Soot Formation from a Bio-derived High Performance Jet Fuel

2022 ◽  
Author(s):  
Ramees Khaleel Rahman ◽  
Farhan Arafin ◽  
Robert Greene ◽  
Erik M. Ninnemann ◽  
Subith Vasu
2021 ◽  
Author(s):  
Nawa Raj Baral ◽  
Minliang Yang ◽  
Benjamin G. Harvey ◽  
Blake A Simmons ◽  
Aindrila Mukhopadhyay ◽  
...  

<div> <div> <div> <p>Near-term decarbonization of aviation requires energy-dense, renewable liquid fuels. Biomass- derived 1,4-dimethylcyclooctane (DMCO), a cyclic alkane with a volumetric net heat of combustion up to 9.2% higher than Jet-A, has the potential to serve as a low-carbon, high- performance jet fuel blendstock that may enable paraffinic bio-jet fuels to operate without aromatic compounds. DMCO can be produced from bio-derived isoprenol (3-methyl-3-buten-1- ol) through a multi-step upgrading process. This study presents detailed process configurations for DMCO production to estimate the minimum selling price and life-cycle greenhouse gas (GHG) footprint considering three different hydrogenation catalysts and two bioconversion pathways. The platinum-based catalyst offers the lowest production cost and GHG footprint of $9.0/L-Jet-Aeq and 61.4 gCO2e/MJ, given the current state of technology. However, when the conversion process is optimized, hydrogenation with a Raney nickel catalyst is preferable, resulting in a $1.5/L-Jet-Aeq cost and 18.3 gCO2e/MJ GHG footprint if biomass sorghum is the feedstock. This price point requires dramatic improvements, including 28 metric-ton/ha sorghum yield and 95-98% of the theoretical maximum conversion of biomass-to-sugars, sugars-to-isoprenol, isoprenol-to-isoprene, and isoprene-to-DMCO. Because increased gravimetric energy density of jet fuels translates to reduced aircraft weight, DMCO also has the potential to improve aircraft efficiency, particularly on long-haul flights. </p> </div> </div> </div>


2019 ◽  
Vol 37 (2) ◽  
pp. 2037-2045 ◽  
Author(s):  
Tongfeng Zhang ◽  
Liyun Zhao ◽  
Mohammad Reza Kholghy ◽  
Sébastien Thion ◽  
Murray J. Thomson

2020 ◽  
Vol 117 (7) ◽  
pp. 3451-3460 ◽  
Author(s):  
Samuel Barak ◽  
Ramees K. Rahman ◽  
Sneha Neupane ◽  
Erik Ninnemann ◽  
Farhan Arafin ◽  
...  

Soot emissions in combustion are unwanted consequences of burning hydrocarbon fuels. The presence of soot during and following combustion processes is an indication of incomplete combustion and has several negative consequences including the emission of harmful particulates and increased operational costs. Efforts have been made to reduce soot production in combustion engines through utilizing oxygenated biofuels in lieu of traditional nonoxygenated feedstocks. The ongoing Co-Optimization of Fuels and Engines (Co-Optima) initiative from the US Department of Energy (DOE) is focused on accelerating the introduction of affordable, scalable, and sustainable biofuels and high-efficiency, low-emission vehicle engines. The Co-Optima program has identified a handful of biofuel compounds from a list of thousands of potential candidates. In this study, a shock tube was used to evaluate the performance of soot reduction of five high-performance biofuels downselected by the Co-Optima program. Current experiments were performed at test conditions between 1,700 and 2,100 K and 4 and 4.7 atm using shock tube and ultrafast, time-resolve laser absorption diagnostic techniques. The combination of shock heating and nonintrusive laser detection provides a state-of-the-art test platform for high-temperature soot formation under engine conditions. Soot reduction was found in ethanol, cyclopentanone, and methyl acetate; conversely, an α-diisobutylene and methyl furan produced more soot compared to the baseline over longer test times. For each biofuel, several reaction pathways that lead towards soot production were identified. The data collected in these experiments are valuable information for the future of renewable biofuel development and their applicability in engines.


1986 ◽  
Vol 108 (4) ◽  
pp. 641-647 ◽  
Author(s):  
H. R. Lander ◽  
H. E. Reif

The most significant potential source of aviation gas turbine fuels in the continental United States is the western oil shale located in the Rocky Mountain States of Colorado, Utah, and Wyoming. Nearly 600 billion barrels of recoverable oil is located in this area. This paper discusses the availability of oil shale and reviews the recovery, upgrading and refining schemes necessary to produce fuel which can be used in present-day aircraft. Other synthetic fuels are discussed with regard to the processing necessary to produce suitable fuels for today’s high-performance aircraft. Heavy oil and tar sand bitumen are likely to be refined in the next decade. Methods for producing suitable fuels are discussed. The chemical structure of these sources, which is basically cyclic, leads to the potential for heavier fuels with more energy per given volume and therefore longer range for certain aircraft. This exciting possibility is reviewed.


Author(s):  
Herbert R. Lander ◽  
Henry E. Reif

The most significant potential source of aviation gas turbine fuels in the continental United States of America is the western oil shale located in the Rocky Mountain States of Colorado, Utah, and Wyoming. Nearly 600 billion barrels of recoverable oil is located in this area. This paper discusses the availability of oil shale and reviews the recovery, upgrading and refining schemes necessary to produce fuel which can be used in present-day aircraft. Other synthetic fuels are discussed with regard to the processing necessary to produce suitable fuels for today’s high performance aircraft. Heavy oil and tar sand bitumen are likely to be refined in the next decade. Methods for producing suitable fuels are discussed. The chemical structure of these sources, which is basically cyclic, leads to the potential of heavier fuels with more energy per given volume and therefore longer range for certain aircraft. This exciting possibility is reviewed.


2021 ◽  
pp. 146808742110436
Author(s):  
Simon Pöllmann ◽  
Martin Härtl ◽  
Georg Wachtmeister

Upcoming emission limits such as Euro VII will make it necessary to further reduce the NOx emission level of internal combustion engines while stricter CO2 limits demand lower fuel consumption. Early closing of the intake valves (Miller timing) leads to reduced combustion temperatures due to lower effective compression ratio, and therefore lower formation and emission of nitrogen oxides. Miller timing is frequently used in gasoline engines, while in Diesel engines it competes with exhaust gas recirculation (EGR). When both measures are applied simultaneously, this may lead to increased emission of soot using standard Diesel fuel, as combustion temperature and oxygen content of the charge become too low. This work shows the investigation of different intake valve timings on an externally supercharged single-cylinder heavy-duty Diesel engine, stationary operated with hydrogenated vegetable oil (HVO), oxymethylene ether (OME), and standard Diesel fuel (DF). The synthetic fuels have a higher cetane number than DF, which supports ignition at lower temperatures. Moreover, OME has a soot-free combustion, which allows an extension of the operating limits without increased emissions. The results show that especially with Miller timing a high-performance turbocharging system is crucial, since higher boost pressure is required to compensate for the filling losses due to the earlier intake closing. The application of a high EGR rate is limited in this case, leading to a trade-off between Miller timing and EGR. All fuels show a reduction in nitrogen oxides of up to 40% with an improved efficiency of more than 3% at a typical road-load point. Measures to reduce ignition delay were found to be necessary, especially for DF. For OME, increased soot formation does not occur when combining Miller timing with low rail pressure, reduced boost pressure or EGR, which promotes simultaneous application of the measures resulting in minimized emissions of nitrogen oxides.


2016 ◽  
Vol 717 ◽  
pp. 9-13
Author(s):  
Jun Mei Cheng ◽  
Shu Gao Zhao

An attempt has been undertaken to assess the effect of RP-3 jet fuel and 4109 lubricant on the mechanical, swelling properties and compression set of two kinds of fluorosilicone rubber (FSR) which are self-made and provided by Dow corning, and are marked as FSR A and FSR B respectively. Results showed that FSR B has better chemical resistance and comparable mechanical properties with that of FSR A, and are promising candidates for the development of high performance sealing materials.


Fuel ◽  
2020 ◽  
Vol 281 ◽  
pp. 118718 ◽  
Author(s):  
Shane Kosir ◽  
Robert Stachler ◽  
Joshua Heyne ◽  
Franchesca Hauck

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