scholarly journals RESEARCH TEMPERATURES OF IGNITION AND SELF-IGNITION OF COTTON AND POLYESTER FABRICS

Fire Safety ◽  
2021 ◽  
Vol 38 ◽  
pp. 32-37
Author(s):  
V. Tovarianskyi ◽  
I. Adolf ◽  
V. Petrovskyi

Formulation of the problem. Most of the fabrics used in the technological processes of garment enterprises are classified as combustible materials and are part of the fire load, which threatens the outbreak and rapid spread of fires in the premises of garment factories. Therefore, it is important to study the indicators of the fire hazard of fabrics to identify the most dangerous of them, as well as to increase the efficiency of fire safety at sewing enterprises.The purpose of the work is to obtain the dependences of the values of ignition and self-ignition temperatures of cotton fabrics on the composition of cotton.Results. It was found that the crushed 100% cotton fabric flamed best, and the worst − solid polyester as a fabric without cotton. The lowest value of the temperature at which ignition was observed was 215°C for cotton (100%, shredded fabric), and if this value is reduced - there were failures, which are caused in particular by the fact that at lower temperatures flammable vapours are no formed in concentrations sufficient for combustion. It was found that the ignition / spontaneous combustion temperatures for a solid sample of the fabric with a composition of 100% cotton are 235°C/420°C, and for a solid sample of the fabric with a composition of 100% polyester − 360°C/500°C, respectively. Ignition / spontaneous com-bustion temperatures for finely divided fabrics are 8,5%/4,78% (cotton fabric) and 2.8%/6% (polyester) lower than the values obtained for whole fabrics.Results. According to the results of the analysis of the most common fabrics (table 1) used in garment enterprises. Identified that the biggest fire hazard is inherent containing cotton. The lowest ignition temperature is observed for cotton (100% shredded fabric) and is 215°C, which is 1,63 times less than the ignition temperature of polyester (0% cotton, shredded fabric). The lowest self-ignition temperature is also observed for cotton (100% shredded fabric) and is 400°C, which is 1,18 less than the self-ignition temperature of polyester (0% cotton, shredded fabric).

2022 ◽  
Vol 354 ◽  
pp. 00012
Author(s):  
Maria Prodan ◽  
Andrei Szollosi-Moța ◽  
Vasilica Irina Nălboc ◽  
Niculina Sonia Șuvar ◽  
Adrian Jurca

Spontaneous combustion is a phenomenon that results from the heating of combustible organic powders by slow oxidation and which occurs through the air passage (created by an air depression) through the mass of dust. The oxidation phenomenon of combustible powders represents their reaction with atmospheric oxygen resulting in products of carbon dioxide, carbon oxide, water and other gases whose content depends on the temperature at which the oxidation takes place. The self-ignition of combustible dusts depends on their chemical composition, the properties of component substances, on the particle size and geometry of the material mass and, last but not least, on the temperature of the environment. Due to global worries of sustainability in construction engineering the trend is to use ecofriendly organic waste to various purposes as in construction materials. The challenge is that by using this kind of materials one should ensure the safety related to the process of such organic materials which are known to have combustible properties. The purpose of this work is to present the self-ignition behavior of combustible dusts such as sunflower and wood by means of drying tests under constant temperature conditions.


2015 ◽  
Vol 60 (3) ◽  
pp. 761-776 ◽  
Author(s):  
Janusz Cygankiewicz

Abstract Decades of experience in the fight against endogenous fire hazard in coal mines indicate a major influence of certain conditions in a given area of the mine on the possibility of fire occurrence, such as: susceptibility of coals to spontaneous combustion, oxygen content in the air incoming to the self-heating coal, conditions of heat exchange between the self-heating coal mass and the environment This paper presents a numerical method for determining the critical conditions of spontaneous combustion of coal in longwall gob areas, i.e. conditions under which spontaneous combustion may occur. It has been assumed that crushed coal in the gob has a shape of a flat layer adjacent from the roof and floor side to the rocks. Our considerations have been limited to coals containing small amount of moisture. A simple model of oxidation kinetics on the coal surface expressed by the Arrhenius equation has been adopted. This model assumes that oxidation rate is independent of the amount of oxygen absorbed by coal. The rate of reaction depends only on temperature, with the parameters of the equation changing after the coal has reached the critical temperature. The article presents also a mathematical model of spontaneous heating of the coal layer in the gob area. It describes the heat balance in the coal as well as the oxygen and heat balance in the flowing gases. The model consists of a system of differential equations which are solved using numerical techniques. The developed computer program enables to perform the relevant calculations. In this paper, on the example of coal from a seam 405, we present the method for determining the following critical parameters of the layer of crushed coal: thickness of the layer, oxygen content in a stream of gases flowing through the layer and thermal conductivity of surrounding rocks.


2021 ◽  
Vol 16 ◽  
pp. 155892502110034
Author(s):  
Xiongfang Luo ◽  
Pei Cheng ◽  
Wencong Wang ◽  
Jiajia Fu ◽  
Weidong Gao

This study establishes an eco-friendly anti-wrinkle treating process for cotton fabric. Sodium hydroxide-liquid ammonia pretreatment followed by 6% (w/w) PU100 adding citric acid pad-cure-dry finishing. In this process, citric acid (CA) was used as the fundamental crosslinking agent during finishing because it is a non-formaldehyde based, cost-effective and well wrinkle resistance agent. Environmental-friendly waterborne polyurethane (WPU) was used as an additive to add to the CA finishing solution. Six commercial WPUs were systematically investigated. Fabric properties like wrinkle resistance, tensile strength retention, whiteness, durable press, softness, and wettability were well investigated. Fourier transform infrared spectra and X-ray diffraction spectra were also measured and discussed before and after adding waterborne polyurethane. Tentative mechanism of the interaction among the WPU, CA, and modified cotton fabrics is provided. The effect of cotton fabric pretreatment on fabric performance was also investigated. After the eco-process’s treatment, the fabric wrinkle resistant angle was upgraded to 271 ± 7°, tensile strength retention was maintained at 66.77% ± 3.50% and CIE whiteness was elevated to 52.13 ± 3.21, which are much better than the traditional CA anti-wrinkle finishing based on mercerized cotton fabrics. This study provides useful information for textile researchers and engineers.


2020 ◽  
Vol 1006 ◽  
pp. 93-100
Author(s):  
Vadym Nizhnyk ◽  
Yurii Feshchuk ◽  
Volodymyr Borovykov

Based on analysis of appropriate literary sources we established that estimation of fire separation distances was based of two criteria: heat flux and temperature. We proposed to use “ignition temperature of materials” as principal criterion when determining fire separation distances between adjacent construction facilities. Based on the results derived while performing complete factorial we created mathematical model to describe trend of changing fire separation distances depending on caloric power of fire load (Q), openings factor of the external enclosing structures (k) and duration of irradiation (t); moreover, its adequacy was confirmed. Based on linear regression equations we substantiated calculation and tabular method for the determination of fire separation distances for a facility being irradiated which contains combustible or otherwise non-combustible façade and a facility where liquid oil products turn. We developed and proposed general methodology for estimation of fire separation distances between construction facilities by calculation.


2011 ◽  
Vol 332-334 ◽  
pp. 77-80 ◽  
Author(s):  
Chuan Jie Zhang ◽  
Hong Yang ◽  
Yun Liu ◽  
Ping Zhu

Cotton fabric with excellent antibacterial properties was obtained by treated with polyamide-amine (PAMAM) dendrimers as a carrier and silver nitrate as an antibacterial agent. The antibacterial cotton fabrics were prepared by the methods of one-bath process and two-bath process. Antibacterial activity of cotton fabrics treated by two different methods was good, but the antibacterial durability of cotton fabric treated with two-bath process was better than that treated with one-bath process. After 50 washing cycles, cotton fabric treated with two-bath process still had good antibacterial property and its inhibitory rate to Gram-positive S. aureus and Gram-negative E. coli was over 99 %. It was found that the breaking strength retention of finished cotton fabrics was 85.83 % and the decrease of cotton fabrics’ whiteness index was about 15 %.


2011 ◽  
Vol 331 ◽  
pp. 261-264 ◽  
Author(s):  
Qi Ming Zhao ◽  
Shan Yan Zhang

The auxiliary devices of ultrasonic treatment was designed and manufactured. The cotton fabric was desized using 2000L desizing enzyme with the conventional enzyme desizing process and ultrasonic enzyme desizing process respectively. Through the orthogonal experiment, the optimum process conditions of conventional enzyme desizing process and ultrasonic enzyme desizing process were determined. For the conventional enzyme desizing process, the optimized desizing conditions of cotton fabrics were: desizing enzyme dosage was 1.5g/l, temperature was 80°C, PH value was 6, and time was 60mins. The optimum process conditions of ultrasonic enzyme desizing process were: desizing enzyme dosage was 1.5g/l, temperature was 50°C, PH value was 6 and time was 45minutes. The research result indicates that, under the same desizing condition, ultrasonication can improve the desizing percentage and whiteness of cotton fabric, but the fabric strength loss increases slightly. And for the same required desizing percentage, the ultrasonic enzyme desizing process saved time and reduced the temperature of experiments compared with traditional enzyme desizing process


2016 ◽  
Vol 87 (13) ◽  
pp. 1620-1630 ◽  
Author(s):  
Yangyi Chen ◽  
Jie An ◽  
Qi Zhong ◽  
Peter Müller-Buschbaum ◽  
Jiping Wang

The smart control of cotton fabric comfort by cross-linking thermo-responsive random copolymer is investigated. The monomers 2-(2-methoxyethoxy) ethoxyethyl methacrylate (MEO2MA) and ethylene glycol methacrylate (EGMA) with a molar ratio of 17:3 are selected to synthesize the thermo-responsive random copolymer poly(2-(2-methoxyethoxy) ethoxyethyl methacrylate- co-ethylene glycol methacrylate), abbreviated as P(MEO2MA- co-EGMA). By using citric acid as a cross-linking agent, the obtained P(MEO2MA- co-EGMA) is successfully immobilized onto cotton fabrics. Smart control is achieved from the thermo-responsive behavior of the copolymer. Cross-linked P(MEO2MA- co-EGMA) will collapse when the ambient temperature exceeds its transition temperature. Therefore, the formerly compact P(MEO2MA- co-EGMA) layer will switch to a porous structure, and the air/moisture permeability of the textiles is enhanced. As the comfort of the textiles is closely related to the air/moisture permeability, a smart control of the cotton fabric comfort can be realized. In addition, the softness of cotton fabrics with and without thermo-responsive polymers does not show a prominent change, even when the applied solution concentration is as high as 16% (wt%). On the contrary, the stiffness of the cotton fabric coated with poly( N-isopropylacrylamide) (PNIPAM) is significantly higher than the original cotton fabric, indicating that homo PNIPAM is less suitable for textiles used in daily lives. Moreover, the whiteness and mechanical properties are studied and stay unchanged after cross-linking. As a consequence, the introduction of P(MEO2MA- co-EGMA) into textiles can provide textiles with smart control of cotton comfort, and it will not influence the wearabilities of the textiles.


2017 ◽  
Vol 48 (1) ◽  
pp. 87-118 ◽  
Author(s):  
MD Teli ◽  
Pintu Pandit

As far as the value addition of textile is concerned, flame retardancy of textile materials is considered to be one of the most important properties in textile finishing by both industries as well as academic researchers. Flame-retardant property with thermal stability was imparted to cotton by using green coconut ( Cocos nucifera Linn) shell extract, a natural waste source of coconut. Coconut shell extract was analyzed by high-performance liquid chromatography, Fourier transform infrared spectroscopy, energy-dispersive spectrometry and its phytochemical analysis was also carried out. The coconut shell extract (acidic after extraction) was applied in three different pH (acidic, neutral, and alkaline) conditions to the cotton fabric. Flame-retardant properties of the untreated and the treated cotton fabrics were analyzed by limiting oxygen index and vertical flammability. The study showed that all the treated fabrics had good flame resistance property compared to that of the untreated fabric. The limiting oxygen index value was found to increase by 72.2% after application of the coconut shell extract from alkaline pH. Pyrolysis and char formation behavior of the concerned fabrics were studied using thermogravimetric analysis and differential scanning calorimetric analysis in a nitrogen atmosphere. The physicochemical composition of the untreated and coconut shell extract treated cotton fabrics were analyzed by attenuated total reflection–Fourier transform infrared, scanning electron microscope, and energy-dispersive X-ray spectroscopy. Also, treated cotton fabric showed natural brown color and antibacterial property against both Gram-positive and Gram-negative bacteria. The durability of the flame-retardant functionality to washing with soap solution has also been studied and reported in this paper.


2012 ◽  
Vol 441 ◽  
pp. 57-60
Author(s):  
Xia Zhu ◽  
Qing Tao Meng

t is pre-mordant dyeing. Dyeing property of Carmine, gardenia yellow and sodium copper chlorophyll on cotton fabrics which were pre-treated by metal mordant (FeSO4AlCl3 and ZnCl2 ) was studied. The reasonable pre-treatment was determined by comparing the color depth (K/S value) of dyed samples. And then, the dyed samples were treated with no-iron finishing resin 931-33 to fix the color. The result shows that the color depth of cotton fabric is greatly improved after determined pre-treatment, and the washing fastness is improved after color fixing.


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