PEMANFAATAN TONGKOL JAGUNG SEBAGAI ADSORBEN LIMBAH LOGAM BERAT

2021 ◽  
Vol 6 (2) ◽  
pp. 89
Author(s):  
Nur Rokhati ◽  
Aji Prasetyaningrum ◽  
Nur ‘Aini Hamada ◽  
Adi Lamda Cahyo Utomo ◽  
Hery Budiarto Kurniawan ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Ion ◽  
Adsorption Process ◽  
Heavy Metal Concentration ◽  
Absorption Efficiency ◽  
Cellulose Content ◽  
Corn Cob ◽  
Adsorption Time ◽  
Metal Absorption ◽  
High Cellulose

Logam berat adalah istilah untuk logam-logam seperti Cd, Cr, Cu, Hg, Ni, Pb, dan Zn yang sering berhubungan dengan polusi dan toksisitas. Adsorpsi merupakan metode yang paling sering digunakan untuk menghilangkan ion logam. Tongkol jagung berpotensi menjadi adsorben karena kadar selulosanya yang tinggi. Penelitian ini bertujuan untuk mengkaji performa tongkol jagung sebagai adsorben ion Cr(VI) dan Cd(II). Penelitian dimulai dengan perlakuan awal adsorben dan dilanjutkan dengan proses adsorbsi. Kadar logam berat dihitung dengan metode spektrofotometri. Nilai efisiensi penyerapan Cd(II) meningkat dengan adanya perlakuan awal menggunakan suhu tinggi. Jumlah logam yang terserap semakin banyak seiring dengan lamanya waktu adsorpsi dengan efisiensi penyerapan sebesar 94,76% untuk Cr(VI) dan 83,96% untuk Cd(II). Penambahan jumlah adsorben tongkol jagung juga meningkatkan efisiensi penyerapan logam kromium hingga 82,33% dan kadmium sebesar 83,98%. Sedangkan jumlah ion Cr(VI) yang terserap tidak linear dengan penambahan kecepatan pengadukan. Berdasarkan hasil penelitian, dapat disimpulkan bahwa tongkol jagung berpotensi digunakan sebagai adsorben ion logam berat dengan efisiensi di atas 80%.  Kata kunci: adsorpsi, kadmium, kromium, tongkol jagung AbstractHeavy metal is a term for metals such as Cd, Cr, Cu, Hg, Ni, Pb, and Zn, often associated with pollution and toxicity. Adsorption is the most commonly used method to remove metal ions. Corncob have the potential to be an adsorbent because of their high cellulose content. This study aimed to examine the performance of corncob as an adsorbent of Cr(VI) and Cd(II) ions. The study began with the pretreatment of the adsorbent and continued with the adsorption process. Heavy metal concentration was calculated by the spectrophotometric method. The value of the absorption efficiency of Cd(II) increased with the pretreatment using high temperature. The amount of metal adsorbed increased with the length of adsorption time with the absorption efficiency of 94.76% for Cr(VI) and 83.96% for Cd(II). The addition of corncob adsorbent also increased the efficiency of chromium metal absorption up to 82.33% and cadmium by 83.98%. Meanwhile, the amount of Cr(VI) ion adsorbed was not linear with increasing stirring speed. Based on the results, it can be concluded that corncob could be used as heavy metal ion adsorbents with an efficiency above 80%. Keywords: adsorption, cadmium, chromium, corn cob

scholarly journals Study on Adsorption Properties of Modified Corn Cob Activated Carbon for Mercury Ion

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4483
Author(s):  
Yuyingnan Liu ◽  
Xinrui Xu ◽  
Bin Qu ◽  
Xiaofeng Liu ◽  
Weiming Yi ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Photoelectron Spectroscopy ◽  
Adsorption Process ◽  
Physical Adsorption ◽  
Raw Material ◽  
Order Kinetic ◽  
Mercury Ions ◽  
Corn Cob ◽  
Adsorption Time ◽  
X Ray

In this study, corn cob was used as raw material and modified methods employing KOH and KMnO4 were used to prepare activated carbon with high adsorption capacity for mercury ions. Experiments on the effects of different influencing factors on the adsorption of mercury ions were undertaken. The results showed that when modified with KOH, the optimal adsorption time was 120 min, the optimum pH was 4; when modified with KMnO4, the optimal adsorption time was 60 min, the optimal pH was 3, and the optimal amount of adsorbent and the initial concentration were both 0.40 g/L and 100 mg/L under both modified conditions. The adsorption process conforms to the pseudo-second-order kinetic model and Langmuir model. Scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and Zeta potential characterization results showed that the adsorption process is mainly physical adsorption, surface complexation and ion exchange.

Utilization of Powdered Cassava Stem as an Alternative Bioadsorbent for Lead (Pb2+) Removal from Aqueous Solution

2021 ◽  
Vol 1033 ◽  
pp. 82-86
Author(s):  
Tintin Mutiara ◽  
Andira Budi Trimartina ◽  
Rafika Erniza Putri ◽  
Achmad Chafidz
Keyword(s):  
Heavy Metals ◽  
Industrial Waste ◽  
Contact Time ◽  
Metal Ion ◽  
Adsorption Process ◽  
Cellulose Content ◽  
Optimum Conditions ◽  
Adsorption Method ◽  
Cassava Stem ◽  
Mesh Sieve

Industrial waste containing heavy metals can pollute the aquatic environment. One method that can be done to manage heavy waste is the adsorption method that uses adsorbent from cassava stem powder. This research was conducted to utilize cassava stem powder waste for the adsorption of Pb2 + metal ions. Cassava stem powder was mashed until it passed 100 mesh sieve. Cassava stems have a cellulose content of 70-80%, lignin 15-20%, ADF 15-20% and cellulose can be used as an absorber of heavy metals. The adsorption process is carried out with variations in pH, time and concentration under optimum conditions. In this adsorption involves the functional groups contained therein so that the interaction between the adsorbent with the metal ion Pb2 +. Based on the research, the optimum conditions were obtained at pH 6, 180 minutes contact time and 50 ppm concentration. This test is carried out using Atomic Absorption Spectroscopy (AAS).

Migration Patterns of Heavy Metals in Soil in Wastewater Irrigation Area in the Suburb of Eastern Inner Mongolia

2011 ◽  
Vol 343-344 ◽  
pp. 340-343
Author(s):  
Ri Cha Hu ◽  
Li Bo Sun
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Inner Mongolia ◽  
Metal Ion ◽  
Vertical Direction ◽  
Heavy Metal Concentration ◽  
Water Shortage ◽  
Wastewater Irrigation ◽  
Irrigation Area ◽  
Eastern Inner Mongolia

Based on the soil test of heavy metals in wastewater irrigation area in eastern Inner Mongolia, this paper analyses the content of heavy metals Cr, Cu, Cd, Pb in different layers of soil samples and reveals the internal relations between heavy metal concentration gradient in the vertical direction and soil properties, thus providing a scientific basis to guide sewage irrigation, solve the problem of water shortage in wastewater irrigation area and carry out environmental impact assessment. Soil is an important subsystem in natural environmental systems, through which many pollutants, especially heavy metals, produced by human activities, enter the food chain and ultimately do harm to human health. Currently, heavy metal ion contamination to the soil caused by wastewater irrigation has become one of the focuses in the study of soil chemistry and agricultural environment pollution. For this reason, it is particularly important to study the migration mechanism of heavy metals in soil and to provide a reliable theoretical basis for the prevention and management of soil contaminants.

Using modified macadamia carbon by H2O2 as adsorbent to remove zinc (Zn2+) in wastewater

2020 ◽  
pp. 195-201
Keyword(s):  
Heavy Metal ◽  
Metal Concentration ◽  
Removal Efficiency ◽  
Processing Time ◽  
Heavy Metal Concentration ◽  
Adsorption Time ◽  
Processing Ability ◽  
Maximum Removal

Using modified macadamia carbon by H2O2 as adsorbent to remove Zn2+ with H2O2 25% in 48 hours. The Parameters, such as pH, dosage and adsorption time affect the processing ability of modified macadamia carbon H2O2. The maximum removal efficiency of 64.52% was obtained at a pH of 4.5, the processing time is 80 minutes, dosage 1.8 g/L and an initial heavy metal concentration of 25ppm.

The Influence of Co-Existing Ions on Adsorbs in the Aqueous Phase Pb2+ by Mycobacterium phlei

2011 ◽  
Vol 183-185 ◽  
pp. 654-657
Author(s):  
Dong Qin Zhou ◽  
Shu Juan Dai ◽  
De Zhou Wei ◽  
Shu Yong Yang
Keyword(s):  
Heavy Metal ◽  
Metal Ion ◽  
Adsorption Process ◽  
Ph Value ◽  
Water Solution ◽  
Alkaline Metal ◽  
Adsorption System ◽  
Mycobacterium Phlei ◽  
Biological Surface ◽  
Positive Ion

The biological adsorption law removes the heavy metal ion, many factor influences, among, in the solution the inherent alkaline metal positive ion existence is affects the microorganism adsorption the important attribute. This article take Mycobacterium phlei as the absorbent, inspected the different pH value, the coexistence ion amount used as well as in tri-, four-, five-, six-coexistent ion systems, to absorbed water solution in Pb2+ ion influence. Through around the determination Mycobacterium phlei Contact angle and the adsorption the biological surface zeta - the potential shift, indicated the Mycobacterium phlei to the Pb2+ adsorption process in, the electrostatic attraction occupies the leadership, but in the multi-dimensional coexistence adsorption system, has the competition adsorption and the ionic.

Biosorption of chromium(VI), nickel(II) and Remazol Blue by Rhodotorula muciloginosa biomass

2012 ◽  
Vol 65 (3) ◽  
pp. 471-477 ◽  
Author(s):  
Nalan Oya San ◽  
Gönül Dönmez
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Aqueous Solutions ◽  
Metal Concentration ◽  
Metal Ion ◽  
Heavy Metal Concentration ◽  
Reactive Dye ◽  
Ion Concentration ◽  
Chromium Vi

The passive removal of commonly used reactive dye and two heavy metals, from aqueous solutions by inexpensive biomaterial, yeast Rhodotorula muciloginosa biomass, termed biosorption, was studied with respect to pH, initial dye concentration and initial metal ion concentration. The biomass exhibited maximum dye and chromium(VI) uptake at pH 5 and pH 6 for nickel(II) in media containing 50 mg/L heavy metal and 50 mg/L remazol blue. It was found that the highest chromium(VI) removal yields measured were 31.3% for 49.0 mg/l initial chromium(VI) concentrations. The nickel(II) removal yield was 32.5% for 22.3 mg/L. Higher R. Blue removal yields were obtained, such as 77.1% for 117.5 mg/L. The maximum dye biosorption yield was investigated in medium with a constant dye (∼50 mg/L) and increasing heavy metal concentration. In the medium with 48.8, 103.8 and 151.8 mg/L chromium(VI) and constant dye concentration, the maximum chromium(VI) biosorption was 7.4, 9.3 and 17.1%, whereas the maximum dye biosorption was 61.6, 56.6 and 55.9%. The maximum nickel(II) biosorptions in the medium with dye were 38.1, 22.1 and 8.8% at 23.7, 37.7 and 60.1 mg/L nickel(II) concentrations. In these media, dye biosorptions were 93.9, 86.4 and 93.3%, respectively.

scholarly journals Surface modified polythiophene/Al2O3 and polyaniline/Al2O3 nanocomposites using poly(vinyl alcohol) for the removal of heavy metal ions from water: kinetics, thermodynamic and isotherm studies

2021 ◽  
Author(s):  
Zeynab Karimi ◽  
Reza Khalili ◽  
Mohammad Ali Zazouli
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Vinyl Alcohol ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
Adsorption Process ◽  
Oxidative Polymerization ◽  
Ion Concentration ◽  
Poly Vinyl Alcohol ◽  
Order Kinetic

Abstract In this study, polythiophene/Al2O3 (PTh/Al2O3) and polyaniline/Al2O3 (PAn/Al2O3) nanocomposites in the presence of poly(vinyl alcohol) (PVA) as the surfactant were synthesized via in situ chemical oxidative polymerization method in aqueous medium. The synthesized nanocomposites were characterized by Scanning electron microscopy (SEM), Fourier transform-infrared (FTIR) spectroscopy and X-ray diffraction (XRD). Results indicated that the Al2O3 and poly(vinyl alcohol) influenced the properties of synthesized nanocomposites. The aim of this research was to investigate the sorption characteristic of polythiophene and polyaniline nanocomposites for the removal of heavy metal cations including Pb(II), Zn(II) and Cd(II) from aqueous solution. The factors that affected the adsorption equilibrium as well as the removal efficiency of the nanoadsorbents, i.e., contact time, metal ion concentration, pH and adsorption conditions were investigated in detail. From the kinetic results, it was concluded that the pseudo-second-order kinetic model was found to the best at describing the adsorption process for Pb(II), Zn(II) and Cd(II) on PTh-PVA/Al2O3 and PAn-PVA/Al2O3. In addition, thermodynamic analysis suggests the endothermic and spontaneous nature of the present adsorption process with increased entropy on PTh-PVA/Al2O3 and PAn-PVA/Al2O3. The results suggest polythiophene, polyaniline and their nanocomposites have great potential to be used as efficient absorbent for the removal of heavy metal ions from water.

scholarly journals Using Modified Fly Ash for Removal of Heavy Metal Ions from Aqueous Solution

2020 ◽  
Vol 2020 ◽  
pp. 1-11 ◽  
Author(s):  
Thuy Chinh Nguyen ◽  
Trang Do Mai Tran ◽  
Van Bay Dao ◽  
Quoc-Trung Vu ◽  
Trinh Duy Nguyen ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Fly Ash ◽  
Adsorption Isotherm ◽  
Metal Ion ◽  
Adsorption Process ◽  
Sodium Dodecyl ◽  
Isotherm Model ◽  
Isotherm Models ◽  
Adsorption Isotherm Models ◽  
Modified Fly Ash

This paper presents the characteristics of fly ash which was modified by 2-mercaptobenzothiazole (MBT) and sodium dodecyl sulfate (SDS) as the surfactants after treating with 1M NaOH solution. The change in morphology, specific surface area, crystal structure, and composition of the unmodified and modified fly ash was evaluated by FTIR, XRD, FESEM, BET, and EDX methods and techniques. The FTIR spectra of modified fly ash showed that there was no chemical reaction between the surfactants and fly ash. The XRD patterns and FESEM images indicated that modified fly ash had zeolite structure with a pore size of about 50 nm. Heavy metal ion adsorption behavior as well as adsorption isotherm models (Langmuir and Freundlich) of Cd2+ and Hg2+ ions of the unmodified and modified fly ash were also investigated and discussed. The amount of adsorbed ions of the modified fly ash was higher than that of the unmodified fly ash. The calculated results from the adsorption data according to the adsorption isotherm models of the above ions displayed that the Langmuir isotherm model was complied for the Cd2+ adsorption process while the Freundlich isotherm model was fitted for the Hg2+ adsorption process.

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