Dissociation of gas hydrates in frozen sands: effect on gas permeability.

2020 ◽  
Author(s):  
Jongwon Jung ◽  
Jaeeun Ryou ◽  
Joo Yong Lee ◽  
Riyadh I AI-Raoush ◽  
Khalid Alshibli ◽  
...  

<p>Gas hydrates are potential energy resources which can be formed at low temperature and high pressure. The number of recoverable gas hydrates are limited due to the specific temperature, pressure conditions and technical limitations of gas production. Various production methods have been studied around the world to overcome these technical limitations. Gas production methods from gas hydrates are divided into methods of dissociating gas hydrates and non-dissociating gas hydrates. The dissociation methods including depressurization method, thermal injection method, and chemical inhibitor injection method can decrease in effective stress of the ground due to phase conversion. On the other hand, CH<sub>4</sub>-CO<sub>2 </sub>replacement method is geomechanically stable because it does not dissociate gas hydrates. Also, CH<sub>4</sub>-CO<sub>2 </sub>replacement method has the advantage of sequestering carbon dioxide while producing methane. However, CH<sub>4</sub>-CO<sub>2</sub> replacement method has the disadvantage such as low production efficiency and understanding kinetics of gas production. In this study, soaking, gas permeability of gas hydrate layer and hydrate saturation are considered in order to promote the production efficiency of CH<sub>4</sub>-CO<sub>2</sub> replacement method. Results show that production efficiency increases with the number of soaking process, the higher gas permeability and hydrate saturation. According to the experimental results in this study, the production efficiency can be increased by considering the soaking time, procedure and selecting the proper gas hydrates site.</p><p>Acknowledgement</p><p>This work is supported by the Korea Agency for Infrastructure Technology Advancement(KAIA) grant funded by the Ministry of Land, Infrastructure and Transport (Grant 20CTAP-C152100-02). Also, it is supported by partial funding from NPRP grant # NPRP8-594-2-244 from the Qatar national research fund (a member of Qatar Foundation) and  the Ministry of Trade, Industry, and Energy (MOTIE) through the Project “Gas Hydrate Exploration and Production Study (20-1143)” under the management of the Gas Hydrate Research and Development Organization (GHDO) of Korea and the Korea Institute of Geoscience and Mineral Resources (KIGAM).</p>


2014 ◽  
Vol 17 (8) ◽  
pp. 705-713 ◽  
Author(s):  
Hikaru Maeda ◽  
Yoshihiro Hirata ◽  
Soichiro Sameshima ◽  
Taro Shimonosono

2018 ◽  
Vol 11 ◽  
pp. 77-91
Author(s):  
V.T. Gudzenko ◽  
◽  
A.A. Varenichev ◽  
M.P. Gromova ◽  
◽  
...  

2020 ◽  
Author(s):  
Adlai Katzenberg ◽  
Debdyuti Mukherjee ◽  
Peter J. Dudenas ◽  
Yoshiyuki Okamoto ◽  
Ahmet Kusoglu ◽  
...  

<p>Limitations in fuel cell electrode performance have motivated the development of ion-conducting binders (ionomers) with high gas permeability. Such ionomers have been achieved by copolymerization of perfluorinated sulfonic acid (PFSA) monomers with bulky and asymmetric monomers, leading to a glassy ionomer matrix with chemical and mechanical properties that differ substantially from common PFSA ionomers (e.g., Nafion™). In this study, we use perfluorodioxolane-based ionomers to provide fundamental insights into the role of the matrix chemical structure on the dynamics of structural and transport processes in ion-conducting polymers. Through <i>in-situ</i> water uptake measurements, we demonstrate that ionomer water sorption kinetics depend strongly on the properties and mass fraction of the matrix. As the PFSA mass fraction was increased from 0.26 to 0.57, the Fickian swelling rate constant decreased from 0.8 s<sup>-1</sup> to 0.2 s<sup>-1</sup>, while the relaxation rate constant increased from 3.1×10<sup>-3</sup> s<sup>-1</sup> to 4.0×10<sup>-3</sup>. The true swelling rate, in nm s<sup>-1</sup>, was determined by the chemical nature of the matrix; all dioxolane-containing materials exhibited swelling rates ~1.5 - 2 nm s<sup>-1</sup> compared to ~3 nm s<sup>-1</sup> for Nafion. Likewise, Nafion underwent relaxation at twice the rate of the fastest-relaxing dioxolane ionomer. Reduced swelling and relaxation kinetics are due to limited matrix segmental mobility of the dioxolane-containing ionomers. We demonstrate that changes in conductivity are strongly tied to the polymer relaxation, revealing the decoupled roles of initial swelling and relaxation on hydration, nanostructure, and ion transport in perfluorinated ionomers. </p>


Author(s):  
Bruna Drumond ◽  
Bonifácio Oliveira Fialho ◽  
José Adilson Castro ◽  
Adriana Teixeira ◽  
Bárbara Louise Lemos Drumond Silva
Keyword(s):  

Author(s):  
Gustavo Alonso Barrientos Sandoval ◽  
Rafhael Andrade ◽  
Edson Soares ◽  
Roney Thompson ◽  
Flavio Barboza Campos ◽  
...  
Keyword(s):  

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