scholarly journals Effects of the Silicate Modulus of Water Glass on the Hydration and Mechanical Properties of Alkali-Activated Blast Furnace Ferronickel Slag

2021 ◽  
Vol 8 ◽  
Author(s):  
Kuisheng Liu ◽  
Zhenguo Liu ◽  
Jianwei Sun
Keyword(s):  
Mechanical Properties ◽  
Adverse Effect ◽  
Tensile Strength ◽  
Blast Furnace ◽  
Water Glass ◽  
Hydration Product ◽  
Strength Development ◽  
Ferronickel Slag ◽  
Alkali Activated ◽  
High Silicate

Blast furnace ferronickel slag (BFNS), currently an underutilized metallurgical residue, was investigated for use as a precursor for alkaline activation. Water glass solutions with various moduli (0.5, 1.0, 1.5 and 2.0) were used at the same water glass concentration of 10% to investigate the influence of the modulus on hydration and mechanical properties. The results show that the modulus has a certain impact on the hydration and mechanical strength development of alkali-activated BFNS. Increasing the modulus of water glass does not change the type of hydration product and the activity of the Mg-containing phases, but it decreases the amount of C2AS, the Ca/Si and Al/Si ratios of the (N,C)-A(M)-S-H gel. In addition, a high silicate modulus deteriorates the pore structure, which has an adverse effect on the development of compressive strength and splitting tensile strength.

Mechanical properties of alkali activated blast furnace slag pastes reinforced with carbon fibers

2016 ◽  
Vol 116 ◽  
pp. 63-71 ◽  
Author(s):  
J.L. Vilaplana ◽  
F.J. Baeza ◽  
O. Galao ◽  
E.G. Alcocel ◽  
E. Zornoza ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Blast Furnace ◽  
Carbon Fibers ◽  
Blast Furnace Slag ◽  
Furnace Slag ◽  
Alkali Activated

scholarly journals Microstructural and Mechanical Properties of Alkali Activated Materials from Two Types of Blast Furnace Slags

Materials ◽  
2019 ◽  
Vol 12 (13) ◽  
pp. 2089 ◽  
Author(s):  
Jun Xing ◽  
Yingliang Zhao ◽  
Jingping Qiu ◽  
Xiaogang Sun
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Blast Furnace ◽  
Thermal Stabilization ◽  
Hydration Process ◽  
Reaction Products ◽  
Basic Oxide ◽  
X Ray ◽  
Physical And Chemical ◽  
Alkali Activated

This paper investigated the effect of blast furnace slags (BFS) characteristics on the properties achievement after being alkali activated. The physical and chemical characteristics of BFS were determined by X-ray fluorescence (XRF), X-ray Diffraction (XRD) and laser granulometry. Multi-technical characterizations using calorimetry, XRD, Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetry (TG-DTG), scanning electron microscope (SEM), nitrogen sorption and uniaxial compressive strength (UCS) were applied to give an in-depth understanding of the relationship between the reaction products, microstructure and BFS characteristics. The test results show that the microstructure and mechanical properties of alkali activated blast furnace slags (BFS) highly depend on the characteristics of BFS. Although the higher content of basic oxide could accelerate the hydration process and result in higher mechanical properties, a poor thermal stabilization was observed. On the other hand, with a higher content of Fe, the hydration process in alkali activated BFS2 lasts for a longer time, contributing to a delayed compressive strength achievement.

Comparison of Selected Properties of Portland Cement Based Materials and Alkali Activated Materials Based on Granulated Blast Furnace Slag

2016 ◽  
Vol 865 ◽  
pp. 107-113 ◽  
Author(s):  
Pavel Mec ◽  
Jana Boháčová ◽  
Josef Koňařík
Keyword(s):  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Water Glass ◽  
Sodium Metasilicate ◽  
Alkali Activation ◽  
Granulated Blast Furnace Slag ◽  
Cement Based Materials ◽  
One Year ◽  
Furnace Slag ◽  
Alkali Activated

Alkali activated systems are materials formed by alkali-activation of latent hydraulic or pozzolanic materials. The outcome is a polymeric structure with properties comparable to materials based on cement.The principle of the experiment is to compare selected properties of alkali-activated materials based on blast furnace slag and using various types of activator (sodium water glass, potassium water glass, DESIL AL and sodium metasilicate) to binders based on white and Portland cements of the highest quality. The samples were left for one year in environments simulating the conditions in the interior and exterior. Selected physical-mechanical properties were evaluated and compared.

High Strength Alkali Activated Slag Cements with Controlled Setting Times and Early Strength Gain

2015 ◽  
Vol 1100 ◽  
pp. 44-49 ◽  
Author(s):  
Pavel Krivenko ◽  
Oleg Petropavlovsky ◽  
Vit Petranek ◽  
Vasiliy Pushkar ◽  
Grigorii Vozniuk
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Water Glass ◽  
High Strength ◽  
Strength Gain ◽  
Setting Times ◽  
Alkaline Activator ◽  
Early Strength ◽  
Activated Slag ◽  
Alkali Activated

The paper discusses approaches to compositional build-up of high strength alkali activated cements made using water glass as alkaline activator represented by commercial products in a form of powder and liquid. The purpose was to study the influence of fineness of ground granulated blast-furnace slags, admixtures and additives, compatible with alkali activated cements, water glass and mode of manufacturing technology in order to reach high compressive strength (≥ 80 MPa at standard age (28 days)) and early strength (≥ 20 MPa after 3 h of hardening in normal conditions).

Experimental Study on Compound Binding Material of Alkali Activated Metakaolin and Ground Granulated Blast Furnace Slag

2011 ◽  
Vol 287-290 ◽  
pp. 1275-1279
Author(s):  
Yong Jia He ◽  
Lin Nu Lu ◽  
Shu Guang Hu
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Hydration Product ◽  
Alkali Activation ◽  
Granulated Blast Furnace Slag ◽  
Binding Material ◽  
Measurement Results ◽  
Furnace Slag ◽  
Alkali Activated

Compound binding material was prepared by the alkali activation of metakaolin and ground granulated blast furnace slag. Hydration product components, microstructure and mechanical properties of the hardened paste were investigated by IR, XRD, SEM, MIP, and compressive strength measurement. Results indicated that hydration products included C-S-H and geopolymer, and both of them were amorphous although there were differences in their structure and morphology. When the dosage of slag was less than 50%, the compressive strength of hardened paste increased as the dosage increased, which was mainly because C-S-H produced by the reaction of GGBFS and alkali filled void in geopolymer phase, and part of unreacted slag particles acting as microaggregate to prevent from extension of microcrack in the hardened paste, so the porosity of hardened paste decreased and compressive strength increased.

scholarly journals MECHANICAL AND CHEMICAL ACTIVATION OF BLAST FURNACE SLAG AND ITS INFLUENCE ON THE MECHANICAL PROPERTIES OF THE RESULTING CEMENT PASTE

2021 ◽  
Vol 30 ◽  
pp. 30-35
Author(s):  
Jan Horych ◽  
Pavel Tesárek ◽  
Zdeněk Prošek
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Water Glass ◽  
High Speed ◽  
Chemical Activation ◽  
Waste Materials ◽  
Slaked Lime ◽  
Furnace Slag

The usage of waste materials is a very important global topic. The large amount of waste everywhere in the world needs to be processed or disposed. Landfilling is not an option anymore, because of European legislation and restrictions. A lot of studies are trying to develop new options or possibilities of using waste materials. This research is trying to find a way to process blast furnace slag. A high-speed mill was used for the mechanical activation. Chemical activation was used as the next step of activation. There are many materials that could be used, but in this study we used slaked lime and water-glass. Slaked lime had a positive effect on mechanical properties. Samples had higher compressive strength but the effect was limited only for 5 wt. %. Another used material was water-glass, but in this case, there was a significant negative effect. Compressive strength and flexural strength were significantly reduced.

The Leachability of Heavy Metals from Alkali-Activated Fly Ash and Blast Furnace Slag Matrices

2016 ◽  
Vol 851 ◽  
pp. 141-146
Author(s):  
Jan Koplík ◽  
Miroslava Smolková ◽  
Jakub Tkacz
Keyword(s):  
Mechanical Properties ◽  
Heavy Metals ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Inductively Coupled Plasma ◽  
Emission Spectrometry ◽  
Alkali Activation ◽  
Furnace Slag ◽  
Alkali Activated

The ability of alkali-activated materials (AAMs) to fix and immobilize heavy metals was investigated. Two raw materials were used to prepare alkali-activated matrices – high-temperature fly ash and blast furnace slag (BFS). NaOH served as an alkaline activator. Two heavy metals (Mn, Ni) were added in different amounts to find out the influence of dosage of heavy metal on the mechanical properties of the matrices and the leachability. Leachability was measured as concentration of heavy metals in leachates (ČSN EN 12457-4) by inductively coupled plasma/optical emission spectrometry (ICP/OES). Structure of prepared matrices was characterized by scanning electron microscopy (SEM). Increasing of addition of heavy metals led to decrease of mechanical properties of matrices. The leaching tests showed, that both matrices can immobilize Mn and Ni in dosages of 0.1 – 2,5%. Higher dosages caused deterioration of the matrices and increased the leachability. After alkali activation both heavy metals were transformed into the form of insoluble salts.

Possibilities of Using Plasticizers in Alkali-Activated Systems

2016 ◽  
Vol 851 ◽  
pp. 57-62
Author(s):  
Lukáš Kalina ◽  
Miroslava Hajdúchová ◽  
Markéta Langová ◽  
Vojtěch Enev
Keyword(s):  
Mechanical Properties ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Preparation Process ◽  
The Stability ◽  
Activated Slag ◽  
Plasticizing Admixture ◽  
Furnace Slag ◽  
Alkali Activated ◽  
Convenient Dose

The study deals with the preparation process and properties of alkali-activated blast furnace slag with different addition of lignosulphonate plasticizer. The goal of this study is to evaluate the suitability of plasticizer and find the convenient dose of this admixture, which improve the workability and mechanical properties of alkali-activated slag. The stability of plasticizing admixture in alkali environment was studied by infrared spectroscopy (FTIR).

scholarly journals Cement Kiln By-Pass Dust: An Effective Alkaline Activator for Pozzolanic Materials

Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1770 ◽  
Author(s):  
Lukáš Kalina ◽  
Vlastimil Bílek ◽  
Tomáš Kiripolský ◽  
Radoslav Novotný ◽  
Jiří Másilko
Keyword(s):  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Autogenous Shrinkage ◽  
Cement Industry ◽  
Strength Development ◽  
Cement Kiln ◽  
Binder Phase ◽  
Fine Grained ◽  
Furnace Slag ◽  
Alkali Activated

Cement kiln by-pass dust (CKD) is a fine-grained by-product of Portland clinker manufacturing. Its chemical composition is not suitable for returning back into feedstock and, therefore, it has to be discharged. Such an increasing waste production contributes to the high environmental impact of the cement industry. A possible solution for the ecological processing of CKD is its incorporation into alkali-activated blast furnace slag binders. Thanks to high alkaline content, CKD serves as an effective accelerator for latent hydraulic substances which positively affect their mechanical properties. It was found out that CKD in combination with sodium carbonate creates sodium hydroxide in situ which together with sodium water glass content increases the dissolution of blast furnace slag particles and subsequently binder phase formation resulting in better flexural and compressive strength development compared to the sample without it. At the same time, the addition of CKD compensates the autogenous shrinkage of alkali-activated materials reducing the risk of material cracking. On the other hand, this type of inorganic admixture accelerates the hydration process causing rapid loss of workability.

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