scholarly journals Experimental Study on Stratification Morphology of the Molten Pool During Severe Accident

2021 ◽  
Vol 9 ◽  
Author(s):  
Yang Li ◽  
Houjun Gong ◽  
Yunwen Hu ◽  
Shengxing Yang ◽  
Yong Li ◽  
...  

Stratification morphology of a molten pool under severe reactor accident was investigated by the CESEF experimental facility. The experimental scale was 5,000 g, the atomic ratio of U/Zr was 1.5, the content of stainless steel was 10%, and the oxidation degree of Zr was 40–100%. It was shown that the molten pool was obviously stratified within the range of experimental parameters; one was a metal layer, and the other was an oxide layer. The layered morphology of the molten pool was different with the composition of different corium. With the decrease in the Zr oxidation degree, the metal layer moved downward in the molten pool, and the molten pool would overturn. The main elements in the oxide layer were U, Zr, and O, and the content of stainless steel was low. The main element in the metal layer was stainless steel and contained a certain amount of U and Zr.

2010 ◽  
Vol 638-642 ◽  
pp. 564-569 ◽  
Author(s):  
Takumi Haruna ◽  
Itsuki Shinohara

It has been tried to develop Ti-Ca alloys which demonstrates corrosion resistance in an aqueous fluoride solutions. The Ti-Ca alloys were produced by diffusion-metallizing method. A Ti plate and Ca grains were put in a sealed container of stainless steel. As the container was heated at 1000 oC, Ca was melted and partially vaporized in the inner space. Ca then contacts and permeats into the Ti plate to metallize. In a holding time of 450 h, the alloy surface consisted of two layers, the first was oxide layer and the second was metal layer of about 200 m thick. A Vickers micro hardness of the second layer was quite large, upto about 600 Hv. Evaluation of corrosion resistance for the second layer and the inner part was carried out by electrochemical potentiokinetic method. Test solutions were aqueous fluoride solutions produced with HF and NaF. A concentration of fluoride ion was fixed to 0.024 kmol m-3, and pH of the solution was varied from 3.4 to 4.7. As a result, both Ti and Ti-Ca alloy were passivated under natural immersion condition in the solution of pH 4.7. At pH 3.4, on the other hand, Ti was actively dissolved, but Ti-Ca alloy was still passivated, that means Ti-Ca alloy performs much better corrosion resistance than Ti.


Author(s):  
L. Carénini ◽  
F. Fichot

The In-Vessel Retention (IVR) strategy for Light Water Reactors (LWR) intends to stabilize and retain the core melt in the reactor pressure vessel. This type of Severe Accident Management (SAM) strategy has already been incorporated in the SAM guidance (SAMG) of several operating small size LWR (reactors below 500MWe, like VVER440) and is part of the SAMG strategies for some Gen III+ PWRs of higher power like the AP1000. One of the main issues for the demonstration of the success of the IVR strategy lies in the evaluation of the transient heat fluxes applied by the corium pool along the vessel wall. Indeed, these transient heat fluxes, during the corium pool stratification evolution, are expected to be higher than the steady-state ones, in particular due to the concentration of the heat flux in the top metal layer when it is thin (so called focusing effect). Another issue appears when a heavy metal is initially formed and rises later to the top (inversion of stratification): in such a situation, the metal goes through the oxide phase and accumulates a significant superheat which is likely to produce a high transient heat flux. Thus, it is of primary importance to be able to evaluate the duration of these transient peaks in order to evaluate the minimal residual vessel thickness after such fast transient ablation and draw conclusions about the vessel integrity. This paper first presents the phenomenology associated to the transient molten pool stratification and the model implemented in the severe accident integral code ASTEC (Accident Source Term Evaluation Code) to evaluate this kinetics. Then, evaluations are presented, based on a typical PWR reactor configuration. A sensitivity study is proposed to consider the impact of the main uncertainties on parameters which govern this kinetics. A particular focus is made on the physical phenomena driving the transient stratification of material layers in the corium pool and on the identification of critical situations with possible consequences in terms of vessel failure. The characteristic times of each individual process (chemistry, stratification, natural convection) are compared. In particular, the limiting cases of very fast chemistry or very slow chemistry are evaluated. This work is performed in the frame of the European H2020 project IVMR (In-Vessel Melt Retention) coordinated by IRSN. This project has been launched in 2015 and gathers 27 organizations with, as main objective, the evaluation of feasibility of IVR strategy for LWR (PWR, VVER, BWR) of total power 1,000MWe or higher.


2019 ◽  
Vol 492 ◽  
pp. 280-284
Author(s):  
Naoya Miyauchi ◽  
Tomoya Iwasawa ◽  
Taro Yakabe ◽  
Masahiro Tosa ◽  
Toyohiko Shindo ◽  
...  

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 621
Author(s):  
Aleksi Laukka ◽  
Eetu-Pekka Heikkinen ◽  
Timo Fabritius

Utilising the oxyfuel practice for CH4-fuelled combustion has positive effects on the emissions, efficiency and cost of high temperature furnace practices. However, especially in older installations, oxyfuel usage requires retrofitting and alters the atmosphere in which the oxidation of the steel occurs, when compared to using air as the oxidiser. Stainless steel slab oxide growth during reheating was studied in different atmospheres. The simulated post-burn atmospheres from oxyfuel, lean oxyfuel and air-fuel practices were used to compare oxide-scale layer growth and morphology during simulated typical AISI 304 stainless steel slab reheating prior to hot rolling. Thermogravimetric measurements, glow discharge optical emission spectrometer (GDOES) and field-emission scanning electron microscope energy dispersive X-ray (FESEM-EDS) methodology were applied to discern differences between oxide growth and inner oxide layer morphology between the three practices. Switching from air to oxyfuel practice at a single temperature had the same increasing effect on the scale formation amount as a 25 °C temperature increase in air atmosphere. Inner oxide layer depth profiling revealed C, Si and Ni to be the main elements that differed between temperatures and atmospheres. A morphology study showed Si and Ni behaviour to be linked to breakaway oxidation.


Author(s):  
Ayumi Itoh ◽  
Nathan C. Andrews ◽  
David L. Luxat ◽  
Randall O. Gauntt ◽  
Masaki Kurata ◽  
...  

2012 ◽  
Vol 87 (5-6) ◽  
pp. 580-583 ◽  
Author(s):  
Yasuhisa Oya ◽  
Makoto Kobayashi ◽  
Junya Osuo ◽  
Masato Suzuki ◽  
Akiko Hamada ◽  
...  

2009 ◽  
Vol 56 (2) ◽  
pp. 799-803 ◽  
Author(s):  
Kenji Okuno ◽  
Sachiko Suzuki ◽  
Hirotada Ishikawa ◽  
Takumi Hayashi ◽  
Toshihiko Yamanishi ◽  
...  

CORROSION ◽  
10.5006/2674 ◽  
2018 ◽  
Vol 74 (9) ◽  
pp. 1011-1022 ◽  
Author(s):  
Megan Mahrokh Dorri ◽  
Stéphane Turgeon ◽  
Maxime Cloutier ◽  
Pascale Chevallier ◽  
Diego Mantovani

Localized corrosion constitutes a major concern in medical devices made of stainless steel. The conventional approach to circumvent such a problem is to convert the surface polycrystalline microstructure of the native oxide layer to an amorphous oxide layer, a few micrometers thick. This process cannot, however, be used for devices such as stents that undergo plastic deformation during their implantation, especially those used in vascular surgery for the treatment of cardiac, neurological, and peripheral vessels. This work explores the feasibility of producing a nano-thick plastic-deformation resistant amorphous oxide layer by plasma-based surface modifications. By varying the plasma process parameters, oxide layers with different features were produced and their properties were investigated before and after clinically-relevant plastic deformation. These properties and the related corrosion mechanisms were mainly evaluated using the electrochemical methods of open-circuit potential, cyclic potentiodynamic polarization, and electrochemical impedance spectroscopy. Results showed that, under optimal conditions, the resistance to corrosion and to the permeation of ions in a phosphate buffered saline, even after deformation, was significantly enhanced.


Author(s):  
Li Fang Mei ◽  
Shun Xie ◽  
Dongbing Yan ◽  
Zhiqin Lei ◽  
Wei Yin ◽  
...  

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