scholarly journals Electron’s Position Expectation Values and Energy Spectrum of Lithium Ion (Li^(2+)) on Principal Quantum Number n≤3

2022 ◽  
Vol 8 (1) ◽  
pp. 252-256
Author(s):  
Aulia Riski Pratikha ◽  
Bambang Supriadi ◽  
Rif’ati Dina Handayani
Keyword(s):  
Energy Spectrum ◽  
Quantum Number ◽  
Principal Quantum Number ◽  
Theory Development ◽  
Lithium Ion ◽  
Electron Energy Spectrum ◽  
Literature Study ◽  
Expectation Values ◽  
Expectation Value ◽  
Simulation Validation

The purpose of this study is to determine the electron’s position expectation values and energy spectrum on the Li2+ ion on the principal quantum number n≤3. This research using literature study methods on quantum mechanics. The expectation values of the electron position and the energy spectrum of the Li2+ ion uses numerical calculations using the Matlab 2019a program. The steps in this research method include: preparation; theory development; simulation; validation of the results of theory development; results of theory development; discussion and conclusion. The results obtained in this study are the electron’s position expectation values and energy of the Lithium ion. The electron’s position expectation values indicates the presence of electrons that often appear around the x-axis by relying on the interval used. The larger the interval, the more constant the electron’s position expectation values will be and towards an almost constant value. From the analysis results, the expectation value varies in positions from  0,0001a0 to 0,1637a0. The electron energy spectrum of the Li2+ ion is inversely proportional to the square of the principal quantum number (n),E1= -122,4 eV ; E2= -30,6 eV ; E3= -13,6 eV

Thermodynamic activity and electron energy spectrum of metallic solutions

2014 ◽  
Vol 44 (2) ◽  
pp. 90-95
Author(s):  
I. F. Selyanin ◽  
V. B. Deev ◽  
A. I. Kutsenko ◽  
A. A. Kutsenko ◽  
O. G. Prikhod’ko
Keyword(s):  
Energy Spectrum ◽  
Electron Energy ◽  
Thermodynamic Activity ◽  
Electron Energy Spectrum

Zur Kenntnis der Dihalogen-tris-(4-dimethylamino-phenyl)-Verbindungen von Phosphor, Arsen, Antimon und Wismut / Dihalogeno-tris- (4-dimethylamino-phenyl) -Compounds of Phosphorus, Arsenic, Antimony, and Bismuth

1972 ◽  
Vol 27 (6) ◽  
pp. 591-595 ◽  
Author(s):  
Jörn-Michael Keck ◽  
Günter Klar
Keyword(s):  
Chemical Shift ◽  
Quantum Number ◽  
Principal Quantum Number ◽  
Valence Electrons ◽  
Phenyl Compounds ◽  
Atomic Parameters

The synthesis of the dihalogeno-tris-(4-dimethylamino-phenyl)-compounds Ar2EX2 (E = P, As, Sb; X = Cl, Br, J and E = Sb, X = F; E = Bi, X = Cl) is described. A generally valid correlation between the chemical shift of the n.m.r. signal of an atom and the atomic parameters electronegativity and principal quantum number of valence electrons is deduced.

scholarly journals CONTRADICTION TO THE TABLE OF D. I. MENDELEEV AND THEIR ELIMINATION

2021 ◽  
Vol 2 (446) ◽  
pp. 14-21
Author(s):  
N.К. Akhmetov ◽  
G.U. Ilyasova ◽  
S. K. Kazybekova
Keyword(s):  
Quantum Number ◽  
Periodic Table ◽  
Chemical Elements ◽  
Principal Quantum Number ◽  
Quantum States ◽  
Outer Electron ◽  
New Approach ◽  
Electronic Configurations ◽  
New Formula ◽  
Electron Shells

The article discusses a new approach to the formation of periods of the Periodic Table of Mendeleev. With the help of the new formula and the first proposed quantum states of the outer electron shells of atoms of chemical elements, the periods of the periodic table are reformatted. It is supposed to reduce the number of periods in the table by introducing the corresponding sub-periods. This is confirmed by the material given in the article. The following description of the order of formation of electron layers is proposed: the principal quantum number (n), then the newly proposed quantum states of electrons («first» and «second»), which in turn constitute the electronic configurations of sub-periods in periods, and only then the remaining quantum orbitals (s, p, d and f).

scholarly journals Evaluation of the one electron expectation values for different wave function of Be atom

2007 ◽  
Vol 4 (3) ◽  
pp. 393-396
Author(s):  
Baghdad Science Journal
Keyword(s):  
Wave Function ◽  
Slater Determinant ◽  
Open Shell ◽  
Expectation Values ◽  
Electronic Density ◽  
Expectation Value ◽  
Hartree Fock ◽  
Shell System ◽  
Electronic Wave Function ◽  
The One

The aim of this work is to evaluate the one- electron expectation value from the radial electronic density function D(r1) for different wave function for the 2S state of Be atom . The wave function used were published in 1960,1974and 1993, respectavily. Using Hartree-Fock wave function as a Slater determinant has used the partitioning technique for the analysis open shell system of Be (1s22s2) state, the analyze Be atom for six-pairs electronic wave function , tow of these are for intra-shells (K,L) and the rest for inter-shells(KL) . The results are obtained numerically by using computer programs (Mathcad).

Electron energy spectrum in 2D-quasicrystals

1988 ◽  
Vol 130 (6-7) ◽  
pp. 381-384 ◽  
Author(s):  
A.V. Kuzmenko ◽  
I.R. Sagdeev ◽  
D.A. Usikov ◽  
G.M. Zaslavsky
Keyword(s):  
Energy Spectrum ◽  
Electron Energy ◽  
Electron Energy Spectrum

The Lithium Group

2010 ◽  
Author(s):  
George K. Schweitzer ◽  
Lester L. Pesterfield
Keyword(s):  
Charge Density ◽  
Quantum Number ◽  
Oxidation State ◽  
Periodic Table ◽  
Alkali Metals ◽  
Principal Quantum Number ◽  
Horizontal Line ◽  
Outer Electron ◽  
Aqueous Chemistry ◽  
Figure Legend

The elements which constitute Group 1 of the Periodic Table are known as the alkali metals. They are lithium Li, sodium Na, potassium K, rubidium Rb, cesium Cs, and francium Fr. (Sometimes the NH4+ ion is included among these since it resembles K+ or Rb+ in many of its reactions.) All six of the elements have atoms characterized by an outer electron structure of ns1 with n representing the principal quantum number. The elements exhibit marked resemblances to each other with Li deviating the most. This deviation is assignable to the small size of Li which causes the positive charge of Li+ to be concentrated, that is, the charge density is high. All of the elements exhibit oxidation numbers of 0 and I, with exceptions being rare, such that their chemistries are dominated by the oxidation state I. The six metals are exceptionally reactive, being strong reductants, reacting with HOH at all pH values to give H2 and M+, and having hydroxides MOH which are strong and soluble. Ionic sizes in pm for the members of the group are as follows: Li (76), Na (102), K (139), Rb (152), Cs (167), and Fr (180). The E° values for the M+/M couples are as follows: Li (−3.04 v), Na (−2.71 v), K (−2.93 v), Rb (−2.92 v), Cs (−2.92 v), and Fr (about −3.03 v). a. E–pH diagram. The E–pH diagram for 10−1.0 M Li is presented in Figure 5.1. The figure legend provides an equation for the line that separates Li+ and Li. The horizontal line appears at an E value of −3.10 v. Considerably above the Li+/Li line, the HOH ≡ H+/H2 line appears, which indicates that Li metal is unstable in HOH, reacting with it to produce H2 and Li+. Note further that Li+ dominates the diagram reflecting that the aqueous chemistry of Li is largely that of the ion Li+.

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