scholarly journals Simulation of the absorption of gaseous SO2 by fog droplets using a refined interpolation-sectional droplet model

Author(s):  
Vladimir Viktorovich Pekunov

This article examines the problem of numerical simulation of interaction between the gaseous sulfur dioxide emitted by road transport and fog in the conditions of high humidity. For this purpose, the author applies a multi-factor two-phase mathematical model, which takes into account the dynamics of turbulent main phase, dynamics and kinetics of the multi-sectional droplet phase, presence of thermal inconsistencies formed as a result of direct and diffused solar radiation in various ranges, diffusion of sulfur dioxide, and its absorption by the fog droplets. The article carries out a numerical calculation of the corresponding task within the modeling system of environmental processes AirEcology-P, which allows generating the optimal calculation code for a particular mathematical model. The proposed complex mathematical model that descries interaction between the emitted sulfur dioxide gas and the fog droplets is new; it specifies the calculation of the kinetics of droplet phase based on consideration of the additional factor of droplet fusion characteristic to fog. The submodel of the droplet phase was tested in the numerical simulation (the results were compared with the data of direct Lagrangian modeling of the composite of 1,000 droplets), indicating decent accuracy results. The article obtains the results of numerical simulation of interaction between the emitted SO2 and the droplets. The author demonstrates the self-cleaning ability of the atmosphere, the degree of which correlates with the initial concentration of the smallest droplets and the height from the surface.

1994 ◽  
Vol 59 (11) ◽  
pp. 2357-2374 ◽  
Author(s):  
Erich Lippert ◽  
Karel Mocek ◽  
Emerich Erdös

Results are presented of an experimental kinetic study of the heterogeneous reaction between gaseous sulfur dioxide and solid anhydrous potassium carbonate. The measurements were carried out in an all glass kinetic flow apparatus with nitrogen as the carrier gas and a fixed bed of the solid working in the differential regime at atmospheric pressure and a temperature of 423 K (150 °C). The reaction course was studied in dependence on the partial pressures of sulfur dioxide (pSO2) and water vapour (pH2O) in concentration ranges pSO2 = 13 - 430 Pa and pH2O = 0 - 2 100 Pa. In the reaction, water vapour acts as a gaseous catalyst. Based on the experimental data, the corresponding kinetic equation was found together with the numerical values of the relevant rate and equilibrium adsorption constants.


1979 ◽  
Vol 19 (03) ◽  
pp. 175-182 ◽  
Author(s):  
Hossein Kazemi ◽  
L.S. Merrill

Original manuscript received in Society f Petroleum Engineers office Sept. 15, 1977. Paper accepted for publication June 9, 1978. Revised manuscript received Feb. 19, 1979. Paper (SPE 6890) first presented at the SPE-AIME 52nd Annual Fall Technical Conference and Exhibition, held in Denver, Oct. 9-12, 1977. Abstract A two-dimensional, two-phase, semi-implicit, numerical simulator was used to simulate water imbibition and oil recovery in artificially fractured and unfractured cores. Experimental results were matched satisfactorily by the numerical simulator. These results provide evidence of the reliability of the concepts underlying an earlier numerical simulator, which was tailored specifically for field applications. We show that the flow equations used to match the laboratory data reduce to the equations used in the field simulator. In addition, the experiments themselves were conducted quite differently from those commonly used in imbibition experiments and provide added insight into oil recovery from fractured reservoirs. Introduction Previously, we reported on the development of a Previously, we reported on the development of a numerical reservoir simulator for use in field applications. In this paper, we examine the reliability of the concepts underlying the numerical simulation by matching experimental results of fractured and unfractured cores with a simulator that accounts for the fracture and the matrix components. The simulator is a conventional two-dimensional, two-phase, semi-implicit simulator, but we show that it reduces to the formulation used in the field simulator. Several studies have reported on water imbibition in fractured media. These studies were concerned primarily with the imbibition aspects of the flow primarily with the imbibition aspects of the flow mechanism in the matrix rather than the total flow problem in the fracture-matrix system. Mattax and problem in the fracture-matrix system. Mattax and Kyte developed equations for scaling up imbibition effects. Parsons and Chaney used these equations to study imbibition effects in carbonate rocks. Iffly et al., in addition to experimental work, used a one-dimensional, two-phase, semi-implicit mathematical model to match oil recoveries from the matrix. A similar mathematical model in two dimensions was used by Kleppe and Morse to match the results of their imbibition experiments. While the last two papers show that imbibition oil recovery can be simulated numerically, the total concept of fluid flow in fracture-matrix systems has not been investigated adequately either numerically or experimentally. Mathematical Model The porous media used here were cylindrical cores or rectangular blocks cut along the long axis. The flow experiments were conducted so that the fracture plane and the entire core were horizontal. Therefore, the fractured cores were simulated by a layered two-dimensional simulator. The core halves were simulated as two matrix layers having the properties of the original core. The fracture was simulated as a very thin, high-permeability, and high-flow-capacity layer, where capillary pressure was essentially zero. The basic flow equations, assuming imcompressible flow, are w w----- wx ------ + ----- wz --------x x x zax az Sw+ qw Bw (X - Xo) = -------................(1)at t o o------ ox------ + ------ oz -------qoBo (X-Xo)x x z z So= ---------..................................(2)t Sw + So = 1.....................................(3) Pc(Sw) = po - pw....................................(4) kxkrwwx = 0.006328 -----------,......................(5)w SPEJ P. 175


Author(s):  
I. G. Goryacheva

The approaches of contact mechanics are used to evaluate the evolution of the contact characteristics in wear process of inhomogeneous bodies (coated bodies, two-phase composition, bodies with inclusions, etc.). The mathematical model is formulated and used to study the kinetics of the wear process depending on the parameters of inhomogeneity such as size and density of inclusions, waviness at the coating-substrate interface, local hardening parameters, etc.


2014 ◽  
Vol 678 ◽  
pp. 620-623
Author(s):  
Xiao Lei Zhou ◽  
Zhe Shi ◽  
Gui Fang Zhang ◽  
Zhong Ning Du

The research status of numerical simulation on LF furnace refining ladle is introduced in this paper.Since 1970, the research on the gas-liquid two-phase region has begun.Szekely began to be simulated by mathematical model and physical experiment method of flow phenomena in ladle in early 1975. It is the first time that the numerical model is introduced to study the refining process of steel. The plume model is presented by Xiao Zeqiang in 1980, then the numerical simulation began to develop rapidly.


Author(s):  
T. V. Ershova ◽  
D. S. Mikhatulin ◽  
D. L. Reviznikov ◽  
A. V. Sposobin ◽  
V. V. Vinnikov

This paper is concerned with numerical simulation of two-phase flows in complex computational regions. Both nozzle flow and jet-obstacle interaction are considered. The presence of dispersed phase (solid or liquid particles) may lead to specific thermal and erosional interaction of inertial particles with the nozzle walls and the obstacle material. The latter makes the conjugated problem much more complicated. Therefore, we consider the complete flow field in the nozzle-jet-obstacle system. The present work is a continuation of the recent study by the authors [1, 2]. A unified approach to the general problem of a two-phase nozzle-jet-obstacle flow is suggested. In this approach, both the continuous and dispersed phase behavior is calculated using the fixed rectangular grids. The solution of transient conduction equation in the solid is also carried out on rectangular grids. Both dynamics and heating/cooling of particles are calculated using the discrete-element method in Lagrangian variables. The computational model includes many mechanical effects such as collisions of particles with each other, reflection of particles from the wall surface and the feedback effect of the dispersed phase on the gas flow. The distinctive feature is the direct numerical simulation of dispersed phase dynamics, where each single real particle in the flow has its computational counterpart. All governing equations for continuous fields are solved on rectangular grids using a ghost-cell immersed boundary method. This method provides discretization of the appropriate boundary conditions via a procedure of polynomial approximation. Such approach works well for both the incompressible and compressible flows. Rectangular grids allow a straightforward implementation of high order TVD and ENO schemes for the numerical simulation of gas flows. The immersed boundary method is perfectly suited for the problems within a computational domain of varying geometry, since it doesn’t require rebuilding the grid after each boundary movement. This feature was successfully used in the numerical simulation of erosive destruction of the circular cylinder in the two-phase flow [2], where the mass carried away from the body resulted in moving boundaries. The current work incorporates the previous methods and algorithms into the software package allowing the numerical investigation of heterogeneous flows in more complex configurations.


1985 ◽  
Vol 50 (8) ◽  
pp. 1642-1647 ◽  
Author(s):  
Štefan Baláž ◽  
Anton Kuchár ◽  
Ernest Šturdík ◽  
Michal Rosenberg ◽  
Ladislav Štibrányi ◽  
...  

The distribution kinetics of 35 2-furylethylene derivatives in two-phase system 1-octanol-water was investigated. The transport rate parameters in direction water-1-octanol (l1) and backwards (l2) are partition coefficient P = l1/l2 dependent according to equations l1 = logP - log(βP + 1) + const., l2 = -log(βP + 1) + const., const. = -5.600, β = 0.261. Importance of this finding for assesment of distribution of compounds under investigation in biosystems and also the suitability of the presented method for determination of partition coefficients are discussed.


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