scholarly journals Level Structure and Properties of Open f-Shell Elements

Atoms ◽  
2022 ◽  
Vol 10 (1) ◽  
pp. 7
Author(s):  
Stephan Fritzsche
Keyword(s):  
Large Scale ◽  
Transition Probabilities ◽  
Level Structure ◽  
Shell Structures ◽  
Strong Correlations ◽  
Structure Transition ◽  
Shell Elements ◽  
Correlated Motion ◽  
Almost All ◽  
Accurate Computations

Open f-shell elements still constitute a great challenge for atomic theory owing to their (very) rich fine-structure and strong correlations among the valence-shell electrons. For these medium and heavy elements, many atomic properties are sensitive to the correlated motion of electrons and, hence, require large-scale computations in order to deal consistently with all relativistic, correlation and rearrangement contributions to the electron density. Often, different concepts and notations need to be combined for just classifying the low-lying level structure of these elements. With Jac, the Jena Atomic Calculator, we here provide a toolbox that helps to explore and deal with such elements with open d- and f-shell structures. Based on Dirac’s equation, Jac is suitable for almost all atoms and ions across the periodic table. As an example, we demonstrate how reasonably accurate computations can be performed for the low-lying level structure, transition probabilities and lifetimes for Th2+ ions with a 5f6d ground configuration. Other, and more complex, shell structures are supported as well, though often for a trade-off between the size and accuracy of the computations. Owing to its simple use, however, Jac supports both quick estimates and detailed case studies on open d- or f-shell elements.

scholarly journals Winter fidelity, movements, and energy expenditure of Midcontinent Greater White-fronted Geese

2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Jay A. VonBank ◽  
Mitch D. Weegman ◽  
Paul T. Link ◽  
Stephanie A. Cunningham ◽  
Kevin J. Kraai ◽  
...  
Keyword(s):  
Energy Expenditure ◽  
Time Allocation ◽  
Large Scale ◽  
Animal Movement ◽  
Transition Probabilities ◽  
Winter Period ◽  
Daily Movement ◽  
Regional Energy ◽  
Wintering Areas ◽  
Wintering Distribution

Abstract Background Animal movement patterns are the result of both environmental and physiological effects, and the rates of movement and energy expenditure of given movement strategies are influenced by the physical environment an animal inhabits. Greater white-fronted geese in North America winter in ecologically distinct regions and have undergone a large-scale shift in wintering distribution over the past 20 years. White-fronts continue to winter in historical wintering areas in addition to contemporary areas, but the rates of movement among regions, and energetic consequences of those decisions, are unknown. Additionally, linkages between wintering and breeding regions are generally unknown, and may influence within-winter movement rates. Methods We used Global Positioning System and acceleration data from 97 white-fronts during two winters to elucidate movement characteristics, model regional transition probabilities using a multistate model in a Bayesian framework, estimate regional energy expenditure, and determine behavior time-allocation influences on energy expenditure using overall dynamic body acceleration and linear mixed-effects models. We assess the linkages between wintering and breeding regions by evaluating the winter distributions for each breeding region. Results White-fronts exhibited greater daily movement early in the winter period, and decreased movements as winter progressed. Transition probabilities were greatest towards contemporary winter regions and away from historical wintering regions. Energy expenditure was up to 55% greater, and white-fronts spent more time feeding and flying, in contemporary wintering regions compared to historical regions. White-fronts subsequently summered across their entire previously known breeding distribution, indicating substantial mixing of individuals of varying breeding provenance during winter. Conclusions White-fronts revealed extreme plasticity in their wintering strategy, including high immigration probability to contemporary wintering regions, high emigration from historical wintering regions, and high regional fidelity to western regions, but frequent movements among eastern regions. Given that movements of white-fronts trended toward contemporary wintering regions, we anticipate that a wintering distribution shift eastward will continue. Unexpectedly, greater energy expenditure in contemporary wintering regions revealed variable energetic consequences of choice in wintering region and shifting distribution. Because geese spent more time feeding in contemporary regions than historical regions, increased energy expenditure is likely balanced by increased energy acquisition in contemporary wintering areas.

scholarly journals Structure transition of Au18 from pyramidal to a hollow-cage during soft-landing onto a TiO2(110) surface

2015 ◽  
Vol 51 (46) ◽  
pp. 9535-9538 ◽  
Author(s):  
Lei Li ◽  
Hui Li ◽  
Xiao Cheng Zeng
Keyword(s):  
Large Scale ◽  
Soft Landing ◽  
Structure Transition

Simulation of the soft-landing process of pyramidal Au18 onto a rutile TiO2(110) surface using large-scale BOMD simulation.

Some new results and current challenges in the finite element analysis of shells

Acta Numerica ◽  
2001 ◽  
Vol 10 ◽  
pp. 215-250 ◽  
Author(s):  
Dominique Chapelle
Keyword(s):  
Finite Element ◽  
Shell Theory ◽  
Shell Structures ◽  
Engineering Practice ◽  
Element Analysis ◽  
Shell Elements ◽  
Shell Models ◽  
The Finite Element Analysis ◽  
Shell Finite Element ◽  
Mathematical Analyses

This article, a companion to the article by Philippe G. Ciarlet on the mathematical modelling of shells also in this issue of Acta Numerica, focuses on numerical issues raised by the analysis of shells.Finite element procedures are widely used in engineering practice to analyse the behaviour of shell structures. However, the concept of ‘shell finite element’ is still somewhat fuzzy, as it may correspond to very different ideas and techniques in various actual implementations. In particular, a significant distinction can be made between shell elements that are obtained via the discretization of shell models, and shell elements – such as the general shell elements – derived from 3D formulations using some kinematic assumptions, without the use of any shell theory. Our first objective in this paper is to give a unified perspective of these two families of shell elements. This is expected to be very useful as it paves the way for further thorough mathematical analyses of shell elements. A particularly important motivation for this is the understanding and treatment of the deficiencies associated with the analysis of thin shells (among which is the locking phenomenon). We then survey these deficiencies, in the framework of the asymptotic behaviour of shell models. We conclude the article by giving some detailed guidelines to numerically assess the performance of shell finite elements when faced with these pathological phenomena, which is essential for the design of improved procedures.

RESEARCH OF EXTERNAL MASS TRANSFER PROCESSES FOR ADSORPTION FROM SOLUTIONS IN A APPARATUS WITH STIRRING

2021 ◽  
pp. 11-20
Author(s):  
V. Solovej ◽  
K. Gorbunov ◽  
V. Vereshchak ◽  
O. Gorbunova
Keyword(s):  
Mass Transfer ◽  
Energy Spectrum ◽  
Energy Dissipation ◽  
Large Scale ◽  
Isotropic Turbulence ◽  
Wave Number ◽  
Wave Form ◽  
Local Isotropy ◽  
Stirred Vessel ◽  
Almost All

A study has been mode of transport-controlled mass transfer-controlled to particles suspended in a stirred vessel. The motion of particle in a fluid was examined and a method of predicting relative velocities in terms of Kolmogoroff’s theory of local isotropic turbulence for mass transfer was outlined. To provide a more concrete visualization of complex wave form of turbulence, the concepts of eddies, of eddy velocity, scale (or wave number) and energy spectrum, have proved convenient. Large scale motions of scale contain almost all of the energy and they are directly responsible for energy diffusion throughout the stirring vessel by kinetic and pressure energies. However, almost no energy is dissipated by the large-scale energy-containing eddies. A scale of motion less than is responsible for convective energy transfer to even smaller eddy sires. At still smaller eddy scales, close to a characteristic microscale, both viscous energy dissipation and convection are the rule. The last range of eddies has been termed the universal equilibrium range. It has been further divided into a low eddy size region, the viscous dissipation subrange, and a larger eddy size region, the inertial convection subrange. Measurements of energy spectrum in mixing vessel are shown that there is a range, where the so called -(5/3) power law is effective. Accordingly, the theory of local isotropy of Kolmogoroff can be applied because existence of the internal subrange. As the integrated value of local energy dissipation rate agrees with the power per unit mass of liquid from the impeller, almost all energy from the impeller is viscous dissipated in eddies of microscale. The correlation for mass transfer to particles suspended in a stirred vessel is recommended. The results of experimental study are approximately 12 % above the predicted values.

Why Do People Stay Poor?

2021 ◽  
Author(s):  
Clare Balboni ◽  
Oriana Bandiera ◽  
Robin Burgess ◽  
Maitreesh Ghatak ◽  
Anton Heil
Keyword(s):  
Occupational Choice ◽  
Large Scale ◽  
Choice Model ◽  
Effective Means ◽  
Threshold Level ◽  
Poverty Traps ◽  
Asset Transfer ◽  
Small Livestock ◽  
Program Costs ◽  
Almost All

Abstract There are two broad views as to why people stay poor. One emphasizes differences in fundamentals, such as ability, talent, or motivation. The other, the poverty traps view, emphasizes differences in opportunities which stem from access to wealth. To test between these two views, we exploit a large-scale, randomized asset transfer and an 11-year panel of 6,000 households who begin in extreme poverty. The setting is rural Bangladesh and the assets are cows. The data supports the poverty traps view—we identify a threshold level of initial assets above which households accumulate assets, take on better occupations (from casual labor in agriculture or domestic services to running small livestock businesses), and grow out of poverty. The reverse happens for those below the threshold. Structural estimation of an occupational choice model reveals that almost all beneficiaries are misallocated in the work they do at baseline and that the gains arising from eliminating misallocation would far exceed the program costs. Our findings imply that large transfers which create better jobs for the poor are an effective means of getting people out of poverty traps and reducing global poverty.

Opuntia ficus-indica (prickly pear).

2021 ◽  
Author(s):  
Nick Pasiecznik
Keyword(s):  
Vitamin C ◽  
Large Scale ◽  
Time Lag ◽  
Prickly Pear ◽  
Invasive Weeds ◽  
Historical Records ◽  
Opuntia Ficus Indica ◽  
Actual Risk ◽  
Invasive Spread ◽  
Almost All

Abstract O. ficus-indica is highly valued as a fruit-producing cactus, also yielding 'leaves' that are used as a vegetable and browsed by livestock. It has been introduced widely from its native Mexico to almost all countries where the climate is suitable. The fruit is very rich in vitamin C and is exploited commercially in many areas. Many countries, especially in Asia, have recently established large-scale commercial plantations. However, O. ficus-indica, like several other species of Opuntia, have been known to spread and become invasive weeds. Historical records, however, appear to indicate a time-lag of about 100 years between introduction and the beginnings of invasive spread thus the actual risk may be low.

What Kind of Friction Model Is Needed to Predict Brake Squeal?

2012 ◽  
Author(s):  
Tore Butlin ◽  
Jim Woodhouse
Keyword(s):  
Large Scale ◽  
Dynamic Properties ◽  
Theoretical Work ◽  
Friction Model ◽  
Coupled Systems ◽  
Brake Squeal ◽  
Model Framework ◽  
Wide Range ◽  
Pin On Disc ◽  
Almost All

Predictive models of friction-induced vibration have proved elusive despite decades of research. There are many mechanisms that can cause brake squeal; friction coupled systems can be highly sensitive to small perturbations; and the dynamic properties of friction at the contact zone seem to be poorly understood. This paper describes experimental and theoretical work aimed at identifying the key ingredients of a predictive model. A large-scale experiment was carried out to identify squeal initiations using a pin-on-disc test rig: approximately 30,000 squeal initiations were recorded, covering a very wide range of frequencies. The theoretical model allows for completely general linear systems coupled at a single sliding point by friction: squeal is predicted using a linearised stability analysis. Results will be presented that show that almost all observed squeal events can be predicted within this model framework, but that some subsets require innovative friction modelling: predictions are highly dependent on the particular choice of friction model and its associated parameters.

scholarly journals The 1995-2018 global evolution of the network of amicable and hostile relations among nation-states

2020 ◽  
Vol 3 (1) ◽  
Author(s):  
Omid Askarisichani ◽  
Ambuj K. Singh ◽  
Francesco Bullo ◽  
Noah E. Friedkin
Keyword(s):  
Large Scale ◽  
Transition Probabilities ◽  
Balance Theory ◽  
Frobenius Norm ◽  
Structural Balance ◽  
Interdisciplinary Field ◽  
Global Evolution ◽  
Nation States ◽  
Appraisal Systems ◽  
Large Scale Networks

AbstractThere has been longstanding interest in the evolution of positive and negative relationships among countries. An interdisciplinary field of study, Structural Balance Theory, has developed on the dynamics of such appraisal systems. However, the advancement of research in the field has been impeded by the lack of longitudinal empirical data on large-scale networks. We construct the networks of international amicable and hostile relations occurring in specific time-periods in order to study the global evolution of the network of such international appraisals. Here we present an empirical evidence on the alignment of Structural Balance Theory with the evolution of the structure of this network, and a model of the probabilistic micro-dynamics of the alterations of international appraisals during the period 1995-2018. Also remarkably, we find that the trajectory of the Frobenius norm of sequential transition probabilities, which govern the evolution of international appraisals among nations, dramatically stabilizes.

scholarly journals The influence of cactus spine surface structure on puncture performance and anchoring ability is tuned for ecology

2018 ◽  
Vol 285 (1891) ◽  
pp. 20182280 ◽  
Author(s):  
S. B. Crofts ◽  
P. S. L. Anderson
Keyword(s):  
Surface Structure ◽  
Large Scale ◽  
Biological Materials ◽  
Morphological Features ◽  
Ecological Functions ◽  
Defensive Mechanisms ◽  
Evolutionary Convergence ◽  
Almost All

Spines are common morphological features found in almost all major biological groups offering an opportunity to explore large-scale evolutionary convergence across disparate clades. As an example, opuntioid cacti have spines with barbed ornamentation that is remarkably similar in form and scale to that found on porcupine quills, suggesting specific biomechanical convergence across the animal and plant kingdoms. While the mechanics of porcupine quills as defensive mechanisms has been previously tested, the mechanics of cactus spines (which have evolved to fill a number of functions including defence, climbing and dispersal) has not been characterized. Here we study the puncturing and anchoring ability of six species of cactus, including both barbed and non-barbed spines. We found that barbed spines require less work to puncture a variety of targets than non-barbed spines. Barbed spines also require more work than non-barbed spines to withdraw from biological materials, owing to their barbs engaging with tissue fibres. These results closely match those found previously for barbed versus non-barbed porcupine quills, implying biomechanical convergence. The variation in performance of barbed versus non-barbed spines, as well as between barbed spines from different species, is probably tied to the diversity of ecological functions of cactus spines.

scholarly journals Small-scale characteristics of extremely high latitude aurora

2009 ◽  
Vol 27 (9) ◽  
pp. 3335-3347 ◽  
Author(s):  
J. A. Cumnock ◽  
L. G. Blomberg ◽  
A. Kullen ◽  
T. Karlsson ◽  
Keyword(s):  
High Latitude ◽  
Large Scale ◽  
Small Scale ◽  
Strong Correlations ◽  
Polar Cap ◽  
Plasma Flows ◽  
Ionospheric Convection ◽  
Local Closure ◽  
Scale Characteristics

Abstract. We examine 14 cases of an interesting type of extremely high latitude aurora as identified in the precipitating particles measured by the DMSP F13 satellite. In particular we investigate structures within large-scale arcs for which the particle signatures are made up of a group of multiple distinct thin arcs. These cases are chosen without regard to IMF orientation and are part of a group of 87 events where DMSP F13 SSJ/4 measures emissions which occur near the noon-midnight meridian and are spatially separated from both the dawnside and duskside auroral ovals by wide regions with precipitating particles typical of the polar cap. For 73 of these events the high-latitude aurora consists of a continuous region of precipitating particles. We focus on the remaining 14 of these events where the particle signatures show multiple distinct thin arcs. These events occur during northward or weakly southward IMF conditions and follow a change in IMF By. Correlations are seen between the field-aligned currents and plasma flows associated with the arcs, implying local closure of the FACs. Strong correlations are seen only in the sunlit hemisphere. The convection associated with the multiple thin arcs is localized and has little influence on the large-scale convection. This also implies that the sunward flow along the arcs is unrelated to the overall ionospheric convection.

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