scholarly journals Room Temperature Synthesis of Cu-BTC Coordination Polymer and Metal-Organic Framework by pH Control

2021 ◽  
Author(s):  
Shiraz Ahmed Siddiqui ◽  
Alexander Prado-Roller ◽  
Hidetsugu Shiozawa
Keyword(s):  
Coordination Polymer ◽  
Metal Organic Framework ◽  
Ph Control ◽  
Laser Raman Spectroscopy ◽  
Organic Crystals ◽  
Crystalline Materials ◽  
One Dimensional ◽  
Laser Raman ◽  
Metal Organic ◽  
Organic Framework

<div>Synthesis of crystalline materials is crucial in the field of</div><div>coordination chemistry. In the present work, the reaction</div><div>between the copper and benzene-1,3,5-tricarboxylic acid</div><div>(BTC) ligand is controlled by adjusting the pH of the</div><div>reaction mixture to synthesize two crystalline structures:</div><div>metal-organic framework HKUST-1 and one-dimensional</div><div>coordination polymer Cu(BTC).3H<sub>2</sub>O. Single crystals of both</div><div>structures are studied by multi-laser Raman spectroscopy.</div><div>It is found that both crystals exhibit photoluminescence.</div><div>Also, the transformation of HKUST-1 into Cu(BTC).3H<sub>2</sub>O is</div><div>demonstrated. This work provides impetus for researchers</div><div>to synthesize large metal-organic crystals.</div>

scholarly journals Room Temperature Synthesis of Cu-BTC Coordination Polymer and Metal-Organic Framework by pH Control

2021 ◽  
Author(s):  
Shiraz Ahmed Siddiqui ◽  
Alexander Prado-Roller ◽  
Hidetsugu Shiozawa
Keyword(s):  
Coordination Polymer ◽  
Metal Organic Framework ◽  
Ph Control ◽  
Laser Raman Spectroscopy ◽  
Organic Crystals ◽  
Crystalline Materials ◽  
One Dimensional ◽  
Laser Raman ◽  
Metal Organic ◽  
Organic Framework

<div>Synthesis of crystalline materials is crucial in the field of</div><div>coordination chemistry. In the present work, the reaction</div><div>between the copper and benzene-1,3,5-tricarboxylic acid</div><div>(BTC) ligand is controlled by adjusting the pH of the</div><div>reaction mixture to synthesize two crystalline structures:</div><div>metal-organic framework HKUST-1 and one-dimensional</div><div>coordination polymer Cu(BTC).3H<sub>2</sub>O. Single crystals of both</div><div>structures are studied by multi-laser Raman spectroscopy.</div><div>It is found that both crystals exhibit photoluminescence.</div><div>Also, the transformation of HKUST-1 into Cu(BTC).3H<sub>2</sub>O is</div><div>demonstrated. This work provides impetus for researchers</div><div>to synthesize large metal-organic crystals.</div>

scholarly journals One-dimensional magnetic order in the metal-organic framework Tb(HCOO)3

2016 ◽  
Vol 94 (17) ◽  
Author(s):  
Daniel R. Harcombe ◽  
Philip G. Welch ◽  
Pascal Manuel ◽  
Paul J. Saines ◽  
Andrew L. Goodwin
Keyword(s):  
Magnetic Order ◽  
Metal Organic Framework ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

Polymorphism in a Two-Dimensional Copper(I) Metal-Organic Framework with the ligand bis(4-pyridylthio)methane

CrystEngComm ◽  
2021 ◽  
Author(s):  
Olaya Paz Gomez ◽  
Rosa Carballo ◽  
Ana Belen Lago ◽  
Ezequiel M. Vazquez-Lopez
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Common Phenomenon ◽  
Two Dimensional ◽  
Structure Property ◽  
Crystalline Materials ◽  
Metal Organic ◽  
Organic Framework

Polymorphism is a common phenomenon in crystalline materials but it has barely been studied in the field of metal organic frameworks. The study of polymorphism is useful to investigate structure–property...

Preparation of a one-dimensional nanorod/metal organic framework Janus nanoplatform via side-specific growth for synergistic cancer therapy

2019 ◽  
Vol 7 (4) ◽  
pp. 1696-1704 ◽  
Author(s):  
Haipeng Zhang ◽  
Qin Zhang ◽  
Chunshui Liu ◽  
Bing Han
Keyword(s):  
Cancer Therapy ◽  
Specific Growth ◽  
Metal Organic Framework ◽  
Drug Loading ◽  
Ct Image ◽  
One Dimensional ◽  
Image Guided ◽  
Metal Organic ◽  
Organic Framework

A unique LA-AuNR/ZIF-8 Janus nanoparticle is firstly prepared by side-specific growth of ZIF-8 on one-dimensional AuNR for drug loading to realize the CT image-guided active targeted synergistic chemo-photothermal cancer therapy.

Enhanced proton conduction of imidazole localized in one-dimensional Ni-metal-organic framework nanofibers

2020 ◽  
Vol 31 (12) ◽  
pp. 125702 ◽  
Author(s):  
Zhongxiong Bai ◽  
Shucheng Liu ◽  
Ping Chen ◽  
Guojie Cheng ◽  
Guangyao Wu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A 2-D Metal–Organic Framework Based on Linear Trinuclear Copper Cluster Units: Syntheses, Structures and Magnetic Properties

2018 ◽  
Vol 42 (4) ◽  
pp. 198-201 ◽  
Author(s):  
Liping Wang ◽  
Erpeng Zhang ◽  
Xiaoli Zhou ◽  
Yufei Wang ◽  
Yanli Liu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Copper Cluster ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

The coordination polymer [Cu3(tci)2(phen)2] n (H3tci = 1,3,5-tris(2-carboxyethyl)isocyanurate; phen = 1,10-phenanthroline) has been synthesised. Single-crystal X-ray diffraction studies have shown that the polymer displays a 2-D metal–organic framework based on linear trinuclear copper cluster units, and its magnetic properties indicate antiferromagnetic interactions.

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

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