scholarly journals New Strategy for Creating TiO2 Thin Films with Embedded Au Nanoparticles

Coatings ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1525
Author(s):  
Sofia Rubtsov ◽  
Albina Musin ◽  
Michael Zinigrad ◽  
Alexander Kalashnikov ◽  
Viktor Danchuk

This paper proposes a new strategy for producing thin films of TiO2 with embedded gold nanoparticles (TiO2/AuNP). One of the main tasks was the synthesis of a stable dispersion of TiO2 and gold nanoparticles in an aqueous solution of ethylene glycol, suitable for inkjet printing—ink with complex gold nanoparticles (AuCNP ink). The AuCNP were synthesized by a reduction from tetrachloroauric acid in the presence of TiO2 nanoparticles and ethylene glycol (EG). The final formation of TiO2/AuNP films occurred during the annealing of AuCNP layers, inkjet printed on a glass substrate. The TiO2/AuNP films demonstrate absorbance in the yellow-green range due to the localized surface plasmon resonance (LSPR) and are promising for solar cell application.

Coatings ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 227
Author(s):  
Marco S. Rodrigues ◽  
Diana I. Meira ◽  
Cláudia Lopes ◽  
Joel Borges ◽  
Filipe Vaz

In this work, plasmonic thin films composed of Au nanoparticles embedded in a TiO2 matrix were prepared in a transparent polymer substrate of poly(dimethylsiloxane) (PDMS). The thin films were deposited by reactive DC magnetron sputtering, and then subjected to heat treatment up to 150 °C in order to promote the growth of the Au nanoparticles throughout the TiO2 matrix. The transmittance spectrum of the thin films was monitored in situ during the heat treatment, and the minimum time required to have a defined localized surface plasmon resonance (LSPR) band was about 10 min. The average size of Au nanoparticles was estimated to be about 21 nm—the majority of them are sized in the range 10–40 nm, but also extend to larger sizes, with irregular shapes. The refractive index sensitivity of the films was estimated by using two test fluids (H2O and DMSO), and the average value reached in the assays was 37.3 ± 1.5 nm/RIU, resulting from an average shift of 5.4 ± 0.2 nm. The results show that it is possible to produce sensitive plasmonic Au-TiO2 thin films in transparent polymer substrates such as PDMS, the base material to develop microfluidic channels to be incorporated in LSPR sensing systems.


2014 ◽  
Vol 553 ◽  
pp. 138-143 ◽  
Author(s):  
S. Reymond-Laruinaz ◽  
L. Saviot ◽  
V. Potin ◽  
C. Lopes ◽  
F. Vaz ◽  
...  

2000 ◽  
Vol 87 (1) ◽  
pp. 612-614 ◽  
Author(s):  
W. Qian ◽  
L. Lin ◽  
Y. J. Deng ◽  
Z. J. Xia ◽  
Y. H. Zou ◽  
...  

2018 ◽  
Vol 122 (24) ◽  
pp. 13095-13105 ◽  
Author(s):  
M. Mercedes Zalduendo ◽  
Judith Langer ◽  
Juan J. Giner-Casares ◽  
Emilia B. Halac ◽  
Galo J. A. A. Soler-Illia ◽  
...  

2019 ◽  
Vol 25 (S2) ◽  
pp. 2248-2249
Author(s):  
Mariana Klementová ◽  
Adriana Lančok ◽  
Radek Fajgar ◽  
Martin Koštejn ◽  
Snejana Bakardijeva

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