scholarly journals Surface Modification of Polycarbonate by an Atmospheric Pressure Argon Microwave Plasma Sheet

Materials ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 2418 ◽  
Author(s):  
Dariusz Czylkowski ◽  
Bartosz Hrycak ◽  
Andrzej Sikora ◽  
Magdalena Moczała-Dusanowska ◽  
Mirosław Dors ◽  
...  

The specific properties of an atmospheric pressure plasma make it an attractive tool for the surface treatment of various materials. With this in mind, this paper presents the results of experimental investigations of a polycarbonate (PC) material surface modification using this new type of argon microwave (2.45 GHz) plasma source. The uniqueness of the new plasma source lies in the shape of the generated plasma—in contrast to other microwave plasma sources, which usually provide a plasma in the form of a flame or column, the new ones provides a plasma in the shape of a regular plasma sheet. The influence of the absorbed microwave power and the number of scans on the changes of the wettability and morphological and mechanical properties of the plasma-treated PC samples was investigated. The mechanical properties and changes in roughness of the samples were measured by the use of atomic force microscopy (AFM). The wettability of the plasma-modified samples was tested by measuring the water contact angle. In order to confirm the plasma effect, each of the above-mentioned measurements was performed before and after plasma treatment. All experimental tests were performed with an argon of flow rate up to 20 L/min and the absorbed microwave power ranged from 300 to 850 W. The results prove the capability of the new atmospheric pressure plasma type in modifying the morphological and mechanical properties of PC surfaces for industrial applications.

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
MiMi Kim ◽  
Heung Soo Kim ◽  
Joong Yeon Lim

The surface modification of wood powder by atmospheric pressure plasma treatment was investigated. The composites were manufactured using wood powder and polypropylene (wood powder: polypropylene = 55 wt% : 45 wt%). Atmospheric pressure plasma treatment was applied under the condition of 3 KV,17±1 KHz, 2 g/min. Helium was used as the carrier gas and hexamethyl-disiloxane (HMDSO) as the monomer to modify the surface property of the waste wood biocomposites by plasma polymerization. The tensile strengths of untreated waste wood powder (W3) and single species wood powder (S3) were about 18.5 MPa and 21.5 MPa while those of plasma treated waste wood powder (PW3) and plasma treated single species wood powder (PS3) were about 21.2 MPa and 23.4 MPa, respectively. Tensile strengths of W3 and S3 were improved by 14.6% and 8.8%, respectively. From the analyses of mechanical properties and morphology, we conclude that the interfacial bonding of polypropylene and wood powder can be improved by atmospheric pressure plasma treatment.


2012 ◽  
Vol 1401 ◽  
Author(s):  
Yoshiyuki Iwata ◽  
Hajime Sakamoto ◽  
Keigo Takeda ◽  
Masaru Hori

ABSTRACTThis study examined surface modification of solder resist and dry film resist using 60 Hz nonequilibrium atmospheric pressure plasma with O2/N2 mixing gas. Results show that the plasma discharge condition at O2/N2 mixing ratio of 0.1% was the best for surface modification for both materials, and the surfaces were modified sufficiently at 0.45 m/min package substrate transportation speed. From the plasma diagnostics by Vacuum Ultraviolet Absorption Spectroscopy (VUVAS) and Optical Emission Spectroscopy (OES), it was found that the behaviors of the oxygen radical density and NO-γ emission intensity correlate strongly with surface modification. The extremely high oxygen radical density around 4.7 × 1013 cm-3 was obtained at O2/N2 mixing ratio of 0.1%. The electron density was 2.5 × 1015 cm-3 that is two digits more than that of the conventional atmospheric pressure plasma such as Dielectric Barrier Discharge (DBD). The solder resist surface with the plasma treatment was analyzed by X-ray Photoelectron Spectroscopy (XPS), and it was clarified that material surface was modified by hydrophilic group generation owing polymer chain oxidation with oxygen radical.


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