scholarly journals Probing the Anti-Corrosion Behavior of X65 Steel Underwater FSW Joint in Simulated Seawater

2022 ◽  
Vol 8 ◽  
Author(s):  
Gang Ma ◽  
Hui Gao ◽  
Chong Sun ◽  
Yanhong Gu ◽  
Jie Zhao ◽  
...  
Keyword(s):  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Corrosion Current ◽  
Joint Surface ◽  
Duty Ratio ◽  
Scanning System ◽  
Coating Surface ◽  
Defect Area ◽  
Simulated Seawater

To detect the corrosion resistance of a friction stud welding (FSW) joint in simulated seawater (a 3.5 wt% NaCl solution), the pulse electrochemical deposition method was used for electroplating Ni coating with different duty ratios (50%, 80%, and 100%) on the surface of FSW joint. The microstructure and surface structure of the coating were observed by micro-spectroscopy and other characterization methods. The corrosion behavior of the coating was analyzed by means of macroscopic electrochemical testing. The local corrosion law of joint surface and coating surface defects were innovatively explored by using micro-zone electrochemical scanning system. The coating characterization results showed that, as the duty ratio continues to increase, the coating surface becomes denser and smoother, and the corrosion products such as Fe2O3, Fe3O4, and FeOOH are generated. The results of macroscopic electrochemical experiment indicated that the coating with 100% duty ratio has the lowest corrosion current density and the maximum polarization resistance. The scanning vibrating electrode technique results showed that the corrosion current density in the defect area is higher than that in the coating area, and the maximum corrosion current density decreases with the increase of duty ratio. The localized electrochemical impedance spectroscopy results indicated that the localized impedance at the welded zone was the largest, and with the increase of the pulse duty ratio, the impedance diffusion in the defect area was decreasing.

Electrochemical Characteristics of Lanthanum Hexaboride in the Environments Containing S2-

2010 ◽  
Vol 663-665 ◽  
pp. 473-476
Author(s):  
Shu Qi Zheng ◽  
Chang Feng Chen ◽  
Rui Jing Jiang ◽  
Dan Ni Wang
Keyword(s):  
Partial Pressure ◽  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Lanthanum Hexaboride ◽  
Electrochemical Characteristics

In the environment with H2S/CO2 or Na2S, the corrosion behavior of Lanthanum hexaboride (LaB6) was investigated by electrochemistry methods. The results indicated that the corrosion potential (Ecorr) and Rf of LaB6 increased as the partial pressure of H2S increased, while the corrosion current density (Icorr) decreased. In the environment containing Na2S, as the content of Na2S increased, the corrosion potential (Ecorr) and Rf of LaB6 decreased, while the corrosion current density (Icorr) increased. Thus, the addition of H2S into the environment with H2S/CO2 would inhibit the corrosion of LaB6; while in the environment containing Na2S, the increasing of the content of Na2S would accelerate the corrosion of LaB6.

Corrosion behavior of X80 steel under disbond coating interfered with AC

2019 ◽  
Vol 66 (6) ◽  
pp. 704-718
Author(s):  
Qingmiao Ding ◽  
Zili Li ◽  
Tao Shen ◽  
Gan Cui
Keyword(s):  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
The Self ◽  
Stray Current ◽  
Content Type ◽  
X80 Steel ◽  
Protection Potential

Purpose This paper aims to research the corrosion behavior of the metal under the disbonded coatings interfered with AC through electrochemical method. Design/methodology/approach The corrosion behavior of the metal under disbond coating interfered with alternate stray current (AC) was studied by electrochemical methods using the rectangular coating disbonded simulator. The obtained data from electrode potential test, electrochemical impedance spectroscopy (EIS) and polarization curves in simulated soil solution indicated that under the natural corrosion condition, the self-corrosion potential and the corrosion current density of the metal at different depths under disbond coating had obviously changed if there was AC interference. Findings The self-corrosion potential of the metal at the same depths under disbond coating shifted negatively with the rising of the AC voltage. Under the condition of cathode polarization, there was still obvious potential gradient with the extension of the deep peeling of the coating gap, and the corrosion current density of the test points was minimum, and the protection effect was best when the cathode protection potential was −1.0 V. When the metal was applied with over-protection, the corrosion rate of the metal increased as AC stray current flowing through it increased. Originality/value This paper used the rectangular aperture device to study the corrosion behavior of X80 steel under the disbonded coatings through electrochemical methods when the AC stray current interference voltage was 0V, 1V, 5V or 10V and the protection potential was 0V, −0.9V, −1.0V, −1.2V or −1.3V, respectively. There is great significance to the safe operation and long-term service of pipeline steel in soil environment.

scholarly journals Experimental Study on the Influence of Sulfate Reducing Bacteria on the Metallic Corrosion Behavior under Disbonded Coating

2017 ◽  
Vol 2017 ◽  
pp. 1-13 ◽  
Author(s):  
Qingmiao Ding ◽  
Liping Fang ◽  
Yanyu Cui ◽  
Yujun Wang
Keyword(s):  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Test Point ◽  
Sulfate Reducing ◽  
Metallic Corrosion ◽  
Reducing Bacteria ◽  
Disbonded Coating

A rectangle disbonded coating simulation device was used to research the effect of sulfate reducing bacteria (SRB) on the metallic corrosion behavior under disbonded coating by the electrochemical method. The results showed that the metal self-corrosion potential at the same test point had little change in the initial experiment stage, whether the solution was without or with SRB. The potential amplitude in the solution with SRB was larger than that without SRB in the later corrosion period. The corrosion current density of the metal at the same test point increased gradually over time in the solution with or without SRB, and SRB could accelerate the corrosion of the metal in the disbonded crevice. The metal self-corrosion potential in the crevice had little change in the SRB solution environment after adding the fungicide, but the corrosion current density decreased significantly. That meant the growth and reproduction of SRB were inhibited after adding the fungicide, so the metal corrosion rate slowed down. Among the three kinds of solution environment, increasing the coating disbonded thickness could accelerate the corrosion of the metal in the crevice, and it was the largest in the solution with SRB.

scholarly journals Corrosion Behavior of Low Carbon Line Pipe Steel in Soil Environment

2017 ◽  
Vol 7 (2) ◽  
pp. 147 ◽  
Author(s):  
A. Benmoussat ◽  
M. Hadjel
Keyword(s):  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Pipe Steel ◽  
Specific Resistance ◽  
Corrosion Current ◽  
Low Carbon ◽  
Line Pipe ◽  
Transfer Resistance ◽  
Line Pipe Steel

<p>Some operating buried transmission pipeline systems will develop unforeseen surface corrosion. Electrochemical corrosion behavior of low carbon line pipe steel in NS<sub>4</sub> soil test solution has been investigated by EIS method. Corrosion phenomenon is accentuated by influence of such soils parameters as specific resistance, pH, temperature, moisture content and chemical composition of electrolytes contained in soil. Results showed that steel corrosion increases considerably at acidic pH environments. Corrosion current density increases with temperature in the range from 20 to 60 °C. The associated activation energy has been determined. Impedance curves showed that the charge transfer resistance (<em>R<sub>t</sub></em>) increases with increasing immersion duration. Parameters such as corrosion current density (<em>I<sub>corr</sub></em>), polarization resistance (<em>R<sub>p</sub></em>), soil specific resistance (r) can serve as the parameters for evaluation of soil corrosiveness.</p>

scholarly journals Effect of Alternating Stray Current Density on Corrosion Behavior of X80 Steel under Disbonded Coating

2021 ◽  
Vol 2021 ◽  
pp. 1-13
Author(s):  
Qing-Miao Ding ◽  
Yong-Xiang Qin ◽  
Tao Shen ◽  
Yu-ning Gao
Keyword(s):  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Corrosion Current ◽  
Negative Deviation ◽  
Stray Current ◽  
Cathode Area ◽  
X80 Steel ◽  
Wire Beam Electrode ◽  
Disbonded Coating

In this paper, the effect of alternating stray current (AC) density on the corrosion behavior of X80 steel under disbonded coating was studied by electrochemical methods, wire beam electrode (WBE) technology, and surface observation technology. The results showed that under the interference of different AC densities, the corrosion potential of X80 steel under disbonded coating underwent negative deviation, and the degree of negative deviation increased with the increase of AC density. The corrosion current density of X80 steel under disbonded coating with the action of 0~100 A/m2 AC density had few differences. While the corrosion current density of X80 steel with the action of 200~300 A/m2 AC density increased and the corrosion current density was higher than that under low AC density. The cathode area of the wire beam electrode under disbonded coating is mainly distributed outside and the edge of the gap between disbonded coating and X80 steel, while the anode area is mainly distributed inside the gap.

scholarly journals Corrosion Behavior of Diffusion Bonding Joints of (OFHC) Copper with Stainless Steel 304L in 3.5% NaCl

2018 ◽  
Vol 21 (1) ◽  
pp. 74
Author(s):  
Sami Abualnoun Ajeel ◽  
Ahmed Ali Akbar Akbar ◽  
Safaa Mohammed Hassoni
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Current Density ◽  
Diffusion Bonding ◽  
Corrosion Current Density ◽  
Pure Copper ◽  
Corrosion Current ◽  
Stainless Steel 304L ◽  
Materials Used

The present work deals with direct diffusion bonding welding without interlayer of austenitic stainless steel type AISI 304L with Oxygen Free High Conductivity pure copper (OFHC) in vacuum atmosphere (1.5 *10-5 mbr.). The optimum bonding conditions are temperature of 650 ◦C, duration time of 45 min. and the applied stress of 30 MPa, in order to secure a tight contact between the mating surfaces. The corrosion behavior of diffusion bonding joints in 3.5% Nacl is studied to evaluate the corrosion resistance of welding joints by using Potentiodynamic method. The observed microstructure of corroded specimen of optimum diffusion bonding joint shows that the corrosion current density has low value as compared with base materials used. During polarization, galvanic coupling is observed between two materials used. At passivity region, inverse polarity is occurred at 450mV. Therefore, passive stainless steel 304 L behaves as cathode respective to pure copper, the corrosion behavior of the diffusion bonding joint was mostly by copper side. The corrosion results indicate the presence of galvanic effect. The corrosion current density of copper, stainless steel 304L and bond joints condition were (3.66 µA/cm2, 1.62 µA/cm2 and 1.85µA/cm2) respectively. A SEM examination of corroded diffusion bonding joint indicates that the galvanic corrosion happened on copper side. The corrosion rate of bonding joint conditions was 0.85 mpy, which is less than 1%. This means that corrosion resistance of bond joint is more than excellent.

scholarly journals Evaluation of Corrosion Behavior on Crept AlSi10MnMg (AA365) Alloy Produced by High-Pressure Die-Casting (HPDC)

2021 ◽  
Vol 11 (13) ◽  
pp. 6227
Author(s):  
Seonghwan Park ◽  
Cheolmin Ahn ◽  
Eunkyung Lee
Keyword(s):  
High Pressure ◽  
Intermetallic Compounds ◽  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Galvanic Corrosion ◽  
Corrosion Current ◽  
Die Cast ◽  
Corrosive Environments ◽  
Pressure Die Casting

High-pressure die-cast AlSi10MnMg (AA365) alloys have been used as a material for automotive components exposed to high temperature and corrosive environments. This work determines the correlation of corrosion resistance with the intermetallic compounds and micro-voids of crept AA365 alloys under temperatures ranging from 373 K to 573 K with various applied stresses. The results showed that crept AA365 alloy at 473 K possessed a large amount of the intermetallic phases, compared with crept AA365 alloys at 373 K and 573 K due to the non-equilibrium solute atoms in Al matrix. By contrast, crept AA365 alloy at 573 K contained the lowest number of intermetallic precipitates owing to the remelting of the phases. With regard to the corrosion behavior, the corrosion potentials showed −687.0, −684.0, and −673.0 mVSCE of crept AA365 alloys at 373 K, 473 K, and 573 K, respectively, which means the corrosion occurred slowly on the crept AA365 alloy at 573 K, rather than at 373 K, 473 K. The value of the corrosion current density (Icorr) in the crept HPDC AA365 alloy at 473 K has the highest corrosion current density of 13.3 × 10−6 Acm−2, compared with others. It can be inferred that the high amount of intermetallic compounds gave rise to severe corrosion and led to the harmful micro-galvanic corrosion of crept AA365 alloy, rather than the micro-voids.

scholarly journals Effect of Recrystallization Annealing on Corrosion Behavior of Ta-4%W Alloy

Materials ◽  
2018 ◽  
Vol 12 (1) ◽  
pp. 117 ◽  
Author(s):  
Guoqiang Ma ◽  
Qiongyao He ◽  
Xuan Luo ◽  
Guilin Wu ◽  
Qiang Chen
Keyword(s):  
Corrosion Resistance ◽  
Anodic Dissolution ◽  
Corrosion Behavior ◽  
Current Density ◽  
Polarization Resistance ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Recrystallization Annealing ◽  
Site Lattice

The effect of recrystallization annealing on corrosion behavior of Ta-4%W alloy was studied. It is found that the deformed sample contains high dense dislocations and dislocation boundaries. During annealing, these dislocations and dislocation boundaries are replaced by recrystallizing grains until the alloy is fully recrystallized. Both the anodic dissolution and the cathodic activity is much more blocked. The corrosion potential gradual shift towards negative values and corrosion current density decrease, while polarization resistance increases after annealing, indicating enhanced corrosion resistance of the alloy. Such an enhancement is caused by the increase of low-Σ coincide site lattice boundaries and decrease of dislocations and dislocation boundaries.

scholarly journals Polarization and EIS studies to evaluate the effect of aluminum concentration on the corrosion behavior of SAC105 solder alloy

2018 ◽  
Vol 35 (4) ◽  
pp. 694-701 ◽  
Author(s):  
N. K. Liyana ◽  
M. A. Fazal ◽  
A. S. M. A. Haseeb
Keyword(s):  
Solder Alloy ◽  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Electrochemical Impedance ◽  
Corrosion Current ◽  
Aluminum Concentration ◽  
Nacl Solution ◽  
Sac105 Solder ◽  
Eis Measurements

Abstract This paper presents an investigation on corrosion behavior of Sn-1.0Ag-0.5Cu-XAl (X = 0, 0.1, 0.5, 1.0) by means of polarization and electrochemical impedance spectroscopy (EIS) measurements in 3.5 wt.% NaCl solution. The results show that addition of aluminum into SAC105 shifts the corrosion current density and passivation current density towards more positive values. It is also found that with an increase in aluminum concentration in SAC105 solder alloy, the corrosion current density increases and polarization resistance decreases. This suggests that SAC105 with the highest concentration of Al has the lowest corrosion resistance. In this case, the corrosion behavior seems to be attributed to anodic dissolution of aluminum and Sn-matrix.

scholarly journals An electrochemical method to investigate the effects of compound composition on gold dissolution in thiosulfate solution

2020 ◽  
Vol 9 (1) ◽  
pp. 496-502 ◽  
Author(s):  
Zhaohui Zhang ◽  
Bailong Liu ◽  
Mei Wu ◽  
Longxin Sun
Keyword(s):  
Dissolution Rate ◽  
Current Density ◽  
Polarization Resistance ◽  
Electrochemical Method ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Gold Dissolution ◽  
Tafel Polarization ◽  
Edta Solution

AbstractThe electrochemical behavior of gold dissolution in the Cu2+–NH3–S2O32−–EDTA solution has been investigated in detail by deriving and analyzing the Tafel polarization curve, as this method is currently widely implemented for the electrode corrosion analysis. The dissolution rate of gold in Cu2+–NH3–S2O32−–EDTA solution was determined based on the Tafel polarization curves, and the effects of various compound compositions in a Cu2+–NH3–S2O32−–EDTA mixture on the corrosion potential and corrosion current density were analyzed. The results showed that the corrosion potential and polarization resistance decreased, whereas the corrosion current density increased for certain concentrations of S2O32−–NH3–Cu2+ and EDTA, indicating that the dissolution rate of gold had changed. The reason for promoting the dissolution of gold is also discussed.

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