has high relative humidity. The converse is true when there is a large difference between the air temperature and the dew point temperature, indicating the presence of low humidity air. To understand the expected changes in the climatic elements in the atmosphere, changes in temperature behavior, dew point, and relative humidity have been studied This study used data obtained from the European Center (ECMWF), which includes monthly and annual mean temperatures, dew, and relative humidity during the period (1988-2018) for selected stations in Iraq. The highest values of temperature and dew were recorded in July and August, and they were accompanied by a decrease in relative humidity. The highest value of relative humidity was recorded in December and January, accompanied by a decrease in temperature and dew, as we note through the results that there is an inverse relationship between relative humidity, temperature, and dew point Relative humidity changes when the temperature rises or falls, and the relative humidity may be higher in the morning when the temperature drops. The lowest amount of relative humidity during the day is when the temperature rises, the highest temperature value was recorded on 21July 2017 (12:00 PM) for Basra Station, while the highest relative value is humidity in Basra Governorate. Mosul station on January 21, 2014 (12:00 AM), and the reason is due to meteorological factors and the nature of the geographical area.


2021 ◽  
Author(s):  
Lei Ye ◽  
Meng Liao ◽  
Xiangran Cheng ◽  
Xufeng Zhou ◽  
Yang Zhao ◽  
...  

2021 ◽  
Vol 41 ◽  
pp. 102812
Author(s):  
Simone Casino ◽  
Thomas Beuse ◽  
Verena Küpers ◽  
Markus Börner ◽  
Tobias Gallasch ◽  
...  

Physchem ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 26-44
Author(s):  
Chiara Ferrara ◽  
Riccardo Ruffo ◽  
Piercarlo Mustarelli

Extended interphases are playing an increasingly important role in electrochemical energy storage devices and, in particular, in lithium-ion and lithium metal batteries. With this in mind we initially address the differences between the concepts of interface and interphase. After that, we discuss in detail the mechanisms of solid electrolyte interphase (SEI) formation in Li-ion batteries. Then, we analyze the methods for interphase characterization, with emphasis put on in-situ and operando approaches. Finally, we look at the near future by addressing the issues underlying the lithium metal/electrolyte interface, and the emerging role played by the cathode electrolyte interphase when high voltage materials are employed.


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